Citation: HE Hong-kui, WANG Wen-liang, CHANG Jian-min. Co-pyrolysis of waste tire and larch wood in TG-FTIR[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(7): 799-804. shu

Co-pyrolysis of waste tire and larch wood in TG-FTIR

1.
1. Energy Research Center, North University of China, Taiyuan 030051, China;

Corresponding author: CHANG Jian-min,
Received Date: 18 April 2014
Available Online: 8 June 2014
Fund Project: 山西省科技攻关项目(20110321017-03) (20110321017-03)教育部博士学科点专项科研基金(20130014110015)。 (20130014110015)

The characteristics of thermal cracking, kinetics and product gas during co-pyrolysis of different mixtures of larch sawdust and waste tire (1:2, 1:1 and 2:1) were investigated using a thermogravimetric analyzer coupled with Fourier Transform Infrared (TG-FTIR). The weight loss curves show that the process of co-pyrolysis is dominated by the larch thermal degradation before 366℃ and by the rubber thermal degradation after 366℃. The pyrolysis efficiency is improved as the ratios of larch sawdust increase. The kinetic model of Coats-Redfern was used to analyze the kinetic behaviors. It is found that the pyrolysis behavior accords with the first-order kinetics, and the activation energy in the high temperature range (370~480℃) is much smaller than that in the low temperature range (250~370℃), moreover, the pyrolysis reaction is easier to occur because the activation energy decreases with increasing the ratios of larch sawdust. The results of infrared analysis show that the organics with oxygen-containing functional groups and small molecules are main product produced. During the process of pyrolysis, the amounts of six kinds of small molecular gases produced are in the order of CO₂>CH₄>H₂O>CO>SO₂>H₂S, and S is mainly converted to SO₂ due to the effect of oxygen free radical, which is produced in the thermal degradation of larch wood.
- larch wood,
- waste tyre,
- co-pyrolysis,
- TG-FTIR
1. [1]
  [1] 王琦. 生物质热裂解制取生物油及其后续应用研究. 杭州: 浙江大学, 2008. (WANG Qi. Research on production and utilization of bio-oil from biomass fast pyrolysis. Hangzhou: Zhejiang University, 2008.)
2. [2]
  [2] 黄菊文, 李光明, 贺文智, 王华, 殷进. 废旧轮胎热解资源化技术研究进展[J]. 化工进展, 2010, 29(11): 2159-2164. (HUANG Ju-wen, LI Guang-ming, HE Wen-zhi, WANG Hua, YIN Jin. Research progress in recovery technology of waste tyre by pyrolysis[J]. Chemical Industry and Engineering Progress, 2010, 29(11): 2159-2164.)
3. [3]
  [3] CHIARAMONTI D, BONINI M, FRATINI E, TONDI G, GARTNER K, BRIDGWATER A V, GRIMM H P, SOLDAINI I, WEBSTER A, BAGLIONI P. Development of emulsions from biomass pyrolysis liquid and diesel and their use in engines: Part 2.Tests in diesel engines[J]. Biomass Bioenergy, 2003, 25(1): 101-111.
4. [4]
  [4] 蔡文娟, 刘耀鑫, 杨天华, 李润东. 生物质催化热解油的GC-MS分析[J]. 沈阳航空工业学院学报, 2010, 27(3): 71-76. (CAI Wen-juan, LIU Yao-xin, YANG Tian-hua, LI Run-dong. GC-MS analysis of bio-oil from biomass pyrolysis[J]. Journal of Shenyang Institute of Aeronautical Engineering, 2010, 27(3): 71-76.)
5. [5]
  [5] WILLIAMS P T, BERSLER S, TAYLOR D T. The pyrolysis of scrap automotive dyres: The influence of temperature and heating rate on product composition[J]. Fuel, 1990, 69(12): 1474-1482.
6. [6]
  [6] 靳利娥, 刘岗, 鲍卫仁, 曹青. 生物质与废轮胎共热解催化热解油蒸发过程及动力学研究[J]. 燃料化学学报, 2007, 35(5): 534-538. (JIN Li-e, LIU Gang, BAO Wei-ren, CAO Qing. Thermal behavior and dynamics of biomass and waste tyre co-pyrolysis oil[J]. Journal of Fuel Chemistry and Technology, 2007, 35(5): 534-538.)
7. [7]
  [7] CAO Q, JIN L E, BAO W R, LV Y K. Investigations into the characteristics of oils produced from co-pyrolysis of biomass and tire[J]. Fuel Process Technol, 2009, 90(3): 337-342.
8. [8]
  [8] CHEN M Q, LIU S M, WANG J, MIN F F, CHEN M G. Catalytic effects of several additives on co-pyrolysis of tobacco stalk and waste rubber tire powder//Proceedings of 2011 International Conference on Materials for Renewable Energy & Environment. Shanghai(China): IEEE Press, 2011, 1: 322-326.
9. [9]
  [9] BERNARDO M, LAPA N, GONCALVES M, MENDES B, PINTO F, FONSECA I, LOPES H. Physico-chemical properties of chars obtained in the co-pyrolysis of waste mixtures[J]. J Hazardous Mater, 2012, 219-220: 196-202.
10. [10]
  [10] JIN L E, WANG L L, SU L, CAO Q. Characteristics of gases from co-pyrolysis of sawdust and tires[J]. Int J Green Energy, 2012, 9(8): 719-730.
11. [11]
  [11] 任学勇, 杜洪双, 王文亮, 苟进胜, 常建民. 基于TG-FTIR的落叶松木材热失重与热解气相演变规律研究[J]. 光谱学与光谱分析, 2012, 32(4): 944-948. (REN Xue-yong, DU Hong-shuang, WANG Wang-liang, GOU Jin-sheng, CHANG Jian-min. Analysis of pyrolysis process and gas evolution rule of larch wood by TG-FTIR[J]. Spectroscopy and Spectral Analysis, 2012, 32(4): 944-948.)
12. [12]
  [12] COATS A W, REDFERN J P. Kinetic parameters from thermo-gravimetric data[J]. Nature, 1964, 201: 68-69.
13. [13]
  [13] LEE J M, LEE J S, KIM J R, KIM S D. Pyrolysis of waste tires with partial oxidation in a fluidized-bed reactor[J]. Energy, 1995, 20(10): 969-976.
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