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造纸白泥催化花生油与甲醇酯交换的特性研究

牛胜利 ,  李辉 ,  路春美 ,  刘梦琪 ,  霍梦佳

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引用本文: 牛胜利, 李辉, 路春美, 刘梦琪, 霍梦佳. 造纸白泥催化花生油与甲醇酯交换的特性研究[J]. 燃料化学学报, 2013, 41(7): 856-861. shu
Citation:  NIU Sheng-li, LI Hui, LU Chun-mei, LIU Meng-qi, HUO Meng-jia. Catalytic performance of papermaking white clay in the transesterification of peanut oil with methanol[J]. Journal of Fuel Chemistry and Technology, 2013, 41(7): 856-861. shu

造纸白泥催化花生油与甲醇酯交换的特性研究

    通讯作者: 牛胜利
  • 基金项目:

    国家自然科学基金(51206098) (51206098)

    中国博士后科学基金(2012M511021) (2012M511021)

    山东省优秀中青年科学家科技奖励基金(BS2012NJ005). (BS2012NJ005)

摘要: 从催化剂用量、酯交换温度及时间、醇油物质的量比等影响因素出发,并借助热重、X射线荧光光谱、X射线衍射、氮气吸附与哈米特指示剂等催化剂表征手段,研究造纸白泥催化花生油与甲醇的酯交换特性.造纸白泥通过800 ℃煅烧-常温水合-600 ℃活化处理后,成分以CaO为主、比表面积为7.28 m2/g、碱性强度为9.8<H_<15.0;花生油成分以二元不饱和亚油酸为主,酸值为0.44 mgKOH/g;较优的酯交换工况为催化剂质量分数6%、酯交换温度64 ℃、酯交换时间2 h以及醇油物质的量比12,相应甘油收率为90.74%;造纸白泥具有较好的重复使用性能,较优工况下,分离、回收第六次使用时,仍能取得88.63%的甘油收率.

English

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  • 收稿日期:  2013-06-01
  • 网络出版日期:  2013-06-24
通讯作者: 陈斌, bchen63@163.com
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