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Citation: GAO Feng, LI Cun-mei, WANG Yuan, SUN Guo-hua, LI Kai-xi. Preparation of resin-base spherical activated carbon and study on adsorption properties towards CO2[J]. Journal of Fuel Chemistry and Technology, ;2014, 42(1): 116-120. shu

Preparation of resin-base spherical activated carbon and study on adsorption properties towards CO2

  • 1.

    1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China;

  • Corresponding author: SUN Guo-hua,  LI Kai-xi, 
  • Received Date: 7 April 2013
    Available Online: 3 June 2013

    Fund Project: 国家自然科学基金(51002166,51061130536) (51002166,51061130536)科技部国际合作项目(2010DFB90690-4) (2010DFB90690-4)山西省国际合作项目(2010081031-2,2013081016) (2010081031-2,2013081016)山西省科技创新项目(2012102007)。 (2012102007)

  • Resin-based spherical activated carbons were prepared from four kinds of ion exchange resin(two strong basic resins D201 and D280, two weak basic resins D301G and D301R)through sulfonation, carbonization and activation treatment. The yield of the spherical activated carbons, the surface morphology and the specific surface area were characterized by thermogravimetric analysis, scanning electron microscopy and nitrogen adsorption. The adsorptive capacities of the spherical activated carbons towards CO2 were investigated. The results showed that the yield of carbonized spheres was improved after sulfonation. The four prepared spherical activated carbon samples exhibited good adsorption performance to CO2. The strong basic resin-based spherical activated carbons provided a higher CO2 adsorption capacity than the weak basic resin-based spherical activated carbons. The CO2 adsorption capacity of the spherical activated carbons obtained from strong basic resin D201 reached 2.57 mmol/g, and remained high after ten cycles.
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    1. [1]

      [1] GODINI H R, MOWLA D. Selectivity study of H2S and CO2 absorption from gaseous mixtures by MEA in packed beds[J]. Chem Eng Res Des, 2008, 6(4): 401-409.

    2. [2]

      [2] PLAZA J M, WAGENER D V, ROCHELLE G T. Modeling CO2 capture with aqueous monoethanolamine[J]. Energy Procedia, 2009, 1(1): 1171-1178.

    3. [3]

      [3] Yang H Q, XU Z H, FAN M H, GUPTA R, SLIMANE R B, BLAND A E, WRIGHT I. Progress in carbon dioxide separation and capture: A review[J]. J Environ Sci, 2008, 20(1): 14-27.

    4. [4]

      [4] KAI T, KAZAMA S, FUJIOKA Y. Development of cesium-incorporated carbon membranes for CO2 separation under humid conditions[J]. J Membr Sci, 2009, 342(1/2): 14-21.

    5. [5]

      [5] 史晶金, 刘亚敏, 陈杰, 张瑜, 施耀. 氨基功能化SBA-16对CO2的动态吸附特性[J]. 物理化学学报, 2010, 26(11): 3023-3029. (SHI Jing-jin, LIU Ya-min, CHEN-Jie, ZHANG Yu, SHI Yao. Dynamic performance of CO2 adsorption with amine-modified SBA-16[J]. Acta Phys-Chim Sin, 2010, 26(11): 3023-3029.)

    6. [6]

      [6] 郑修新, 张晓云, 余青霓, 赵蓓. CO2吸收材料的研究进展[J]. 化工进展, 2012, 31(2): 360-366. (ZHENG Xiu-xin, ZHANG Xiao-yun, YU Qing-ni, ZHAO Bei. Progress in carbon dioxide absorption materials[J]. Chemical Industry and Engineering Progress, 2012, 31(2): 360-366.)

    7. [7]

      [7] YAMAGUCHI T, NⅡTSUMA T, NAIR B N, NAKAGAWA K. Lithium silicate based membranes for high temperature CO2 separation[J]. J Membr Sci, 2007, 294(1/2): 16-21.

    8. [8]

      [8] 张睿, 周贝, 段晓佳, 胡子君, 李俊宁, 金鸣林. 活性炭表面化学性质对二氧化碳吸附平衡的影响[J]. 煤炭转化, 2011, 34(4): 57-61. (ZHANG Rui, ZHOU Bei, DUAN Xiao-jia, HU Zi-jun, LI Jun-ning, JIN Ming-lin. Effect of surface chemistry of activated carbon on its equilibrium adsorption capacity for CO2[J]. Coal Conversion, 2011, 34(4): 57-61.)

    9. [9]

      [9] DÍAZ E, MUÑOZ E, VEGA A, ORDÓÑEZ S. Enhancement of the CO2 retention capacity of X zeolites by Na-and Cs-treatments[J]. Chemosphere, 2008, 70(8): 1375-1382.

    10. [10]

      [10] PEVIDA C, PLAZA M G, ARIAS B, FERMOSO J, RUBIERA F, PIS J J. Surface modification of activated carbons for CO2 capture[J]. Appl Surf Sci, 2008, 254(22): 7165-7172.

    11. [11]

      [11] GUO B, CHANG L P, XIE K C. Adsorption of carbon dioxide on activated carbon[J]. J Nat Gas Chem, 2006, 15(3): 223-229.

    12. [12]

      [12] 闻霞, 孙楠楠, 李碧, 李军平, 王峰, 赵宁, 肖福魁, 魏伟, 孙予罕, 任泽厚, 郭金刚, 王志杰, 李庆, 吴志斌. MgO/Al2O3 吸附剂对CO2 动态吸附性能的研究[J]. 燃料化学学报, 2010, 38(2): 247-251. (WEN Xia, SUN Nan-nan, LI Bi, LI Jun-ping, WANG Feng, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han, REN Ze-hou, GUO Jin-gang, WANG Zhi-jie, LI Qing, WU Zhi-bin. Dynamic adsorption study of CO2 adsorption by MgO/Al2O3[J].Journal of Fuel Chemistry and Technology, 2010, 38(2): 247-251.)

    13. [13]

      [13] 张学军, 刘生, 沈曾民. 制备工艺对球状活性炭结构与性能的影响[J]. 现代化工, 2006, 26(2): 150-153. (ZHANG Xue-jun, LIU Sheng, SHEN Zeng-min. Effect of preparing process on structure and property of spherical activated carbon[J]. Modern Chemical Industry, 2006, 26(2): 150-153.)

    14. [14]

      [14] 司崇殿, 郭庆杰.活性炭活化机理与再生研究进展[J]. 中国粉体技术, 2008, 14(5): 48-52. (SI Chong-dian, GUO Qing-jie. Progress research on activation mechanism and regeneration of activated carbon[J]. China Powder Science and Technology, 2008, 14(5): 48-52.)

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