Citation: GUO Peng-fei, JIN Guo-qiang, GUO Cong-xiu, WANG Ying-yong, TONG Xi-li, GUO Xiang-yun. Effects of Yb₂O₃ promotor on the performance of Ni/SiC catalysts in CO₂ reforming of CH₄[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(6): 719-726. shu

Effects of Yb₂O₃ promotor on the performance of Ni/SiC catalysts in CO₂ reforming of CH₄

1.
1. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: JIN Guo-qiang,
Received Date: 6 March 2014
Available Online: 4 May 2014
Fund Project: 国家重点基础研究发展规划(973计划,2011CB201405)。 (973计划,2011CB201405)

Ni/SiC and Ni-Ybx/SiC (x=2%, 4%, 6%,10%) catalysts were prepared by the impregnation method, and the performances of catalysts in the carbon dioxide reforming of methane were studied in a fixed-bed reactor.The catalysts were characterized by BET, ICP-AES, XRD, H₂-TPR, TG-DTA, XPS and TEM techniques.The experimental results indicate that the appropriate addition amount of Yb is 4% to 6%.Ni-Yb4/SiC and Ni-Yb6/SiC catalysts exhibit excellent catalytic activity and stability at 800 ℃, and the conversion of CH₄ and CO₂ can be maintained over 90% during the 100 h testing. Yb₂O₃ promotor can inhibit the growth of nickel nanoparticles and reduce the amount of carbon deposition,therefore Ni-Yb/SiC catalysts show stable activity in the continuous reforming reaction.
- CO₂ reforming of CH₄,
- Ni-Yb/SiC catalyst,
- promotor,
- stability
1. [1]
  [1] FAN M S, ABDULLAH A Z, BHATIA S. Catalytic technology for carbon dioxide reforming of methane to synthesis gas[J]. ChemCatChem, 2009, 1(2): 192-208.
2. [2]
  [2] 王莉, 敖先权, 王诗翰. 甲烷与二氧化碳催化重整制取合成气催化剂[J]. 化学进展, 2012, 24(9): 1696-1706. (WANG Li, AO Xian-quan, WANG Shi-han. Catalysts for carbon dioxide catalytic reforming of methane to synthesis gas[J]. Progress in Chemistry, 2012, 24(9): 1696-1706.)
3. [3]
  [3] FISCHER F, TROPSCH H. Conversion of methane into hydrogen and carbon monoxide[J]. BrennstChem, 1928, 9: 39-46.
4. [4]
  [4] BRADFORD M C J, VANNICE M A. CO₂ reforming of CH₄ over supported Ru catalysts[J]. J Catal, 1999, 183(1): 69-75.
5. [5]
  [5] WANG H Y, RUCKENSTEIN E. Carbon dioxide reforming of methane to synthesis gas over supported rhodium catalysts: The effect of support[J]. Appl Catal A: Gen, 2000, 204(1): 143-152.
6. [6]
  [6] YAMAGUCHI A, IGLESIA E. Catalytic activation and reforming of methane on supported palladium clusters[J]. J Catal, 2010, 274(1): 52-63.
7. [7]
  [7] WEI J M, GLESIA E. Structural and mechanistic requirements for methane activation and chemical conversion on supported iridium clusters[J]. Angew Chem Int Ed, 2004, 43(28): 3685-3688.
8. [8]
  [8] PANT B, STAGG-WILLIAMS S M. Investigation of the stability of Pt/LaCoO₃ during high temperature reforming reactions[J]. Catal Commun, 2004, 5(6): 305-309.
9. [9]
  [9] ROSTRUPNIELSEN J R, HANSEN J H B. CO₂-reforming of methane over transition metals[J]. J Catal, 1993, 144(1): 38-49.
10. [10]
  [10] 徐军科, 任克威, 王晓蕾, 周伟, 潘相敏, 马建新. 甲烷干重整制氢研究进展[J]. 天然气化工, 2008, 33(3): 53-60. (XU Jun-ke, REN Ke-wei, WANG Xiao-lei, ZHOU Wei, PAN Xiang-min, Ma Jian-xin. Progress in studies on dry-reforming of methane to hydrogen[J]. Natural Gas Chemical Industry, 2008, 33(3): 53-60.)
11. [11]
  [11] 孙楠楠, 闻霞, 王峰, 彭伟才, 肖福魁, 魏伟, 孙予罕, 李海. 反应条件对Ni-CaO-ZrO₂催化剂上CH₄-CO₂重整反应及积炭的影响[J]. 燃料化学学报, 2012, 40(3): 345-349. (SUN Nan-nan, WEN Xia, WANG Feng, PENG Wei-cai, XIAO Fu-kui, WEI Wei, SUN Yu-han, LI Hai. Influences of reaction conditions on the CH₄-CO₂ reforming and coking properties of a Ni-CaO-ZrO₂ catalyst[J]. Journal of Fuel Chemistry and Technology, 2012, 40(3): 345-349.)
12. [12]
  [12] LIU H T, LI S Q, ZHANG S B, CHEN L, ZHOU G J, WANG J M, WANG X L. Catalytic performance of monolithic foam Ni/SiC catalyst in carbon dioxide reforming of methane to synthesis gas[J]. Catal Lett, 2008, 120(1/2): 111-115.
13. [13]
  [13] SUNW Z, JIN G Q, GUO X Y. Partial oxidation of methane to syngas over Ni/SiC catalysts[J]. Catal Commun, 2005, 6(2): 135-139.
14. [14]
  [14] 职国娟, 王英勇, 靳国强, 郭向云. 镍盐前驱体对CO₂甲烷化Ni/SiC催化剂性能的影响[J]. 天然气化工, 2012, 37(5): 10-14. (ZHI Guo-juan, WANG Ying-yong, JIN Guo-qiang, GUO Xiang-yun. Effect of nickel precursors on catalytic performance of Ni/SiC catalysts for CO₂ methanation[J]. Natural Gas Chemical Industry, 2012, 37(5): 10-14.)
15. [15]
  [15] YANG R Q, XING C, LV C X, SHI L, TSUBAKI N. Promotional effect of La₂O₃ and CeO₂ on Ni/gamma-Al₂O₃ catalysts for CO₂ reforming of CH₄[J]. Appl Catal A: Gen, 2010, 385(1/2): 92-100.
16. [16]
  [16] LI X C, WU M, LAI Z H, HE F. Studies on nickel-based catalysts for carbon dioxide reforming of methane[J]. Appl Catal A: Gen, 2005, 290(1/2): 81-86.
17. [17]
  [17] BARROSO-QUIROGA M M, CASTRO-LUNA A E. Catalytic activity and effect of modifiers on Ni-based catalysts for the dry reforming of methane[J]. Int J Hydrogen Energy, 2010, 35(11): 6052-6056.
18. [18]
  [18] AMAIN M H, MANTRI K, NEWNHAM J, TARDIO J, BHARGAVA S K. Highly stable ytterbium promoted Ni/gamma-Al₂O₃ catalysts for carbon dioxide reforming of methane[J]. Appl Catal B: Environ, 2012, 119-120: 217-226.
19. [19]
  [19] JIN G Q, GUO X Y. Synthesis and characterization of mesoporous silicon carbide[J]. Microporous Mesoporous Mater, 2003, 60(1/3): 207-212.
20. [20]
  [20] GARCIA-VARGAS J M, VALVERDE J L, DE LUCAS-CONSUEGRA A, GOMEZ-MONEDERO B, SANCHEZ P, DORADO F. Precursor influence and catalytic behaviour of Ni/CeO₂ and Ni/SiC catalysts for the tri-reforming process[J]. Appl Catal A: Gen, 2012, 431-432: 49-56.
21. [21]
  [21] CONTARINI S, HOWLETT S P, RIZZO C, DE ANGELIS B A. XPS study on the dispersion of carbon additives in silicon carbide powders[J]. Appl Surf Sci, 1991, 51(3/4): 177-183.
22. [22]
  [22] YAMAMOTO T, MATSUYAMA T, TANAKA T, FUNABIKI T, YOSHIDA S. Silica-supported ytterbium oxide characterized by spectroscopic methods and acid-catalyzed reactions[J]. J Mol Catal A: Chem, 2000, 155(1/2): 43-58.
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Effects of Yb2O3 promotor on the performance of Ni/SiC catalysts in CO2 reforming of CH4

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Effects of Yb₂O₃ promotor on the performance of Ni/SiC catalysts in CO₂ reforming of CH₄