Citation: YUE Chuan-jun, WANG Ji-xiang, CAO Gui-ping, LIU Bao-liang. Study on the Cu-P system with water for hydrogen production[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(4): 507-512. shu

Study on the Cu-P system with water for hydrogen production

1.
Department of Chemical Engineering, School of Science, Changzhou Institute of Technology, Changzhou 213022, China

Corresponding author: YUE Chuan-jun,
Received Date: 17 October 2013
Available Online: 29 December 2013
Fund Project: 江苏省自然科学基金(BK2011235)。 (BK2011235)

Hydrogen production was studied in the Cu-P oxidation-reduction system with water. The influence of Cu /P ratio, reaction temperature, acidity and additional Cu on hydrogen yield was investigated. The green process of Cu-P system was realized by the design of the copper recycling and the phosphorus transformation and utilization. The results showed the hydrogen yield from the hydrogen atom in the reaction was mainly dependent on the Cu/P ratio and the reaction temperature, with the optimal yield of 18.6 mL under the conditions of 95 ℃ and 0.05 mol ratio of Cu to P with 0.20 g CuSO₄·5H₂O. H₂O₂ oxidation of elemental Cu in Cu-P system was also achieved for 10 times recycling under acidic condition. FT-IR and XRD results revealed that H₂PO₃-from the hydrogen production process could be converted into the new antirust CaHPO₃·H₂O with Ca(OH)₂.
- hydrogen production,
- Cu-P system,
- water,
- green process
1. [1]
  [1] DINCER I. Environmental and sustainability aspects of hydrogen and fuel cell systems[J]. Int J Hydrogen Energy, 2007, 31(1): 29-55.
2. [2]
  [2] TUMER J, SVERDRUP G, MANN M K, MANESS P C, KROPOSKI B, GHIRARDI M, EVANS R J, BLAKE D. Renewable hydrogen production[J]. Int J Energy Res, 2008, 32(5): 379-407.
3. [3]
  [3] MEYER S, HSING C. Modern and prospective technologies for hydrogen production from fossil fuels[J]. Int J Hydrogen Energy, 1989, 14(11): 797-820.
4. [4]
  [4] NILGEN C, BILGEN E. An assessment on hydrogen production using central receiver solar systems[J]. Int J Hydrogen Energy, 1984, 9(3): 197-204.
5. [5]
  [5] PENA M A, GOMEZ J P, FIERRO J L G. New catalytic routes for syngas and hydrogen production[J]. Appl Catal A: Gen, 1996, 144(1/2): 7-57.
6. [6]
  [6] KARUNADASA H I, CHANG C J, LONG J R. A molecular molybdenum-oxo catalyst for generating hydrogen from water[J]. Nature, 2010, 464(7285): 132-133.
7. [7]
  [7] 杨亚辉, 陈启元, 尹周澜, 李洁. 光催化分解水的研究进展[J]. 化学进展, 2005, 17(4): 631-642. (YANG Ya-hui, CHEN Qi-yuan, YIN Zhou-lan, LI Jie. Progress in research of photocatalytic water splitting[J]. Progress in Chemistry, 2005, 17(4): 631-642.)
8. [8]
  [8] 祝星, 王华, 魏永刚, 李孔斋, 晏冬霞. 金属氧化物两步热化学循环分解水制氢[J]. 化学进展, 2010, 22(5): 1010-1020. (ZHU Xing, WANG Hua, WEI Yong-gang, LI Kong-zhai, YAN Dong-xia.. Hydrogen production by two-step water-splitting thermochemical cycle based on metal oxide redox system[J]. Progress in Chemistry, 2010, 22(5): 1010-1020.)
9. [9]
  [9] NAVARRO R M, PENA M A, FIERRO J L G. Hydrogen production reactions from carbon feedstocks: Fossil fuels and biomass[J]. Chem Rev, 2007, 107(10): 3952-3991.
10. [10]
  [10] TUZA P V, MANFRO R L, RIBEIRO N F P, SOUZA M M V M. Production of renewable hydrogen by aqueous-phase reforming of glycerol over Ni-Cu catalysts derived from hydrotalcite precursors[J]. Renew Energy, 2013, 50: 408-414.
11. [11]
  [11] VADUVA C C, VASZILCSIN N, KELLENBERGER A, MEDELEANU M. Catalytic enhancement of hydrogen evolution reaction on copper in the presence of benzylamine[J]. Int J Hydrogen Energy, 2011, 36(12): 6994-7001.
12. [12]
  [12] 梁艳, 王平, 戴洪斌. 硼氢化钠催化水解制氢[J]. 化学进展, 2009, 21(10): 2219-2228. (LIANG Yan, WANG Ping, DAI Hong-bin. Hydrogen generation from catalytic hydrolysis of sodium borohydride solution[J]. Progress in Chemistry, 2009, 21(10): 2219-2228.)
13. [13]
  [13] 乐传俊, 顾黎萍, 何仁. RuH₂(PPh₃)₄在催化有机反应中的应用[J]. 贵金属, 2009, 30(3): 54-61. (YUE Chuan-jun, GU Li-ping, HE Ren. RuH₂(PPh₃)₄as a catalyst for organic reactions[J]. Precious Metals, 2009, 30(3): 54-61.)
14. [14]
  [14] HENRY J R. Electroless (autocatalytic) plating[J]. Metal Finish, 1971, 69(3): 424-436.
15. [15]
  [15] MALLORY G O, HAJDU J B. Electroless plating: Fundamentals and application[M]. Orlando: American Electroplaters and Surface Finishers Society, 1990.
16. [16]
  [16] BROOMAN E W. Modifying organic coatings to provide corrosion resistance: Part Ⅱ. Inorganic additives and inhibitors[J]. Metal Finish, 2002, 100(5): 42-53.
17. [17]
  [17] SPENCER L F. The inducing process of electroless nicking[J]. Metal Finish, 1974, 72(4): 50-56.
18. [18]
  [18] SMITH S F. The metal activity in electroless plating[J]. Metal Finish, 1979, 77(6): 60-64.
19. [19]
  [19] VASKELIS A, JACIAUSKIENE J, STALNIONIENE I, NORKUS E. Accelerating effect of ammonia on electroless copper deposition in alkaline formaldehyde-containing solutions[J]. J Electroanal Chem, 2007, 600(1): 6-12.
20. [20]
  [20] VASIKELIS A, JUSIKECNAS R, JACIIAUSKIENEC J. Copper hydride formation in the electroless copper plating process: In situ X-ray direction evidence and electrochemical study[J]. Electrochim Acta, 1998, 43(9): 1061-1066.
21. [21]
  [21] 陈世途, 涂敏端, 刘家丽, 曹建荣. 亚磷酸氢钙的结构特性分析[J]. 四川联合大学学报(工程科学版), 1998, 2(3): 82-86. (CHEN Shi-tu, TU Min-duan, LIU Jia-li, CAO Jian-rong. The construction characteristics of calcium phosphite[J]. Journal of Sichuan Union University (Engineering Science Edition), 1998, 2(3): 82-86.)
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