Citation: RAN Jing-yu, ZHANG Song, QIN Chang-lei, YU Jian-gong, FU Fan-xuan, YANG Lin. Gasification reactivity of biomass char with oxygen carrier CuO[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(11): 1316-1323. shu

Gasification reactivity of biomass char with oxygen carrier CuO

RAN Jing-yu ^1,2,, ,
ZHANG Song ^1,2 ,
QIN Chang-lei ^1,2 ,
YU Jian-gong ^1,2 ,
FU Fan-xuan ^1,2 ,
YANG Lin ^1,2

1.
1. Key Laboratory of Low-Grade Energy Utilization Technologies and Systems, Chongqing University, Chongqing 400030, China;

Corresponding author: RAN Jing-yu,
Received Date: 6 May 2014
Available Online: 16 July 2014
Fund Project: 重庆市自然科学基金(cstc2013jjB90003) (cstc2013jjB90003) 低品位能源利用技术及系统教育部重点实验室开放基金(LLEUTS-201306). (LLEUTS-201306)

Calculations of reactions between biomass char and oxygen carriers CuO were conducted via the method of Gibbs free energy minimization. The effect of temperature, mass ration of oxygen carrier/biomass char and pressure on the gasification of biomass char was examined. The reactions were experimentally investigated using thermogravimetric analysis and scanning electron microscopy (SEM). The results show that when using CuO as oxygen carrier in chemical looping gasification (CLG) of biomass char, the conversion rate of biomass char is improved with increasing reaction temperature. The oxygen carrier CuO starts to sinter when the reaction temperature is above 750 ℃. The addition of oxygen carrier has the best enhancement on the CLG of biomass char with mass ratio of biomass char/CuO being 1:6. It is also found that the increase of reaction pressure would inhibit the CLG of biomass chars.
- chemical-looping gasification,
- biomass char,
- thermodynamic calculations,
- thermogravimetric analysis
1. [1]
  [1] 吴创之, 马隆龙. 生物质能现代利用技术[M]. 北京: 化学工业出版社, 2003.(WU Chuang-zhi, MA Long-long. Modern application technology of biomass[M]. Beijing: Chemical Industry Press, 2003.)
2. [2]
  [2] DE DIEGO L F, ORTIZ M, GARCÍA-LABIANO F, ADÁNEZ J, ABAD A, GAYÁN P. Hydrogen production by chemical-looping reforming in a circulating fluidized bed reactor using Ni-based oxygen carriers[J]. J Power Sources, 2009, 192(1): 27-34.
3. [3]
  [3] ORTIZ M, de DIEGO L F, ABAD A, GARCIA-LABIANO F, GAYAN P, ADANEZ J. Hydrogen production by auto-thermal chemical-looping reforming in a pressurized fiuidized bed reactor using Ni-based oxygen carriers[J]. Int J Hydrogen Energy, 2010, 35(1): 151-160.
4. [4]
  [4] ISHIDA T, JIN H. A novel chemical-looping combustor without NO_x Formation[J]. Ind Eng Chem Res, 1996, 35(7): 2469-2472.
5. [5]
  [5] ADÁNEZ-RUBIO I, ABAD A, GAYÁN P, DE DIEGO L F, GARCÍA-LABIANO F, ADÁNEZ J. Identification of operational regions in the Chemical-Looping with Oxygen Uncoupling (CLOU) process with a Cu-based oxygen carrier[J]. Fuel, 2012, 102: 634-645.
6. [6]
  [6] De DIEGO L F, ORTIZ M, ADANEZ J, GARCA-LABIANO F, ABAD A, GAYN P. Synthesis gas generation by chemical-looping reforming in a batch fluidized bed reactor using Ni-based oxygen carriers[J]. Chem Eng J, 2008, 144(2): 289-298.
7. [7]
  [7] BOLHÀR-NORDENKAMPF J, PROLL T, KOLBITSCH P, HOFBAUER H. Performance of a NiO-based oxygen carrier for chemical looping combustion and reforming in a 120 kW unit[J]. Energy Procedia, 2009, 1(1): 19-25.
8. [8]
  [8] 郑敏, 沈来宏, 冯晓琼. CaO加入条件下煤与CaSO₄氧载体化学链燃烧的反应性能研究[J]. 燃料化学学报, 2014, 42(4): 399-406.(ZHENG Min, SHEN Lai-hong, FENG Xiao-qiong. Study on chemical-looping combustion of coal with CaSO₄ oxygen carrier assisted by CaOaddition[J]. Journal of Fuel Chemistry and Technology, 2014, 42(4): 399-406.)
9. [9]
  [9] 余钟亮, 李春玉, 景旭亮, 丁亮, 房倚天, 黄戒介. 碳酸钾催化的铁基氧载体煤催化化学链燃烧[J]. 燃料化学学报, 2013, 41(7): 826-831.(YU Zhong-liang, LI Chun-yu, JING Xu-liang, DING Liang, FANG Yi-tian, HUANG Jie-jie. Catalytic chemical looping combustion of coal with iron-based oxygen carrier promoted by K₂CO₃[J]. 2013, 41(7): 826-831.)
10. [10]
  [10] 黄振, 何方, 李海滨, 赵增立. 天然铁矿石为氧载体的生物质化学链气化制合成气实验研究[J]. 燃料化学学报, 2012, 20(3): 300-308.(HUANG Zhen, HE Fang, LI Hai-bin, ZHAO Zeng-li. Synthesis gas generation by chemical-loopinggasification of biomass using natural hematite as oxygen carrier[J]. Journal of Fuel Chemistry and Technology, 2012, 20(3): 300-308.)
11. [11]
  [11] XLANG W, SUN X, WANGT S, WENDONG T, XIANG X, YANJI X, YUNHAN X. Investigation of coal fueled chemical looping combustion using Fe₃O₄ as oxygen carrier[C]//Proceedings of the 20th International Conference on Fluidized Bed Combustion. Springer Berlin Heidelberg, 2010: 527-532.
12. [12]
  [12] 刘永强, 王志奇, 吴晋沪, 武景丽, 徐梅. 铜基载氧体与可燃固体废弃物化学链燃烧特性研究[J]. 燃料化学学报, 2013, 41(9): 1056-1063.(LIU Yong-qiang, WANG Zhi-qi, WU Jin-hu, WU Jing-li, XU Mei. Investigation on Cu-based oxygen carrier for chemical looping combustion of combustible solid waste[J]. Journal of Fuel Chemistry and Technology[J]. 2013, 41(9): 1056-1063.)
13. [13]
  [13] 秦翠娟, 沈来宏, 郑敏, 肖军. 基于CaSO₄载氧体的煤化学链燃烧还原反应实验研究[J]. 中国电机工程学报, 2009, 29(17): 43-50. (QIN Cui-juan, SHEN Lai-hong, ZHENG Min, XIAO Jun. Experiments on reducing reaction for chemical looping combustion of coal with CaSO₄ oxygen carrier[J]. Proceedings of the CSEE, 2009, 29(17): 43-50.)
14. [14]
  [14] QILEI S, RUI S, ZHONGYI D, HUIYAN Z, LAIHONG S, JUN X, MINGYAO Z. Chemical-looping combustion of methane with CaSO₄oxygencarrier in a fixedbedreactor[J]. Energy Convers Manage, 2008, 49(11): 3178-3187.
15. [15]
  [15] 赵坤, 何方, 黄振, 魏国强, 李海滨, 赵增立. 三维有序大孔 Fe₂O₃为载氧体的生物质热解气化实验研究[J]. 燃料化学学报, 2013, 41(3): 277-284.(ZHAO Kun, HE Fang, HUANG Zhen, WEI Guo-qiang, LI Hai-bin, ZHAO Zeng-li. Biomass pyrolysis /gasification using three dimensional ordered macroporous (3DOM) Fe₂O₃as an oxygen carrier[J]. Journal of Fuel Chemistry and Technology, 2013, 41(3): 277-284).
16. [16]
  [16] HUANG Z, HE F, FENG Y,ZHAO K , ZHENG A Q, CHANG S , WEI G , ZHAO Z L, AND LI H B. Biomass char direct chemical looping gasification using NiO-modified iron ore as an oxygen carrier[J]. Energy Fuels, 2013, 28(1): 183-191.
17. [17]
  [17] 黄振, 何方, 李新爱, 赵坤, 李海滨. Fe基氧载体的生物质化学链气化过程热力学分析及实验研究[J]. 太阳能学报, 2013, 34(11): 1943-1949.(HUANG Zhen, HE Fang, LI Xin-ai, ZHAO Kun, LI Hai-bin. Thermodynamic analysis and experimental investigation of chemical-looping gasifiction of biomass with Fe-based oxygen carriers[J]. Acta Energiae Solaris Sinica, 2013, 34(11): 1943-1949.)
18. [18]
  [18] CAO Y, CASENAS B, PAN W P. Investigation of chemical-looping combustion by solid fuels. 2. Redox reaction kinetics and product characterization with coal, biomass, and solid waste as solid fuels and CuO as an oxygen carrier[J]. Energy Fuels, 2006, 20(5): 1845-1854.
19. [19]
  [19] 梅道锋, 赵海波, 马兆军, 方彦飞, 郑楚光. 不同挥发分含量的煤焦与铜基氧载体化学链氧解耦的实验研究[J]. 中国电机工程学报, 2013, 33(11): 14-21.(MEI Dao-feng, ZHAO Hai-bo, MA Zhao-jun, FANG Yan-fei, ZHENG Chu-guang. Experimental study on chemical looping with oxygen uncoupling using copper based oxygen carrier and different volatiles contained coal chars[J]. Proceedings of the CSEE, 2013, 33(11): 14-21.)
20. [20]
  [20] KANG K S, KIM C H, BAE K K,CHOA WC, KIMB SH, PARKA C S. Oxygen-carrier selection and thermal analysis of the chemical-looping process for hydrogen production[J]. Int J Hydrogen Energy, 2010, 35(22): 12246-12254.
21. [21]
  [21] HE F, GALINSKY N, LI F. Chemical looping gasification of solid fuels using bimetallic oxygen carrier particles-feasibility assessment and process simulations[J]. Int J Hydrogen Energy, 2013, 38(19): 7839-7854.
22. [22]
  [22] SIRIWARDANE R, TIAN H J, MILLER D, RICHARDS G, SIMONYI T, POSTON J. Evaluation of reaction mechanism of coal-metal oxide interactions in chemical-looping combustion[J]. Combust Flame, 2010, 157(11): 2198-2208.
1. [1]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
2. [2]
  Sheng Zhang , Mingyu Wang , Xiaohong Wang , Jiancheng Feng . Multidimensional Teaching Design and Ideological and Political Exploration of Analytical Chemistry Experiment under the Complete Credit System. University Chemistry, 2024, 39(2): 189-195. doi: 10.3866/PKU.DXHX202307071
3. [3]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
4. [4]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
5. [5]
  Tingting Jiang , Jing Chang . Application of Ideological and Political Education in Chemical Analysis Experiment under the Background of Emerging Engineering Education: Taking the Redox Titration Experiment as an Example. University Chemistry, 2024, 39(2): 168-174. doi: 10.3866/PKU.DXHX202308007
6. [6]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
7. [7]
  Jianchun Wang , Ruyu Xie . The Fantastical Dance of Miss Electron: Contra-Thermodynamic Electrocatalytic Reactions. University Chemistry, 2025, 40(4): 331-339. doi: 10.12461/PKU.DXHX202406082
8. [8]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
9. [9]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
10. [10]
  Zhenli Sun , Ning Wang , Kexin Lin , Qin Dai , Yufei Zhou , Dandan Cao , Yanfeng Dang . Visual Analysis of Hotspots and Development Trends in Analytical Chemistry Education Reform. University Chemistry, 2024, 39(11): 57-64. doi: 10.12461/PKU.DXHX202403095
11. [11]
  Zhening Lou , Quanxing Mao , Xiaogeng Feng , Lei Zhang , Xu Xu , Yuyang Zhang , Xueyan Liu , Hongling Kang , Dongyang Feng , Yongku Li . Practice of Implementing Blended Teaching in Shared Analytical Chemistry Course. University Chemistry, 2024, 39(2): 263-269. doi: 10.3866/PKU.DXHX202308089
12. [12]
  Yan Zhang , Ping Wang , Tiebo Xiao , Futing Zi , Yunlong Chen . Measures for Ideological and Political Construction in Analytical Chemistry Curriculum. University Chemistry, 2024, 39(4): 255-260. doi: 10.3866/PKU.DXHX202401017
13. [13]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
14. [14]
  Liuchuang Zhao , Wenbo Chen , Leqian Hu . Discussion on Improvement of Teaching Contents about Common Evaluation Parameters in Analytical Chemistry. University Chemistry, 2024, 39(2): 379-391. doi: 10.3866/PKU.DXHX202308079
15. [15]
  Guangming Yang , Yunhui Long . Design and Implementation of Analytical Chemistry Curriculum Based on the Learning Community of Teachers and Students. University Chemistry, 2024, 39(3): 132-137. doi: 10.3866/PKU.DXHX202309089
16. [16]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
17. [17]
  Tian Li , Liping Zhang , Ling Liu , Ruifang Li , Longfei Mao , Hui Yang . Reform and Practice of Analytical Chemistry Teaching under the Guidance of Course Ideology and Politics. University Chemistry, 2024, 39(6): 189-194. doi: 10.3866/PKU.DXHX202310014
18. [18]
  Fan Yu , Aihua Li , Yun Liu , Tianrong Zhu , Liang Wang , Junhui Xu , Yazhen Wang . Exploration and Practice in Developing a Premier Course in Inorganic and Analytical Chemistry. University Chemistry, 2024, 39(8): 36-43. doi: 10.3866/PKU.DXHX202312037
19. [19]
  Shuangyan Huan , Jianhui Jiang , Gongke Li , Wenqing Zhang , Na Li , Yi Yang , Bin Hu , Yang Tian , Shuo Wu , Sichun Zhang , Yonghai Yue , Dechen Jiang , Zengping Chen , Zhonglin Lu , Cheng Cui , Yuzhi Wang , Weihong Tan . Exploration on the Construction of Analytical Chemistry Core Curriculum in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 22-26. doi: 10.12461/PKU.DXHX202409003
20. [20]
  Lijun Dong , Pengcheng Du , Guangnong Lu , Wei Wang . Exploration and Practice of Independent Design Experiments in Inorganic and Analytical Chemistry: A Case Study of “Preparation and Composition Analysis of Tetraammine Copper(II) Sulfate”. University Chemistry, 2024, 39(4): 361-366. doi: 10.3866/PKU.DXHX202310041

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(438)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142