
Citation: QIN Yu-cai, GAO Xiong-hou, PEI Ting-ting, ZHENG Lan-ge, WANG Lin, MO Zhou-sheng, SONG Li-juan. Adsorption and catalytic conversion of thiophene on Y-type zeolites modified with rare-earth metal ions[J]. Journal of Fuel Chemistry and Technology, 2013, 41(7): 889-896.

噻吩在稀土离子改性Y型分子筛上吸附与催化转化研究
English
Adsorption and catalytic conversion of thiophene on Y-type zeolites modified with rare-earth metal ions
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Key words:
- thiophene
- / REY
- / adsorption
- / hydrogen transfer
- / catalytic cracking
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[1] BABICH I V, MOULIJN J A. Science and technology of novel processes for deep desulfurization of oil refinery streams: A review[J]. Fuel, 2003, 82(6): 607-631.[1] BABICH I V, MOULIJN J A. Science and technology of novel processes for deep desulfurization of oil refinery streams: A review[J]. Fuel, 2003, 82(6): 607-631.
-
[2] SONG C. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel[J]. Catal Today, 2003, 86(1): 211-263.[2] SONG C. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel[J]. Catal Today, 2003, 86(1): 211-263.
-
[3] HERNÁNDEZ-MALDONADO A J, YANG R T. Desulfurization of transportation fuels by adsorption[J]. Catal Rev, 2004, 46(2): 111-150.[3] HERNÁNDEZ-MALDONADO A J, YANG R T. Desulfurization of transportation fuels by adsorption[J]. Catal Rev, 2004, 46(2): 111-150.
-
[4] LAPPAS A A, VALLA J A, VASALOS I A, KUEHLER C, FRANCIS J, OSymbolbB@CONNOR P, GUDDE N J. The effect of catalyst properties on the in situ reduction of sulfur in FCC gasoline[J]. Appl Catal A: Gen, 2004, 262(1): 31-41.[4] LAPPAS A A, VALLA J A, VASALOS I A, KUEHLER C, FRANCIS J, OSymbolbB@CONNOR P, GUDDE N J. The effect of catalyst properties on the in situ reduction of sulfur in FCC gasoline[J]. Appl Catal A: Gen, 2004, 262(1): 31-41.
-
[5] 冯辉, 曾勇平, 居沈贵. 载铜5A 分子筛在汽油模拟体系中脱硫性能的研究[J]. 燃料化学学报, 2006, 34(1):117-119. (FENG Hui, ZENG Yong-ping, JU Shen-gui. Desulfurization of model gasoline by 5A molecular sieves loded with Cu2+[J]. Journal of Fuel Chemistry and Technology, 2006, 34(1):117-119)[5] 冯辉, 曾勇平, 居沈贵. 载铜5A 分子筛在汽油模拟体系中脱硫性能的研究[J]. 燃料化学学报, 2006, 34(1):117-119. (FENG Hui, ZENG Yong-ping, JU Shen-gui. Desulfurization of model gasoline by 5A molecular sieves loded with Cu2+[J]. Journal of Fuel Chemistry and Technology, 2006, 34(1):117-119)
-
[6] PANG X M, ZHANG L, SUN S H, LIU T, GAO X H. Effects of metal modifications of Y zeolites on sulfur reduction performance in fluid catalytic cracking process[J]. Catal Today, 2007, 125(3): 173-177.[6] PANG X M, ZHANG L, SUN S H, LIU T, GAO X H. Effects of metal modifications of Y zeolites on sulfur reduction performance in fluid catalytic cracking process[J]. Catal Today, 2007, 125(3): 173-177.
-
[7] WEN Y S, WANG G, XU C M, GAO J S. Study on in situ sulfur removal from gasoline in fluid catalytic cracking process[J]. Energy Fuels, 2012, 26(6): 3201-3211.[7] WEN Y S, WANG G, XU C M, GAO J S. Study on in situ sulfur removal from gasoline in fluid catalytic cracking process[J]. Energy Fuels, 2012, 26(6): 3201-3211.
-
[8] VELU S, MA X, SONG C. Selective adsorption for removing sulfur from jet fuel over zeolite-based adsorbents[J]. Ind Eng Chem Res, 2003, 42(21): 5293-5304.[8] VELU S, MA X, SONG C. Selective adsorption for removing sulfur from jet fuel over zeolite-based adsorbents[J]. Ind Eng Chem Res, 2003, 42(21): 5293-5304.
-
[9] XUE M, CHITRAKAR R, SAKANE K, HIROTSU T, OOI K, YOSHIMURA Y, FENG Q, SUMIDA N. Selective adsorption of thiophene and 1-benzothiophene on metal-ion-exchanged zeolites in organic medium[J]. J Colloid Interface Sci, 2005, 285(2): 487-492.[9] XUE M, CHITRAKAR R, SAKANE K, HIROTSU T, OOI K, YOSHIMURA Y, FENG Q, SUMIDA N. Selective adsorption of thiophene and 1-benzothiophene on metal-ion-exchanged zeolites in organic medium[J]. J Colloid Interface Sci, 2005, 285(2): 487-492.
-
[10] XUE M, CHITRAKAR R, SAKANE K, HIROTSU T, OOI K, YOSHIMURA Y, TOBA M, FENG Q. Preparation of cerium-loaded Y-zeolites for removal of organic sulfur compounds from hydrodesulfurizated gasoline and diesel oil[J]. J Colloid Interface Sci, 2006, 298(2): 535-542.[10] XUE M, CHITRAKAR R, SAKANE K, HIROTSU T, OOI K, YOSHIMURA Y, TOBA M, FENG Q. Preparation of cerium-loaded Y-zeolites for removal of organic sulfur compounds from hydrodesulfurizated gasoline and diesel oil[J]. J Colloid Interface Sci, 2006, 298(2): 535-542.
-
[11] WANG H G, SONG L J, JIANG H, JING X, JIN L L, ZHANG X T, SUN Z L. Effects of olefin dsorptive desulfurization of gasoline over Ce (IV) Y zeolites[J]. Fuel Process Technol, 2009, 90(6): 835-838.[11] WANG H G, SONG L J, JIANG H, JING X, JIN L L, ZHANG X T, SUN Z L. Effects of olefin dsorptive desulfurization of gasoline over Ce (IV) Y zeolites[J]. Fuel Process Technol, 2009, 90(6): 835-838.
-
[12] 王旺银,潘明雪, 秦玉才,王凌涛, 宋丽娟. Cu(I)Y分子筛表面酸性对其吸附脱硫性能的影响[J]. 物理化学学报,2011, 27(5):1176-1180. (WANG Wang-yin, PAN Ming-xue, QIN Yu-cai, WANG Ling-tao, SONG Li-juan. Effects of Surface acidity on the adsorption desulfurization of Cu(I)Y zeolites[J]. Acta Physico-Chimica Sinica, 2011, 27(5): 1176-1180.)[12] 王旺银,潘明雪, 秦玉才,王凌涛, 宋丽娟. Cu(I)Y分子筛表面酸性对其吸附脱硫性能的影响[J]. 物理化学学报,2011, 27(5):1176-1180. (WANG Wang-yin, PAN Ming-xue, QIN Yu-cai, WANG Ling-tao, SONG Li-juan. Effects of Surface acidity on the adsorption desulfurization of Cu(I)Y zeolites[J]. Acta Physico-Chimica Sinica, 2011, 27(5): 1176-1180.)
-
[13] 宋丽娟, 潘明雪, 秦玉才, 鞠秀芳, 段林海, 陈晓陆. NiY分子筛选择性吸附脱硫性能及作用机理[J]. 高等学校化学学报, 2011, 32(3):787-792. (SONG Li-juan, PAN Ming-xue, QIN Yu-cai, JU Xiu-fang, DUAN Lin-hai. Selective adsorption desulfurization performance and adsorptive mechanisms of NiY zeolites[J]. Chemical Journal of Chinese Universities, 2011, 32(3): 787-792.)[13] 宋丽娟, 潘明雪, 秦玉才, 鞠秀芳, 段林海, 陈晓陆. NiY分子筛选择性吸附脱硫性能及作用机理[J]. 高等学校化学学报, 2011, 32(3):787-792. (SONG Li-juan, PAN Ming-xue, QIN Yu-cai, JU Xiu-fang, DUAN Lin-hai. Selective adsorption desulfurization performance and adsorptive mechanisms of NiY zeolites[J]. Chemical Journal of Chinese Universities, 2011, 32(3): 787-792.)
-
[14] DUAN L H, GAO X H, MENG X H, ZHANG H T, WANG Q, QIN Y C, ZHANG X T, SONG L J. Adsorption, co-adsorption, and reactions of sulfur compounds, aromatics, olefins over Ce-exchanged Y zeolite[J]. J Phys Chem C, 2012, 116(49): 25748-25756.[14] DUAN L H, GAO X H, MENG X H, ZHANG H T, WANG Q, QIN Y C, ZHANG X T, SONG L J. Adsorption, co-adsorption, and reactions of sulfur compounds, aromatics, olefins over Ce-exchanged Y zeolite[J]. J Phys Chem C, 2012, 116(49): 25748-25756.
-
[15] 朱华元, 朱可明, 张信, 邱孝培. 超稳 Y 沸石制备技术对沸石铝分布的影响[J]. 催化学报, 1993, 14(2): 133-138. (ZHU Hua-yuan, ZHU Ke-ming, ZHANG Xin, QIU Xiao-pei. Influence of preparation methods of ultra-stable Y zeolites on aluminum distribution of zeolites[J]. Chinese Journal of Catalysis, 1993, 14(2): 133-138.)[15] 朱华元, 朱可明, 张信, 邱孝培. 超稳 Y 沸石制备技术对沸石铝分布的影响[J]. 催化学报, 1993, 14(2): 133-138. (ZHU Hua-yuan, ZHU Ke-ming, ZHANG Xin, QIU Xiao-pei. Influence of preparation methods of ultra-stable Y zeolites on aluminum distribution of zeolites[J]. Chinese Journal of Catalysis, 1993, 14(2): 133-138.)
-
[16] WARD J W. The nature of active sites on zeolites: III. The alkali and alkaline earth ion-exchanged forms[J]. J Catal, 1968, 10(1): 34-46.[16] WARD J W. The nature of active sites on zeolites: III. The alkali and alkaline earth ion-exchanged forms[J]. J Catal, 1968, 10(1): 34-46.
-
[17] 李宣文, 佘励勤, 刘兴云. LaHY表面与NaOH的作用及酸性表面性质研究[J]. 催化学报, 1983, 4(1): 43-50. (LI Xuan-wen, SHE Li-qin, LIU Xing-yun. Studies on the interaction between NaOH and acidic sites on LaHY surface and the nature of acidic surface of LaHY[J]. Chinese Journal of Catalysis, 1983, 4(1): 43-50.)[17] 李宣文, 佘励勤, 刘兴云. LaHY表面与NaOH的作用及酸性表面性质研究[J]. 催化学报, 1983, 4(1): 43-50. (LI Xuan-wen, SHE Li-qin, LIU Xing-yun. Studies on the interaction between NaOH and acidic sites on LaHY surface and the nature of acidic surface of LaHY[J]. Chinese Journal of Catalysis, 1983, 4(1): 43-50.)
-
[18] WARD J W. The nature of active sites on zeolites: VIII. Rare earth Y zeolite[J]. J Catal, 1969, 13(3): 321-327.[18] WARD J W. The nature of active sites on zeolites: VIII. Rare earth Y zeolite[J]. J Catal, 1969, 13(3): 321-327.
-
[19] LAYMAN K A, BUSSELL M E. Infrared spectroscopic investigation of thiophene adsorption on silica-supported nickel phosphide catalysts[J]. J Phys Chem B, 2004, 108(40): 15791-15802.[19] LAYMAN K A, BUSSELL M E. Infrared spectroscopic investigation of thiophene adsorption on silica-supported nickel phosphide catalysts[J]. J Phys Chem B, 2004, 108(40): 15791-15802.
-
[20] GARCIA C L, LERCHER J A. Adsorption and surface reactions of thiophene on ZSM 5 zeolites[J]. J Phys Chem, 1992, 96(6): 2669-2675.[20] GARCIA C L, LERCHER J A. Adsorption and surface reactions of thiophene on ZSM 5 zeolites[J]. J Phys Chem, 1992, 96(6): 2669-2675.
-
[21] SARA Y Y, GARCIA-MARTINEZ J, LI W, MEITZNER G D, IGLESIA E. Kinetic, infrared, and X-ray absorption studies of adsorption, desorption, and reactions of thiophene on H-ZSM5 and Co/H-ZSM5[J]. Phys Chem Chem Phys, 2002, 4(7): 1241-1251.[21] SARA Y Y, GARCIA-MARTINEZ J, LI W, MEITZNER G D, IGLESIA E. Kinetic, infrared, and X-ray absorption studies of adsorption, desorption, and reactions of thiophene on H-ZSM5 and Co/H-ZSM5[J]. Phys Chem Chem Phys, 2002, 4(7): 1241-1251.
-
[22] LOUARN G, MEVELLEC J Y, BUISSON J P, LEFRANT S. Comparison of the vibrational properties of polythiophene and polyalkylthiophenes[J]. Synth met, 1993, 55(1): 587-592.[22] LOUARN G, MEVELLEC J Y, BUISSON J P, LEFRANT S. Comparison of the vibrational properties of polythiophene and polyalkylthiophenes[J]. Synth met, 1993, 55(1): 587-592.
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