Citation: LI Mei-hui, MA Wen-chao, BI Ya-dong, CHEN Guan-yi, CHEN Hui. Catalytic co-cracking of reduced pressure distillation of bio-oil and ethanol over ZSM-5/MCM-41[J]. Journal of Fuel Chemistry and Technology, ;2015, 43(3): 309-314. shu

Catalytic co-cracking of reduced pressure distillation of bio-oil and ethanol over ZSM-5/MCM-41

1.
1. Tianjin University of Technology, Tianjin 300384, China;

Corresponding author: MA Wen-chao,
Received Date: 22 August 2014

Fund Project: 国家自然科学基金(51036006, 51306131)。 (51036006, 51306131)

The reduced pressure distillation of bio-oil and the ethanol with the mixing ratio of 2:3 by weight were subjected to catalytic co-cracking over ZSM-5/MCM-41 molecular sieve in a fixed-bed reactor. The effects of reaction temperature and WHSV on cracking products were investigated. The catalyst is characterized by NH₃-TPD, BET, N₂ adsorption and desorption. The gaseous products were analyzed by gas chromatograph, and reduced pressure distillation of bio-oil and the upgraded bio-oil were quantified by gas chromatograph-mass spectrometry. It is found that the optimum conditions for the upgrading of bio-oil are 500 ℃ of the reaction temperature and 3.75 h^-1 of the WHSV, under which the acid substance in upgraded bio-oil is markedly reduced from 25.6% in reduced pressure distillation of bio-oil to 0.1% after upgrading. Meanwhile, the yield of upgraded bio-oil is 46.8%, and the concentration of CO₂ and CO in the gaseous products is 9.5%.
- bio-oil,
- ZSM-5/MCM-41,
- catalytic co-cracking,
- upgrading
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