Citation:
QU Cheng-rui, XU Bin, WU Jian, LIU Jian-xin, WANG Xue-tao. Effect of limestone addition on PM2.5 formation during fluidized bed coal combustion under O2/CO2 atmosphere[J]. Journal of Fuel Chemistry and Technology,
;2013, 41(8): 1020-1024.
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The effect of limestone addition on the emission characteristics of PM2.5 (particulates with aerodynamic diameter less than 2.5 μm) was studied in a fluidized bed combustor. The combustion tests were carried out at 1 123 K under O2/CO2 atmosphere. The PM2.5 generated from coal combustion was collected and analyzed with an Electrical Low Pressure Impactor (ELPI). The results indicate that limestone has a great effect on the formation of PM2.5 during coal combustion under O2/CO2 atmosphere. The concentration of PM1.0 is diminished; but the concentration of PM1.0~2.5 is enhanced slightly with the addition of limestone. The mass size distribution of PM2.5 is similar, which displays two peaks around 0.2 and 2.0 μm, respectively. As the molar ratio of Ca/S increases, the concentrations of Si, Na, K, S, and Cu decrease. As the particle size decreases, the concentrations of S, Cu, K, and Na increase, but the concentrations of Si decrease.
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Keywords:
- O2/CO2,
- coal combustion,
- PM2.5,
- fluidized bed,
- limestone
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[1]
[1] LINAK W P, YOO J I, WASSON S J, ZHU W Y, WENDT J O L, HUGGINS F E, CHEN Y Z, SHAH N, HUFFMAN G P, GILMOUR M I. Ultrafine ash aerosols from coal combustion: Characterization and health effects[J]. P Combust Inst, 2007, 31(2): 1929-1937.
-
[2]
[2] WANG Q Y, ZHANG L, SATO A, NINOMIYA Y, YAMASHITA T. Effects of coal blending on the reduction of PM(10) during high-temperature combustion 2. A coalescence-fragmentation model[J]. Fuel, 2009, 88(1): 150-157.
-
[3]
[3] WANG S Z, BAXTER L, FONSECA F. Biomass fly ash in concrete: SEM, EDX and ESEM analysis[J]. Fuel, 2008, 87(2): 372-379.
-
[4]
[4] BUHRE B J P, HINKLEY J T, GUPTA R P, NELSON P F, WALL T F. Fine ash formation during combustion of pulverized coal-coal property impacts[J]. Fuel, 2006, 85(2): 185-193.
-
[5]
[5] YU Y, XU M H, YAO H, YU D X, QIAO Y, SUI J C, LIU X W, CAO Q. Char characteristics and particulate matter formation during Chinese bituminous coal combustion[J]. P Combust Inst, 2007, 31(2): 1947-1954.
-
[6]
[6] CHEN Y Z, NARESH S, HUGGINS F E. Investigation of primary fine particulate matter from coal combustion by computer-controlled scanning electron microscopy[J]. Fuel Process Technol, 2004, 85(6-7): 743-761.
-
[7]
[7] 吕建燚, 李晶欣. 煤粉物化特性对燃烧后灰颗粒物的影响[J]. 燃料化学学报, 2011, 39(6): 419-424. (Lü Jian-yi, Li Jing-xing. Influence of coal physicochemical properties on ash particulate matter after coal combustion[J]. Journal of Fuel Chemistry and Technology, 2011, 39(6): 419-424.)
-
[8]
[8] 朱建航, 胡勤海, 陈菊芬, 张辉, 刘建忠, 岑可法. 污泥水煤浆燃烧和污染排放特性研究[J]. 燃料化学学报, 2012, 40(2): 252-256. (ZHU Jian-hang, HU Qin-hai, CHEN Ju-fen, ZHANG hui, LIU Jian-zhong, CEN Ke-fa. Combustion of sludge coal water slurry and emission property of contaminants[J]. Journal of Fuel Chemistry and Technology, 2012, 40(2): 252-256.)
-
[9]
[9] BUHRE B J P, HINKLEY J T, GUPTA R P, WALL T F, LSON P F. Submicron ash formation from coal combustion[J]. Fuel, 2005, 84(10): 1206-1214.
-
[10]
[10] XU M H, YU D X, YAO H, LIU X W, QIAO Y. Coal combustion-generated aerosols: Formation and properties[J]. P Combust Inst, 2011, 33(1): 1681-1697.
-
[11]
[11] SHENG C D, LU Y H, GAO X P, YAO H. Fine ash formation during pulverized coal combustions-a comparison of O2/CO2 combustion versus air combustion[J]. Energy Fuels, 2007, 21(2): 435-440.
-
[12]
[12] LINAK W P, SRIVASTAVA R K, WENDT J O L. Sorbent capture of nickel, lead and cadmium in a laboratory swirl flame incinerator[J]. Combust Flame, 1994, 100(1-2): 241-250.
-
[13]
[13] MORRIS W J, YU D X, WENDT J O L. Soot, unburned carbon and ultrafine particle emissions from air- and oxy-coal flames[J]. P Combust Inst, 2011, 33(2): 3415-3421.
-
[14]
[14] FRYDA L, SOBRINO C, GLAZER M. Study of ash deposition during coal combustion under oxyfuel conditions[J]. Fuel, 2012, 92(1): 308-317.
-
[15]
[15] 王春波, 雷鸣, 阎维平, 王松岭. 煤粉的增压富氧燃烧特性及煤灰矿物演变[J]. 燃料化学学报, 2012, 40(7): 790-794. (WANG Chun-bo, LEI Ming, YAN Wei-ping, WANG Song-ling. Combustion characteristics of pulverized coal and mineral conversion under pressurized oxy-fuel condition[J]. Journal of Fuel Chemistry and Technology, 2012, 40(7): 790-794.)
-
[1]
-
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