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Citation: LIU Jian-jun, YANG Zhong-qing, ZHANG Li. Effect of Ni addition on the catalytic performance of Cu/γ-Al2O3 in the combustion of lean methane containing SO2[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(10): 1253-1258. shu

Effect of Ni addition on the catalytic performance of Cu/γ-Al2O3 in the combustion of lean methane containing SO2

  • 1.

    1. Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Ministry of Education, Chongqing University, Chongqing 400030, China;

  • Corresponding author: ZHANG Li, 
  • Received Date: 29 May 2014
    Available Online: 28 July 2014

    Fund Project: 国家自然科学基金(51206200) (51206200) 中央高校基本科研业务经费(CDJZR12140031)。 (CDJZR12140031)

  • The Cu/γ-Al2O3 catalyst promoted with Ni was prepared by incipient wetness impregnation and used in the catalytic combustion of lean methane (3%) containing SO2 (0.01%) in a fixed bed reactor; the effect of Ni addition on the catalytic activity of Cu/γ-Al2O3 and stability against sulfur poisoning in lean methane combustion was investigated. The results showed that Cu/γ-Al2O3 catalyst is facilely poisoned by SO2 in the feed gas and its resistance against sulfur poisoning can be effectively improved through the addition of Ni as a promoter. The stability of Cu/γ-Al2O3 catalyst is increased with the increase of Ni content; over the Cu/γ-Al2O3 catalyst promoted by 10% Ni, the conversion of CH4 remains above 96% after reaction at 650 ℃ for 10 h. The catalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and NH3 temperature-programmed desorption (NH3-TPD); the results illustrated that NiAl2O4 spinel is formed on the Ni-promoted Cu/γ-Al2O3 catalyst. Upon the formation of NiAl2O4 spinel, the surface Lewis acidity is reduced, and meanwhile, the adsorption of SO2 is weakened and the retention time of CO2 on the surface is reduced, all these may contribute to the high activity and stability against sulfur poisoning of the Ni-promoted Cu/γ-Al2O3 catalyst in lean methane combustion.
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