Citation: CONG Xing-shun, ZONG Zhi-min, ZHOU Yin, LI Min, ZHAO Yun-peng, FAN Xing, WEI Xian-yong. Enrichment and analysis of long-chain normal alkanals from Zhundong subbituminous coal[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(3): 257-261. shu

Enrichment and analysis of long-chain normal alkanals from Zhundong subbituminous coal

1.
1. Key Laboratory of Coal Processing and Efficient Utilization (Ministry of Education), China University of Mining & Technology, Xuzhou 221116, China;

Corresponding author: ZONG Zhi-min,
Received Date: 11 November 2013
Available Online: 3 January 2014
Fund Project: National Basic Research Program of China (973 Program, 2011CB201302) (973 Program, 2011CB201302) the Key Project of Natural Science Foundation of China (20936007) (20936007) the Fund from Natural Science Foundation of China for Innovative Research Group (51221462) (51221462) the Key Project of Coal Joint Fund from Natural Science Foundation of China and Shenhua Group Corporation Limited (51134021) (51134021) The Strategic Chinese-Japanese Joint Research Program (2013DFG60060) (2013DFG60060) National Natural Science Foundation of China (51074153) (51074153) National Natural Science Foundation of China for Young Researchers (21206187 and 21206188) (21206187 and 21206188)

Zhundong subbituminous coal was exhaustively extracted with isometric carbon disulfide (CDS) and acetone mixed solvent. The extract was fractionated with petroleum ether (PE) and CDS into PE-extractable portion (E₁) and CDS-extractable portion (E₂). E₂ was sequentially eluted with PE and 30% CDS/PE mixed solvent through a silica gel-packed column. A series of long-chain normal alkanals (LCNAs, C_18~27) were enriched from E₂ and identified with a gas chromatography/mass spectrometer. The fractional extraction and subsequent column chromatography provide an effective approach for enriching LCNAs from middle-and low-rank coals. LCNAs could be a class of important biomarkers.
- long-chain normal alkanals,
- Zhundong subbituminous coal,
- fractional extraction,
- column chromatography
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