Citation: WU Hong-xiang, LI Hai-bin, FENG Yi-peng, WANG Xiao-bo, ZHAO Zeng-li, HE Fang. Effects of potassium on the pyrolysis of biomass components by TG-FTIR analysis[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(8): 950-957. shu

Effects of potassium on the pyrolysis of biomass components by TG-FTIR analysis

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Key Laboratory of Renewable Energye, The New and Renewable Energy Key Laboratory of Guangdong Province, Guangzhou Institute of Energy Conversion, CAS, Guangzhou 510640, China

Corresponding author: LI Hai-bin,
Received Date: 9 June 2013
Available Online: 27 June 2013
Fund Project: 国家重点基础研究发展规划(973计划, 2011CB201500) (973计划, 2011CB201500) 中国科学院可再生能源与天然气水合物重点实验室基金(y307j81001) . (y307j81001)

The pyrolysis of K₂CO₃-impregnated hemicelluloses, cellulose, lignin and pine was investigated by TG-FTIR to assess the influence of potassium on the pyrolysis mechanisms of the main components of biomass. The results show that the pyrolysis temperature range of hemicelluloses, cellulose and lignin is 200~350 ℃, 300~365 ℃,200~600 ℃, respectively. CO and CO₂ are mainly produced during hemicellulose pyrolysis, and levoglucosan and carbonyl group are mainly produced during cellulose pyrolysis, while solid product is the main product for lignin pyrolysis. The pyrolysis of the mixture of three components reveals that there are interactions among biomass components. Potassium could catalyze the pyrolysis process of hemicelluloses and cellulose, lower the pyrolysis temperature, and increase the char yields. Potassium influences the pyrolysis of cellulose most obviously, leading to a marked increase in the yields of CO, CO₂ and solid product, and a decrease in carbonyl compound yield. However, potassium has little effect on the char yield of lignin, and the catalysis of potassium for the pyrolysis of mixture weakens.
- biomass,
- pyrolysis,
- components,
- potassium,
- TG-FTIR analysis
1. [1]
  [1] MCKENDRY P. Energy production from biomass (Part I): Overview of biomass[J]. Bioresour Technol, 2002, 83(1): 37-46.
2. [2]
  [2] WORASUWANNARAK N, SONOBE T, TANTHAPANICHAKOON W. Pyrolysis behaviors of rice straw, rice husk, and corncob by TG–MS technique[J]. J Anal Appl Pyrol, 2007, 78(2): 265-271.
3. [3]
  [3] HOSOYA T, KAWAMOTO H, SAKA S. Pyrolysis behaviors of wood and its constituent polymers at gasification temperature[J]. J Anal Appl Pyrol, 2007, 78(2): 328-336.
4. [4]
  [4] VAN DE VELDEN M, BAEYENS J, BREMS A, JANSSENS B, DEWIL R. Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction[J]. Renew Energy, 2010, 35(1): 232-242.
5. [5]
  [5] DEMIRBAS A. Effects of temperature and particle size on bio-char yield from pyrolysis of agricultural residues[J]. J Anal Appl Pyrol, 2004, 72(2): 243-248.
6. [6]
  [6] FAHMI R, BRIDGWATER AV, DARVELL L I, JONES J M, YATES N, THAIN S, DONNISON I S. The effect of alkali metals on combustion and pyrolysis of Lolium and Festuca grasses, switchgrass and willow[J]. Fuel, 2007, 86(10/11): 1560-1569.
7. [7]
  [7] SHIMADA N, KAWAMOTO H, SAKA S. Different action of alkali/alkaline earth metal chlorides on cellulose pyrolysis[J]. J Anal Appl Pyrol, 2008, 81(1): 80-87.
8. [8]
  [8] NIK-AZAR M, HAJALIGOL M R, SOHRABI M, DABIR B. Mineral matter effects in rapid pyrolysis of beech wood[J]. Fuel Process Technol, 1997, 51(1/2): 7-17.
9. [9]
  [9] PUSHKARAJ P R, SATRIO J A, BROWN R C, SHANKS B H. Influence of inorganic salts on the primary pyrolysis products of cellulose[J]. Bioresour Technol, 2010, 101(12): 4646-4655.
10. [10]
  [10] NOWAKOWSKI D J, JONES J M. Uncatalysed and potassium-catalysed pyrolysis of the cell-wall constituents of biomass and their model compounds[J]. J Anal Appl Pyrol, 2008, 83(1): 12-25.
11. [11]
  [11] COLLARD F X, BLIN J, BENSAKHRIA A, VALETTE J. Influence of impregnated metal on the pyrolysis conversion of biomass constituents[J]. J Anal Appl Pyrol, 2012, 95: 213-226.
12. [12]
  [12] 武宏香, 赵增立, 张伟, 李海滨, 何方. 碱/碱土金属对纤维素热解特性的影响[J]. 农业工程学报, 2012, 28(4): 215-220. (WU Hong-xiang, ZHAO Zeng-li, ZHANG Wei, LI Hai-bin, HE Fang. Effects of alkali/alkaline earth metals on pyrolysis characteristics of cellulose[J]. Transactions of the CSAE, 2012, 28(4): 215-220.)
13. [13]
  [13] 郑安庆, 赵增立, 江洪明, 张伟, 常胜, 吴文强, 李海滨. 松木预处理温度对生物油特性的影响[J]. 燃料化学学报, 2012, 40(1): 29-36. (ZHENG An-qing, ZHAO Zeng-li, JIANG Hong-ming, ZHANG Wei, CHANG Sheng, WU Wen-qing, LI Hai-bin. Effect of pretreatment temperature of pine on bio-oil characteristics[J]. Journal of Fuel Chemistry and Technology, 2012, 40(1): 29-36.)
14. [14]
  [14] ALN R, KUOPPALA E, OESCH P. Formation of the main degradation compound groups from wood and its components during pyrolysis[J]. J Anal Appl Pyrol, 1996, 36(2): 137-148.
15. [15]
  [15] AZEEZ A M, MEIER D, ODERMATT J. Temperature dependence of fast pyrolysis volatile products from European and African biomasses[J]. J Anal Appl Pyrol, 2011, 90(2): 81-92.
16. [16]
  [16] SHEN D K, GU S. The mechanism for thermal decomposition of cellulose and its main products[J]. Bioresour Technol, 2009, 100(24): 6496-6504.
17. [17]
  [17] SHEN D K, GU S, BRIDGWATER A V. Study on the pyrolytic behaviour of xylan based hemicellulose using TG–FTIR and Py-GC-FTIR[J]. J Anal Appl Pyrol, 2010, 87(2): 199-206.
18. [18]
  [18] LIU Q, ZHONG Z P, WANG S R, LUO Z Y. Interactions of biomass components during pyrolysis: A TG-FTIR study[J]. J Anal Appl Pyrol, 2011, 90(2): 213-218.
19. [19]
  [19] 王树荣, 廖艳芬, 文丽华, 骆仲泱, 岑可法. 钾盐催化纤维素快速热裂解机理研究[J]. 燃料化学学报, 2004, 32(6): 694-698. (WANG Shu-rong, LIAO Yan-fen, WEN Li-hua, LUO Zhong-yang, CEN Ke-fa. Catalysis mechanism of potassium salt during rapid pyrolysis of cellulose[J]. Journal of Fuel Chemistry and Technology, 2004, 32(6): 694-698.)
20. [20]
  [20] 刘军利, 蒋剑春, 黄海涛. 纤维素CP-GC-MS法裂解行为研究[J]. 林产化学与工业, 2009, 29(5): 47-53. (LIU Jun-li, JIABG Jian-chun, HUANG Hai-tao. Study of thermal transformations of cellulose under curie-point pyrolysis-GC-MS conditions[J]. Chemistry and Industry of Forest Products, 2009, 29(5): 47-53.)
21. [21]
  [21] MAYER Z A, APFELBACHER A, HORNUNG A. A comparative study on the pyrolysis of metal- and ash-enriched wood and the combustion properties of the gained char[J]. J Anal Appl Pyrol, 2012, 96: 196-202.
22. [22]
  [22] HOSOYA T, KAWAMOTO H, SAKA S. Secondary reactions of lignin-derived primarytar components[J]. J Anal Appl Pyrol, 2008, 83(1): 78-87.
23. [23]
  [23] LI S, LYONS-HART J, BANYASZ J, SHAFER K. Real-time evolved gas analysis by FTIR method: An experimental study of cellulose pyrolysis[J]. Fuel, 2001, 80(12): 1809-1817.
24. [24]
  [24] PAPPA A, MIKEDI K, TZAMTZIS N, STATHEROPOULOS M. Chemometric methods for studying the effects of chemicals on cellulose pyrolysis by thermogravimetry-mass spectrometry[J]. J Anal Appl Pyrol, 2003, 67(2): 221-235.
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沈阳化工大学材料科学与工程学院沈阳 110142