Citation: GENG Rui, DONG Mei, WANG Hao, NIU Xian-jun, FAN Wei-bin, WANG Jian-guo, QIN Zhang-feng. An investigation on the catalytic performance of 10 MR zeolites in methanol aromatization reaction[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(9): 1119-1127. shu

An investigation on the catalytic performance of 10 MR zeolites in methanol aromatization reaction

GENG Rui ^1,2 ,
DONG Mei ^1,, ,
WANG Hao ¹ ,
NIU Xian-jun ^1,2 ,
FAN Wei-bin ^1,, ,
WANG Jian-guo ¹ ,
QIN Zhang-feng ¹

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: DONG Mei, FAN Wei-bin,
Received Date: 17 January 2014
Available Online: 5 March 2014
Fund Project: 国家自然科学基金(21103216,21273264,21273263) (21103216,21273264,21273263)国家重点基础研究发展规划(973计划,2011CB201403) (973计划,2011CB201403)山西省自然科学基金(2012011005-2)。 (2012011005-2)

Five zeolites ZSM-5, ZSM-22, EU-1, MCM-22, and ITQ-13 with 10 member ring channels were hydrothermally synthesized and their structure, acidity, morphology and catalytic behaviors in methanol aromatization reaction were compared. The results indicate that the morphology, microporous volumes, and physicochemical properties of the zeolites differ significantly from each other, and thus results in considerable influence on the catalytic activity and stability. Among the five zeolites studied, ZSM-5 shows the highest aromatic yield of 34.8%, followed by MCM-22 with the aromatic yield of 21.9%. However, unlike ZSM-5 and MCM-22, the other three catalysts are inactivitive for methanol aromatization. The introduction of Ga species into ZSM-5 and MCM-22, however, can improve the aromatic yield significantly. The aromatic yields on Ga/ZSM-5 and Ga/MCM-22 reach 40.8% and 27.1%, respectively. The TG/DTA and GC analyses of the coke compounds deposited on the deactivated catalysts suggest that the five zeolites display much differences in composition, location and distribution of coke deposition.
- methanol aromatization,
- 10 MR zeolites,
- ZSM-5,
- ZSM-22,
- EU-1,
- MCM-22,
- ITQ-13,
- coke deposition
1. [1]
  [1] TRAVALLONI L, GOMES A C L, GASPAR A B, SILVA M A P. Methanol conversion over acid solid catalysts[J]. Catal Today, 2008, 133-135: 406-412.
2. [2]
  [2] STÖCKER M. Methanol to hydrocarbons: Catalytic materials and their behavior[J]. Microporous Mesoporous Mater, 1999, 29(1/2): 3-48.
3. [3]
  [3] KIM J, CHOI M, RYOO R. Effect of mesoporosity against the deactivation of MFI zeolite catalyst during the methanol to hydrocarbon conversion process[J]. J Catal, 2010, 269(1): 219-228.
4. [4]
  [4] CHEN J Q, BOZZANO A, GLOVER B, FUGLERUD T, KVISLE S. Recent advancements in ethylene and propylene production using the UOP/Hydro MTO process[J]. Catal Today, 2005, 106(1/4): 103-107.
5. [5]
  [5] MOKRANI T, SCURRELL M. Gas conversion to liquid fuels and chemicals: The methanol route-catalysis and processes development[J]. Catal Rev, 2009, 51(1): 1-145.
6. [6]
  [6] KUMAR R, RATNASWAMY P. Isomerization and formation of xylenes over ZSM-5 and ZSM-23 zeolites[J]. J Catal, 1989, 116(2): 440-448.
7. [7]
  [7] BRISCOE N A, JOHNSON D W, SHANNON M D. The framework topology of zeolite EU-1[J]. Zeolites, 1988, 8(1): 74-76.
8. [8]
  [8] BOXI T, PUCHE M, CAMBLOR M A. Synthetic porous crystalline material, used as catalyst and adsorbent, comprises sets of generally parallel channels defined by specific rings of tetrahedrally coordinated atoms, which intersect mutually: US, 6471941. 2002.
9. [9]
  [9] BAERLOCHER C H, MCCUSKER L B, OLSON D H. Atlas of zeolite framework types sixth revised edition[M]. Netherlands: Elsevier Science Ltd, 2007.
10. [10]
  [10] ROBSON H, LILLERUD K P. Verified synthesis of zeolitic materials[M]. Netherlands: Elsevier Science Ltd, 2001.
11. [11]
  [11] 苗青, 董梅, 牛宪军, 王浩, 樊卫斌, 王建国, 秦张峰. 含镓ZSM-5 分子筛的制备及其在甲醇芳构化反应中的催化性能[J]. 燃料化学学报, 2012, 40(10): 1230-1239. (MIAO Qing, DONG Mei, NIU Xian-jun, WANG Hao, FAN Wei-bin, WANG Jian-guo, QIN Zhang-feng. Synthesis of gallium-containing ZSM-5 molecular sieves and their catalytic performance in methanol aromatization[J]. Journal of Fuel Chemistry and Technology, 2012, 40(10): 1230-1239.)
12. [12]
  [12] JOLY J F, AJOT H, MERLEN E, RAATZ F, ALARIO F. Parameters affecting the dispersion of the gallium phase of gallium H-MFI aromatization catalysts[J]. Appl Catal A: Gen, 1991, 79(2): 249-263.
13. [13]
  [13] TEKETEL S. Shape selectivity in the conversion of methanol to hydrocarbons: The catalytic performance of one-dimensional 10-ring zeolites: ZSM-22, ZSM-23, ZSM-48, and EU-1[J]. ACS Catal, 2012, 2(1): 26-37.
14. [14]
  [14] BJØRGEN M, OLSBYE U, PETERSEN D, KOLBOE S. The methanol to hydrocarbons reaction: Insight into the reaction mechanism from ¹²C benzene and ¹³C methanol coreactions over zeolite H-beta[J]. J Catal, 2004, 221(1): 1-10.
15. [15]
  [15] TEKETEL S, OLSBYE U, LILLERUD K P, BEATO P, SVELLE S. Selectivity control through fundamental mechanistic insight in the conversion of methanol to hydrocarbons over zeolites[J]. Microporous Mesoporous Mater, 2010, 136(1/3): 33-41.
16. [16]
  [16] BEECKMAN J W, FROMENT G F. Catalyst deactivation by active site coverage and pore blockage[J]. Ind Eng Chem Fundam, 1979, 18(3): 245-256.
17. [17]
  [17] BEECKMAN J W, FROMENT G F. Catalyst deactivation by site coverage and pore blockage: Finite rate of growth of the carbonaceous deposit[J]. Chem Eng Sci, 1980, 35(4): 805-815.
18. [18]
  [18] ROLLMANN L D, WALSH D E. Shape selectivity and carbon formation in zeolites[J]. J Catal, 1979, 56(1): 139-140.
19. [19]
  [19] 刘中民, 陈国权, 王清遐, 梁娟, 蔡光宇. 分子筛催化剂的失活与积炭[J]. 催化学报, 1994, 15(4): 301-303. (LIU Zhong-min, CHEN Guo-quan, WANG Qing-xia, LIANG Juan, CAI Guang-yu. Deactivation and coke formation on zeolite catalysts[J]. Chinese Journal of Catalysis, 1994, 15(4): 301-303.)
20. [20]
  [20] BJØRGEN M, SVELLE S, JOENSEN F, NERLOV J, KOLBOE S, BONINO F, PALUMBO L, BORDIGA S, OLSBYE U. Conversion of methanol to hydrocarbons over zeolite H-ZSM-5: On the origin of the olefinic species[J]. J Catal, 2007, 249(2): 195-207.
21. [21]
  [21] BLEKEN F, SKISTAD W, BARBERA K, KUSTOVA M, BORDIGA S, BEATO P, LILLERUD K P, SVELLE S, OLSBYE U. Conversion of methanol over 10-ring zeolites with differing volumes at channel intersections: Comparison of TNU-9, IM-5, ZSM-11 and ZSM-5[J]. Phys Chem Chem Phys, 2011, 13(7): 2539-2549.
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