Citation: MA Li-hai, ZHANG Jian-li, FAN Su-bing, ZHAO Tian-sheng. Preparation of Fe-Mn catalyst by hydrothermal method and its catalytic activity for the synthesis of light olefins from CO hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(11): 1356-1360. shu

Preparation of Fe-Mn catalyst by hydrothermal method and its catalytic activity for the synthesis of light olefins from CO hydrogenation

1.
State Key Laboratory Cultivation Base of Natural Gas Conversion, Ningxia University, Yinchuan 750021, China

Corresponding author: ZHANG Jian-li, ZHAO Tian-sheng,
Received Date: 28 February 2013
Available Online: 14 April 2013
Fund Project: 国家重点基础研究发展规划(973计划, 2012CB723106)。 (973计划, 2012CB723106)

A series of potassium modified Fe-Mn catalysts were prepared by hydrothermal method and applied to the catalytic synthesis of light olefins from CO hydrogenation. The catalyst samples were characterized by SEM, TEM, XRD, H₂-TPR and FT-IR techniques. Results showed that the prepared sample particles were spherical with 50~70 nm size and the carbonyl and hydroxy groups were observed on their surfaces. The bulk composition was mainly Fe₃O₄ before the reaction. Fe₅C₂ and MnCO₃ were formed after the reaction. The prepared samples showed high activity and olefin selectivity under the given reaction conditions. Using the sample S₃ (Fe:Mn:C₆:K=3:1:5:0.10), the CO conversion and the olefin productivity reached 95.02% and 62.86 g/m³ (H₂+CO), respectively. Compared with the catalyst prepared with co-precipitation method, the S₃ catalyst had lower CH₄ selectivity(13.88%) and CO₂ selectivity(13.98%).
- Fe-Mn catalyst,
- hydrothermal method,
- CO hydrogenation,
- light olefins
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沈阳化工大学材料科学与工程学院沈阳 110142