Advanced Search

Citation: ZHANG Sheng-peng, XU Yong-qiang, LV En-jing, CHAI Yong-ming, LIU Chen-guang. Study of sulfur transfer reaction on Ni-Mo/Al2O3 catalyst[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(4): 494-500. shu

Study of sulfur transfer reaction on Ni-Mo/Al2O3 catalyst

  • 1.

    1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, China University of Petroleum (East China), Qingdao 266580, China;

  • Corresponding author: XU Yong-qiang, 
  • Received Date: 9 December 2013
    Available Online: 22 January 2014

    Fund Project: 国家重点基础研究发展规划(973计划,2010CB226905)。 (973计划,2010CB226905)

  • The bimetal Ni-Mo catalysts supported on γ-Al2O3 were prepared and used for the selective hydrogenation of FCC gasoline for sulfur transfer. The reaction mechanism of sulfur transfer on Ni-Mo/Al2O3 catalyst was studied and the influence of reaction conditions on sulfur transfer was investigated. The results showed that the reaction of thiol and olefin happened on the active sites of hydrogenation on catalyst surface. Hydrodesulfurization of small molecule thiol firstly produced adsorbed hydrogen sulfide, then the adsorbed hydrogen sulfide reacted with adsorbed olefin and formed macromolecular thiol or thioether; Besides, small molecule thiol can also directly reacted with olefins to produce thioether. The activity of sulfur transfer reaction of Ni-Mo/Al2O3 catalyst was improved through the increase of reaction temperature, pressure, and H2/oil ratio or the decrease of LHSV. The conversion of light sulfur compounds was obviously improved, and mono-olefins selectivity was maintained at around 98%.
  • 加载中
    1. [1]

      [1] 高道伟, 段爱军, 赵震, 邓云川. FCC汽油加氢脱硫工艺技术研究进展[J]. 石油与天然气化工, 2013, 42(3): 216-221. (GAO Dao-wei, DUAN Ai-jun, ZHAO Zhen, DENG Yun-chuan. Research development of hydrodesulfurization technology of FCC gasoline[J]. Chemical Engineering of Oil & Gas, 2013, 42(3): 216-221.)

    2. [2]

      [2] 邢金仙, 刘晨光. 催化裂化汽油中硫和族组成及硫化物类型的馏分分布[J]. 炼油技术与工程, 2003, 33(6): 6-9. (XING Jin-xian, LIU Chen-guang. Distribution of sulfur, group composition and types of sulfur compounds in FCC naphtha[J]. Petroleum Refinery Engineering, 2003, 33(6): 6-9.)

    3. [3]

      [3] 马宝利, 徐峰, 刘茉, 董春明, 杨晓东. FCC汽油加氢脱硫提高辛烷值技术研究进展[J]. 炼油与化工, 2013, 24(4): 1-3. (MA Bao-li, XU Feng, LIU Mo, DONG Chun-ming, YANG Xiao-dong. Technical research progress on FCC gasoline hydrodesulfurization for improvement of octane number[J]. Refining and Chemical Industry, 2013, 24(4): 1-3.)

    4. [4]

      [4] 梁咏梅, 史权, 刘旭霞, 何俊辉. 催化裂化汽油选择性加氢脱硫中轻重馏分切割温度的研究[J]. 石油炼制与化工, 2011, 42(5): 40-44. (LIANG Yong-mei, SHI Quan, LIU Xu-xia, HE Jun-hui. Study on the cut points of light and heavy gasoline fractions for selective hydrodesulfurization of FCC gasoline[J]. Petroleum Processing and Petrochemicals, 2011, 42(5): 40-44.)

    5. [5]

      [5] 温广明, 王丹, 赵野, 吴昆鹏. 催化裂化汽油加氢脱硫技术进展[J]. 工业催化, 2008, 16(12): 1-6. (WEN Guang-ming, WANG Dan, ZHAO Ye, WU Kun-peng. Advances in FCC gasoline hydrodesulfurization technologies[J]. Industrial Catalysis, 2008, 16(12): 1-6.)

    6. [6]

      [6] 董海明, 曲云, 孙丽琳. Prime-G+技术在催化裂化汽油加氢脱硫装置上的应用[J]. 石油炼制与化工, 2012, 43(11): 27-30. (DONG Hai-ming, QU Yun, SUN Li-lin. Application of Prime-G+ technology in FCC naphtha hydrodesulfurization unit[J]. Petroleum Processing and Petrochemicals, 2012, 43(11): 27-30.)

    7. [7]

      [7] 周庆水, 郝振歧, 王艳涛, 赵乐平. OCT-M FCC汽油深度加氢脱硫技术的研究及工业应用[J]. 石油炼制与化工, 2007, 38(9): 28-31. (ZHOU Qing-shui, HAO Zhen-qi, WANG Yan-tao, ZHAO Le-ping. Development and commercial application of OCT-M process for FCC naphtha deep hydrodesulfurization[J]. Petroleum Processing and Petrochemicals, 2007, 38(9): 28-31.)

    8. [8]

      [8] BRUNET S, MEY D, PEROT G, BOUCHY C, DIEHL F. On the hydrodesulfurization of FCC gasoline: A review[J]. Appl Catal A: Gen, 2005, 286(2): 143-172.

    9. [9]

      [9] DENNIS H. Process for the removal of mercaptans and hydrogen sulfide from hydrocarbon streams: US, 5510568. 1997-02-04.

    10. [10]

      [10] PODREBARAC G G, GILDERT G R. Process for sulfur reduction in naphtha streams: US, 6444118. 2002-09-03.

    11. [11]

      [11] DENNIS H, GILDERT G R. Process for removal of mercaptans from hydrocarbon streams: US, 6440299. 2002-08-27.

    12. [12]

      [12] ALEXIS A, GRIESBAUM K, WARREN A. Organic sulfur compounds. VIII. Addition of thiol to conjugated diolefins[J]. J Am Chem Soc, 1962, 84(20): 3897-3904.

    13. [13]

      [13] MARVEL C S, MARKHART A H. Polyalkylene sulfides. V. The rate of formation in emulsion[J]. J Am Chem Soc, 1951, 73(3): 1064-1065.

  • 加载中
    1. [1]

      Longfei MA , Fang SI , Congjie PAN , Xinhua WANG . Synthesis and crystal structure of extended tetrathiafulvalene derivatives and cupric bromide charge transfer complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1229-1236. doi: 10.11862/CJIC.20250355

    2. [2]

      Zhi Chai ,  Huashan Huang ,  Xukai Shi ,  Yujing Lan ,  Zhentao Yuan ,  Hong Yan . Wittig反应的立体选择性. University Chemistry, 2025, 40(8): 192-201. doi: 10.12461/PKU.DXHX202410046

    3. [3]

      Yilin Cui ,  Zhongfu Li ,  Weikun Zhang ,  Yu Gao ,  Zhichao Dong ,  Conghua Liu . Sulfur vacancies boosting C2H4 selectivity of 2D/2D In2.77S4/CuInS2 S-scheme heterojunction for CO2 photoreduction. Acta Physico-Chimica Sinica, 2026, 42(7): 100274-. doi: 10.1016/j.actphy.2026.100274

    4. [4]

      Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H2O2 synthesis via melamine-foam supported S-scheme Cd0.5Zn0.5In2S4/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093

    5. [5]

      Jinyao Du ,  Xingchao Zang ,  Ningning Xu ,  Yongjun Liu ,  Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039

    6. [6]

      Ting YANG , Jia AN , Jinyu ZHANG , Ruonan FAN , Rong YAN , Xiaoxia JING , Panpan CHANG , Wei YAN . Synergistic enhancement of ion migration and sulfur conversion kinetics in lithium-sulfur batteries by CeO2/g-C3N4. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 519-530. doi: 10.11862/CJIC.20250274

    7. [7]

      Tao Wang , Qin Dong , Cunpu Li , Zidong Wei . Sulfur Cathode Electrocatalysis in Lithium-Sulfur Batteries: A Comprehensive Understanding. Acta Physico-Chimica Sinica, 2024, 40(2): 2303061-0. doi: 10.3866/PKU.WHXB202303061

    8. [8]

      Junjie Zhang ,  Yue Wang ,  Qiuhan Wu ,  Ruquan Shen ,  Han Liu ,  Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

    9. [9]

      Yiming Liang ,  Ziyan Pan ,  Kin Shing Chan . One Drink, Two Tears in the Central Nervous System: The Perils of Disulfiram-Like Reactions. University Chemistry, 2025, 40(4): 322-325. doi: 10.12461/PKU.DXHX202406016

    10. [10]

      Guanghuan Chen ,  Yinghua Wang ,  Jinhui Ming ,  Jian Ling ,  Zhihui Shao ,  Chongdao Lu ,  Yong Shi . 香芹酮β硼化：一个可用于展示反应选择性的教学实验. University Chemistry, 2026, 41(5): 101-108. doi: 10.12461/PKU.DXHX202510042

    11. [11]

      Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO2. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153

    12. [12]

      Yujie WANG , Laobang WANG , Zheng ZHANG , Qi LIU , Jianping LANG . Construction of W/Cu/S cluster-based supramolecular compounds via alkynyl/sulfur cycloaddition and their third-order nonlinear optical properties. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2069-2077. doi: 10.11862/CJIC.20250129

    13. [13]

      Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . Surface Sulfur Species Influence Hydrogenation Performance of Palladium-Sulfur Nanosheets. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-0. doi: 10.3866/PKU.WHXB202309043

    14. [14]

      Haozhe Hu ,  Haoyu Zhang ,  Changsheng Lu . Study on the Precipitation Process of Elemental Sulfur from the Decomposition Products of Thiosulfuric Acid: Is It an Unexpected Failed Experiment?. University Chemistry, 2025, 40(11): 409-415. doi: 10.12461/PKU.DXHX202412034

    15. [15]

      Baitong Wei ,  Jinxin Guo ,  Xigong Liu ,  Rongxiu Zhu ,  Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003

    16. [16]

      Hongyao Li ,  Youyan Liu ,  Luwei Dai ,  Min Yang ,  Qihui Wang . The Blessing of Indium Sulfide：Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104

    17. [17]

      Yinuo Wang ,  Siran Wang ,  Yilong Zhao ,  Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063

    18. [18]

      Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015

    19. [19]

      Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441

    20. [20]

      Nan Xiao ,  Fang Sun . 二芳基硫醚化合物的构建及应用. University Chemistry, 2025, 40(6): 360-363. doi: 10.12461/PKU.DXHX202407099

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(678)
  • HTML views(11)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return