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Citation: HONG Chun-yan, LI Min, LIU Jia-xiang. Preparation of Pt/Au/Fe3O4 nanocomposites and their electrocatalytic activities in methanol oxidation[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1108-1114. shu

Preparation of Pt/Au/Fe3O4 nanocomposites and their electrocatalytic activities in methanol oxidation

  • 1.

    College of Materials Science and Engineering, the Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China

  • Corresponding author: LIU Jia-xiang, 
  • Received Date: 23 December 2012
    Available Online: 11 April 2013

  • Pt/Au/Fe3O4 nanocomposites were prepared by the continuous reduction method, through loading Pt and Au on the surface of nano Fe3O4. The Pt/Au/Fe3O4 nanocomposites were characterized by UV-vis spectra, transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectrometer (XPS); their electrocatalytic activities in methanol oxidation were investigated. The results indicated that Au and Pt are uniformly deposited on Fe3O4 surface. The cyclic voltammograms of Pt/Au/Fe3O4 suggests that the best catalytic performance is achieved when the amount of H2PtCl6 added is 8 mL. Current peak ip is proportional to the square root of scanning speed (v1/2) and the catalytic methanol oxidation process is under the control of diffusion. The Pt/Au/Fe3O4 nanocomposites remain high active during the measurements of cyclic voltammograms for 201 times, suggesting that Pt/Au/Fe3O4 is a kind of anode catalyst materials with high chemical activity and stability.
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    1. [1]

      [1] CHEREVKO S, KULYK N, CHUNG C H. Nanoporous Pt@AuxCu100-x by hydrogen evolution assisted electrodeposition of AuxCu100-x and galvanic replacement of Cu with Pt: Electrocatalytic properties[J]. Langmuir, 2012, 28(6): 3306-3315.

    2. [2]

      [2] IRISSOU E, LAPLANTE F, GARBARINO S, CHAKER M, GUAY D. Structural and electrochemical characterization of metastable PtAu bulk and surface alloys prepared by crossed-beam pulsed laser deposition[J]. J Phys Chem C, 2010, 114(5): 2192-2199.

    3. [3]

      [3] ZHANG X, ZHANG F, CHAN K Y. Preparation of Pt-Ru-Co trimetallic nanoparticles and their electrocatalytic properties[J]. Catal Commun, 2004, 5(12): 749-753.

    4. [4]

      [4] CHO Y H, JEON T Y, YOO S J, LEE K S, AHN M, KIM O H, CHO Y H, LIM J W, JUNG N, YOON W S, CHOE H, SUNG Y E. Stability characteristics of Pt1Ni1/C as cathode catalysts in membrane electrode assembly of polymer electrolyte membrane fuel cell[J]. Electrochim Acta, 2012, 59: 264-269.

    5. [5]

      [5] 刘丹丹, 邬冰, 高颖. 碳载Pt-Ni催化剂对直接甲醇燃料电池阴极氧电还原性能的影响[J]. 燃料化学学报, 2010, 38(3): 370-373. (LIU Dan-dan, WU Bin, GAO Ying. Effect of carbon supported Pt-Ni catalysts on oxygen reduction for direct methanol fuel cell[J]. Journal of Fuel Chemistry and Technology, 2010, 38(3): 370-373.)

    6. [6]

      [6] ZHONG W, LIU Y, ZHANG D. Theoretical study of methanol oxidation on the PtAu(111) bimetallic surface: CO pathway vs non-CO pathway[J]. J Phys Chem C, 2012, 116(4): 2994-3000.

    7. [7]

      [7] FENG R J, LI M, LIU J X. Preparation and catalytic activity of CO-resistant catalyst core-shell Au@Pt/C for methanol oxidation[J]. Rare Metals, 2012, 31(5): 451-456.

    8. [8]

      [8] LI J, REN J, YANG G, WANG P, LI H, SUN X, CHEN L, MA J T, LI R. Simple and efficient deposition of Pd nanoparticles on Fe3O4 hollow nanospheres: A new catalytic system for methanol oxidation in alkaline media[J]. Mater Sci Eng, 2010, 172(3): 207-212.

    9. [9]

      [9] JIA J, WANG R, WANG H, JI S, KEY J, LINKOV V, SHI K, LEI Z. A novel structural design of CNx-Fe3O4 as support to immobilize Pd for catalytic oxidation of formic acid[J]. Catal Commun, 2011, 16(1): 60-63.

    10. [10]

      [10] LUO J, WANG L, MOTT D, NJOKI P N, LIN Y, HE T, XU Z, WANJANA B N, LIM I I S, ZHONG C J. Core/shell nanoparticles as electrocatalysts for fuel cell reactions[J]. Adv Mater, 2008, 20(22): 4342-4347.

    11. [11]

      [11] DUFF D G, BAIKER A. A new hydrosol of gold clusters. 1. Formation and particle size variation[J]. Langmuir, 1993, 9(9): 2301-2309.

    12. [12]

      [12] WANJALA B N, LUO J, LOUKRAKPAM R, FANG B, MOTT D, NJOKI P N, ENGELHARD M, NASLUND H R, WU J K, WANG L, MALIS O, ZHONG C J. Nanoscale alloying, phase-segregation, and core-shell evolution of gold-platinum nanoparticles and their electrocatalytic effect on oxygen reduction reaction[J]. Chem Mater, 2010, 22(14): 4282-4294.

    13. [13]

      [13] VEL ZQUEZ-PALENZUELA A, CENTELLAS F, GARRIDO J A, ARIAS C, RODR GUEZ R M, BRILLAS E, CABOT P L. Kinetic analysis of carbon monoxide and methanol oxidation on high performance carbon-supported Pt-Ru electrocatalyst for direct methanol fuel cells[J]. J Power Sources, 2011, 196(7): 3503-3512.

    14. [14]

      [14] GENNERO DE CHIALVO M R, CHIALVO A C. Recent progress in the kinetics of the hydrogen electrode reaction in steady state[J]. Curr Top Electrochem, 2006, 11:1-11.

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