Advanced Search

Citation: ZHANG Guo-dong, YU Feng-wen, GAO Long-chao, WANG Wei-jin, LU Mei-zhen, JI Jian-bing. Pyrolysis of soybean oil with molten salt for bio-fuel[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(11): 1316-1321. shu

Pyrolysis of soybean oil with molten salt for bio-fuel

  • 1.

    Zhejiang Province Key Laboratory of Biofuel, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, China

  • Corresponding author: YU Feng-wen, 
  • Received Date: 25 March 2013
    Available Online: 4 May 2013

    Fund Project: 教育部博士点基金(20103317110001) (20103317110001)浙江省生物质能清洁利用创新团队自主设计项目(2009R50012)。 (2009R50012)

  • Pyrolysis of soybean oil was carried out in a ZnCl2-KCl molten salt. The effects of feed rate, flow rate of carrier gas, pyrolysis temperature and input quantity were studied. And the compositions of the bio-oil were analyzed by GC-MS. The results show that the feed rate and carrier gas flow rate have great influences on the pyrolysis by changing the reaction residence time of soybean oil. When the feed rate is 1.2 g/min and without the carrier gas, the soybean oil can be fully cracked with the longer residence time. The gasification of the primary pyrolysis products is enhanced with the increasing of temperature, which leads to the yield, the content of oxygenated compounds and the acid value of bio-oil increase. With the increasing of input quantity, the yield of bio-oil is near 70% and keeps stable, but the decarboxylation effect decreases. The properties of bio-oil are improved and its component distribution is similar to the 0# diesel after catalytic hydrogenation.
  • 加载中
    1. [1]

      [1] 赵檀, 张全国, 孙生波. 生物柴油的最新研究进展[J]. 化工技术与开发, 2011, 40(4): 22-26. (ZHAO Tan, ZHANG Quan-guo, SUN Sheng-bo. Research advances in biodiesel[J]. Technology & Development of Chemical Industry, 2011, 40(4): 22-26.)

    2. [2]

      [2] DEMIRBAS A. Progress and recent trends in biodiesel fuels[J]. Energy Convers Manage, 2009, 50(1): 14-34.

    3. [3]

      [3] SHAHID E M, JAMAL Y. Production of biodiesel: A technical review[J]. Renew Sust Energy Rev, 2011, 15(9): 4732-4745.

    4. [4]

      [4] 李梅, 吕鹏梅, 杨玲梅, 罗文, 王忠铭, 李惠文, 袁振宏. Fe-Ca磁性固体碱催化剂上菜籽油酯交换反应[J]. 燃料化学学报, 2012, 40(4): 405-411. (LI Mei, LU Peng-mei, YANG Ling-mei, LUO Wen, WANG Zhong-ming, LI Hui-wen, YUAN Zhen-hong. Magnetic Fe-Ca oxide as a solid base catalyst for transesterification of rapeseed oil to produce biodiesel[J]. Journal of Fuel Chemistry and Technology, 2012, 40(4): 405-411.)

    5. [5]

      [5] DEMIRBAS A. Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: A survey[J]. Energy Convers Manage, 2003, 44(13): 2093-2109.

    6. [6]

      [6] HOEKMAN S K, BROCH A, ROBBINS C, CENICEROS E, NATARAJAN M. Review of biodiesel composition, properties, and specifications[J]. Renew Sust Energy Rev, 2012, 16(1): 143-169.

    7. [7]

      [7] 李俊雄. 高酸价油脂制备生物柴油的研究[J]. 生物质化学工程, 2007, 41(6): 25-28. (LI Jun-xiong. Preparation of biodiesel from oils with high acid value[J]. Biomass Chemical Engineering, 2007, 41(6): 25-28.)

    8. [8]

      [8] WISNIEWSKI A JR, WIGGERS V R, SIMIONATTO E L, MEIER H F, BARROS A A C, MADUREIRA L A S. Biofuels from waste fish oil pyrolysis: Chemical composition[J]. Fuel, 2010, 89(3): 563-568.

    9. [9]

      [9] CHEW T L, BHATIA S. Effect of catalyst additives on the production of biofuels from palm oil cracking in a transport riser reactor[J]. Bioresour Technol, 2009, 100(9): 2540-2545.

    10. [10]

      [10] NGO T A, KIM J, KIM S K, KIM S S. Pyrolysis of soybean oil with H-ZSM5 (proton-exchange of zeolite socony mobil #5) and MCM41 (mobil composition of matter No. 41) catalysts in a fixed-bed reactor[J]. Energy, 2010, 35(6): 2723-2728.

    11. [11]

      [11] MBARAKA I K, SHANKS B H. Conversion of oils and fats using advanced mesoporous heterogeneous catalysts[J]. J Am Oil Chem Soc, 2006, 83(2): 79-91.

    12. [12]

      [12] 徐俊明, 蒋剑春, 陈洁, 卢言菊. 甘油三酯裂解制备可再生液体燃料油研究[J]. 燃料化学学报, 2010, 38(2): 178-182. (XU Jun-ming, JIANG Jian-chun, CHEN Jie, LU Yan-ju. Production of renewable liquid fuel from triglycerides[J]. Journal of Fuel Chemistry and Technology, 2010, 38(2): 178-182.)

    13. [13]

      [13] 姬登祥, 蔡腾跃, 艾宁, 于凤文, 姜洪涛, 计建炳. 熔盐热裂解生物质制生物油[J]. 生物工程学报, 2011, 27(3): 475-481. (JI Deng-xiang, CAI Teng-yue, AI Ning, YU Feng-wen, JIANG Hong-tao, JI Jian-bing. Bio-oil production from biomass pyrolysis in molten salt[J]. Chinese Journal of Biotechnology, 2011, 27(3): 475-481.)

    14. [14]

      [14] 吕红云, 于凤文, 唐强, 计建炳. 熔融盐裂解木焦油的初步研究[J]. 林产化学与工业, 2012, 32(4): 53-57. (LU Hong-yun, YU Feng-wen,TANG Qiang, JI Jian-bing. Preliminary study on pyrolysis of wood tar in molten salt media[J]. Chemistry and Industry of Forest Products, 2012, 32(4): 53-57.)

    15. [15]

      [15] CSUKAS B, VARGA M, MISKOLCZI N, BALOGH S, ANGYAL A, BARTHA L. Simplified dynamic simulation model of plastic waste pyrolysis in laboratory and pilot scale tubular reactor[J]. Fuel Process Technol, 2013, 106: 186-200.

    16. [16]

      [16] 徐俊明, 戴伟娣, 许玉, 蒋剑春. 稻壳快速热解制备生物油条件探索及产物分析[J]. 生物质化学工程, 2011, 45(4): 23-26. (XU Jun-ming, DAI Wei-di, XU Yu, JIANG Jian-chun. Conditions of rice husk fast pyrolysis in fluidized bed and its product analysis[J]. Biomass Chemical Engineering, 2011, 45(4): 23-26.)

    17. [17]

      [17] HEW K L, TAMIDI A M, YUSUP S, LEE K T, AHMAD M M. Catalytic cracking of bio-oil to organic liquid product (OLP)[J]. Bioresour Technol, 2010, 101(22): 8855-8858.

    18. [18]

      [18] LUO YAN, AHMED I, KUBÁTOVÁ A, Š ĪÁVOVÁ J, AULICH T, SADRAMELI S M, SEAMES W S. The thermal cracking of soybean/canola oils and their methyl esters[J]. Fuel Process Technol, 2010, 91(6): 613-617.

    19. [19]

      [19] 尤占平, 由世俊, 李宪莉, 郝长生. 焦永刚生物质炭催化裂解焦油的实验研究[J]. 太阳能学报, 2011, 32(5): 718-723. (YOU Zhan-ping, YOU Shi-jun, LI Xian-li, HAO Chang-sheng, JIAO Yong-gang. Experimental research on tar catalytic cracking[J]. Acta Energiae Solaris Sinica, 2011, 32(5): 718-723.)

    20. [20]

      [20] 王艳秋, 金万祥, 宗志敏, 金鑫, 魏贤勇, 赵锁奇, 鲍晓军. 活性炭对大港减压渣油超临界萃取残渣的催化加氢[J]. 河北师范大学学报(自然科学版), 2009, 33(3): 352-356. (WANG Yan-qiu, JIN Wan-xiang, ZONG Zhi-min, JIN-Xin, WEI Xian-yong, ZHAO Suo-qi, BAO Xiao-jun. Catalytic hydroconversion of the draff from supercriticai fluid extraction of dagang vacuum residue with active carbon[J]. Journal of He bei Normal University (Natural Science Edition), 2009, 33(3): 352-356.

    21. [21]

      [21] KUBÁTOVÁ A, LUO Y, ŠTÁVOVÁ J, SADRAMELI S M, AULICH T, KOZLIAK E, SEAMES W. New path in the thermal cracking of triacylglycerols (canola and soybean oil)[J]. Fuel, 2011, 90(8): 2598-2608.

    22. [22]

      [22] 商宜美, 柴忠义, 纪玉国, 栗同林, 李建伟. 新型介孔Ni/TiO2-A12O3催化剂的表征及其用于选择加氢反应[J]. 石油化工, 2011, 40(11): 1177-1183. (SHANG Yi-mei, CHAI Zhong-yi, JI Yu-guo, LI Tong-lin, LI Jian-wei. Characterization of a new mesoporous Ni/TiO2-A12O3 catalyst and its application in selective hydrogenation[J]. Petrochemical Technology, 2011, 40(11): 1177-1183.)

  • 加载中
    1. [1]

      Hailian Tang ,  Siyuan Chen ,  Qiaoyun Liu ,  Guoyi Bai ,  Botao Qiao ,  Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004

    2. [2]

      Yu Wang ,  Shoulei Zhang ,  Tianming Lv ,  Yan Su ,  Xianyu Liu ,  Fuping Tian ,  Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035

    3. [3]

      Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356

    4. [4]

      Jiaxin Su ,  Jiaqi Zhang ,  Shuming Chai ,  Yankun Wang ,  Sibo Wang ,  Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012

    5. [5]

      Jinghua Wang ,  Yanxin Yu ,  Yanbiao Ren ,  Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057

    6. [6]

      Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO2 hydrogenation over a Mg-doped In2O3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

    7. [7]

      Weihan Zhang ,  Menglu Wang ,  Ankang Jia ,  Wei Deng ,  Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043

    8. [8]

      Liuyun Chen ,  Wenju Wang ,  Tairong Lu ,  Xuan Luo ,  Xinling Xie ,  Kelin Huang ,  Shanli Qin ,  Tongming Su ,  Zuzeng Qin ,  Hongbing Ji . Soft template-induced deep pore structure of Cu/Al2O3 for promoting plasma-catalyzed CO2 hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054

    9. [9]

      Xiao Liu ,  Guangzhong Cao ,  Mingli Gao ,  Hong Wu ,  Hongyan Feng ,  Chenxiao Jiang ,  Tongwen Xu . Seawater Salinity Gradient Energy’s Job Application in the Field of Membranes. University Chemistry, 2024, 39(9): 279-282. doi: 10.3866/PKU.DXHX202306043

    10. [10]

      Chengqian Mao ,  Yanghan Chen ,  Haotong Bai ,  Junru Huang ,  Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014

    11. [11]

      Xinhao Yan ,  Guoliang Hu ,  Ruixi Chen ,  Hongyu Liu ,  Qizhi Yao ,  Jiao Li ,  Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073

    12. [12]

      Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360

    13. [13]

      Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(603)
  • HTML views(97)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return