Citation: ZHANG Hai-yong, WANG Yong-gang, ZHANG Pei-zhong, LIN Xiong-chao, ZHU Yu-fei. Preparation of NiW catalysts with alumina and zeolite Y for hydroprocessing of coal tar[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(9): 1085-1091. shu

Preparation of NiW catalysts with alumina and zeolite Y for hydroprocessing of coal tar

1.
1. School of Chemical and Environmental Engineering, China University of Mining &Technology (Beijing), Beijing 100083, China;

Corresponding author: WANG Yong-gang,
Received Date: 27 April 2013
Available Online: 18 June 2013
Fund Project: National Natural Science Foundation of China (U1261213) (U1261213)the National High-Tech R&D Program of China (863 Program, 2011AA05A203). (863 Program, 2011AA05A203)

γ-alumina supported Ni-W catalysts with different zeolite Y contents were prepared and characterized by N₂ sorption, XRD, H₂-TPR and NH₃-TPD. Their catalytic activities were investigated on a trickle bed reactor by hydroprocessing cresol-naphthalene model compounds in n-heptane solution. The results show that all the catalysts exhibit excellent hydrodeoxygenation and hydrogenation activities, while the isomerization and ring-opening products increase with the addition of zeolite, and trans-decalin is preferred with acid sites. A better catalyst was selected for hydroprocessing a low temperature coal tar fraction and the product oil was analyzed by GC-MS and elementary analysis. Phenols and di-aromatics in the tar are almost converted into indans, cycloalkanes and hydro-aromatics. In the meantime, heteroatoms, especially S and O atoms, reduce remarkably.
- low temperature coal tar,
- hydroprocessing,
- catalyst,
- zeolite
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