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新型碳纤维负载直接乙醇燃料电池Pt-SnO2阳极催化剂的性能研究

王旭红 ,  朱慧 ,  黄金山 ,  纪网金 ,  骆秀淇

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引用本文: 王旭红, 朱慧, 黄金山, 纪网金, 骆秀淇. 新型碳纤维负载直接乙醇燃料电池Pt-SnO2阳极催化剂的性能研究[J]. 燃料化学学报, 2014, 42(6): 763-768. shu
Citation:  WANG Xu-hong, ZHU Hui, Huang Jin-shan, JI Wang-jin, LUO Xiu-qi. Performance of carbon fiber supported Pt-SnO2 anode catalyst for direct ethanol fuel cell[J]. Journal of Fuel Chemistry and Technology, 2014, 42(6): 763-768. shu

新型碳纤维负载直接乙醇燃料电池Pt-SnO2阳极催化剂的性能研究

    通讯作者: 朱慧,Tel:13812981831,E-mail:keying716@gmail.com。
  • 基金项目:

    江苏省自然科学基金(BK2007704)。 (BK2007704)

摘要: 采用静电纺丝技术制备了碳纤维基纳米Pt-SnO2阳极催化剂(Pt/Sn原子比为3)。通过X射线衍射(XRD)、红外光谱(FT-IR)、扫描电子显微镜(SEM)等技术对该催化剂进行了表征,并采用循环伏安法对其在乙醇燃料电池中的阳极催化活性进行了评价。结果表明,纳米Pt-SnO2催化剂均匀地分散在碳纤维骨架上;随着烧结温度的升高,碳纤维载体的致密度越高、导电性能越好。电催化性能测试表明,烧结温度为800 ℃时催化剂的峰电流密度最大,达到0.11 A/cm2,抗中毒能力也最强。单电池的发电性能表明,在一定的乙醇浓度下,1.0 mL/min进样流速具有最优的发电效率。

English

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  • 收稿日期:  2013-12-19
  • 网络出版日期:  2014-02-23
通讯作者: 陈斌, bchen63@163.com
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