Citation: LIU Li-hua, LIU Shu-qun, CHAI Yong-ming, LIU Yun-qi, LIU Chen-guang. Synergetic effect between Ni₂P/γ-Al₂O₃ and MoS₂/γ-Al₂O₃ catalysts on their performance in hydrodenitrogenation of quinoline[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(6): 698-702. shu

Synergetic effect between Ni₂P/γ-Al₂O₃ and MoS₂/γ-Al₂O₃ catalysts on their performance in hydrodenitrogenation of quinoline

1.
1. School of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, China;

Corresponding author: LIU Li-hua,
Received Date: 1 March 2013
Available Online: 29 April 2013
Fund Project: Major State Basic Research Development Program of China (973 Program,2010CB226905) (973 Program,2010CB226905) the Natural Science Foundation of Educational Committee of Anhui Province (KJ2013B243) (KJ2013B243) the Youth Foundation of Huaibei Normal University (2012xq47, 2013xqz01). (2012xq47, 2013xqz01)

The synergetic effect between Ni₂P/Al₂O₃ and MoS₂/Al₂O₃ catalysts on their performance in the hydrodenitrogenation of quinoline was proved by a simplified experimental design and explained by the remote control model through a migration of hydrogen spillover. The results indicated that the synergism factor of Ni₂P and MoS₂ is slightly higher than that of NiS_x and MoS₂; it decreases with the increase of reaction temperature. Since the spillover hydrogen with Ni₂P can increase the amount of hydrogenation active sites of MoS₂, the hydrogenation rate of 1,2,3,4-tetrahydroquinoline and 5,6,7,8-tetrahydroquinoline to decahydroquinoline over the Ni₂P/Al₂O₃ and MoS₂/Al₂O₃ catalyst system is then greatly enhanced; as a result, Ni₂P is a superior promoter for MoS₂ catalyst for hydrodenitrogenation.
- hydrogen spillover,
- synergetic effect,
- hydrodenitrogenation,
- MoS₂,
- Ni₂P,
- quinoline
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沈阳化工大学材料科学与工程学院沈阳 110142

Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline

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通讯作者: 陈斌, bchen63@163.com

Synergetic effect between Ni₂P/γ-Al₂O₃ and MoS₂/γ-Al₂O₃ catalysts on their performance in hydrodenitrogenation of quinoline