Citation: ZHONG Wei-cheng, GUO Qing-jie, WANG Xu-yun, ZHANG Liang. Catalytic hydroprocessing of the fast pyrolysis bio-oil of Chlorella[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(5): 571-578. shu

Catalytic hydroprocessing of the fast pyrolysis bio-oil of Chlorella

1.
Key Laboratory of Clean Chemical Processing of Shandong Province, College of Chemical Engineering, Qingdao University of Science ＆ Technology, Qingdao 266042, China

Corresponding author: GUO Qing-jie,
Received Date: 31 December 2012
Available Online: 21 February 2013
Fund Project: 海洋可再生能源专项资金(GHME2001SW02) (GHME2001SW02) 山东省科技攻关项目(2008GG10006010, 2009GG10007001)。 (2008GG10006010, 2009GG10007001)

Catalytic hydroprocessing of the bio-oil obtained through fast pyrolysis of Chlorella was carried out in a bench-scale continuous-flow fixed-bed reactor equipped with a Ni-Co-Pd/γ-Al₂O₃ catalyst. The effects of the hydrogenation temperature and the H/oil molar ratio on the moisture content, calorific value, viscosity and cetane number of the refined bio-oils were investigated at the pressure of 2×10⁶ Pa, It was shown that the yield of the refined oil reached 86.1%, and the calorific value and cetane number were increased by 17.94% and 71.2% respectively, while the viscosity was decreased by 66.32% at the temperature of 300 ℃, the pressure of 2×10⁶ Pa and the H/oil mol ratio of 120. The elemental analysis and GC-MS analysis results of the bio-oil before and after hydrogenation show that the H/C mol ratio was increased from 1.55 to 1.97, while the oxygen, nitrogen and sulfur contents were significantly decreased. The deoxidation degree reached 80.46%. The amounts of organic acids, esters, ketones and aldehyde in the refined oils were obviously decreased, while those of alcohols and alkanes were markedly increased.
- chlorella pyrolysis oil,
- catalytic hydroprocessing,
- Ni-Co-Pd/γ-Al₂O₃ catalyst,
- reaction mechanism
1. [1]
  [1] 杨文衍, 曾燕, 罗嘉, 童冬梅, 卿人韦, 范勇, 胡常伟. 微拟球藻热解及其催化热解制备生物油研究[J]. 燃料化学学报, 2011, 39(9): 664-669. (YANG Wen-yan, ZENG Yan, LUO Jia, TONG Dong-mei, QING Ren-wei, FAN Yong, HU Chang-wei. Production of bio-oil by direct and catalytic pyrolysis of Nannochloropsissp[J]. Journal of Fuel Chemistry and Technology, 2011, 39(9): 664-669.)
2. [2]
  [2] WILDSCHUT J, ARENTZ J, RASRENDRA C B, VENDERBOSCH R H, HEERESA H J. Catalytic hydrotreatment of fast pyrolysis oil: Model studies on reaction pathways for the carbohydrate fraction[J]. Environ Prog Sustain Energy, 2009, 28(3): 450-460.
3. [3]
  [3] ELLIOTT D C, HART T R, GARY G, NEUENSCHWANDER G G, ROTNESS L J, ZACHER A H. Catalytic hydroprocessing of biomass fast pyrolysis bio-oil to produce hydrocarbon products[J]. Environ Prog Sustain Energy, 2009, 3(28): 441-449.
4. [4]
  [4] DONNIS B, EGEBERG RG, BLOM P, GRΦNKNUDSEN J. Hydroprocessing of bio-oils and oxygenates to hydrocarbons: Understanding the reaction routes[J]. Top Catal, 2009, 52(3): 229-240.
5. [5]
  [5] ELLIOTT D C, HART T R. Catalytic hydroprocessing of fast pyrolysis bio-oil from pine sawdust[J]. Energy Fuels, 2012, 26(6): 3891-3896.
6. [6]
  [6] GANDARIAS I, BARRIO V L, REQUIES J. From biomass to fuels: Hydrotreating of oxygenated compounds[J]. Int J Hydrogen Energy, 2008, 33(13): 3485-3488.
7. [7]
  [7] 杨骏, 陈满英, 陈运红, 孙玉川. Ni-Mo/Al₂O₃加氢脱氧催化剂的研究[J]. 现代化工, 2005, 25(21): 119-122. (YANG Jun, CHEN Man-ying, CHEN Yun-hong, SUN Yu-chuan. Study of Ni-Mo/Al₂O₃ catalyst for hydrodeoxygenation[J]. Modern Chemical Industry, 2005, 25(21): 119-122.)
8. [8]
  [8] 徐春明, 杨朝合. 石油炼制工程[M]. 第四版. 北京: 石油工业出版社, 2009. (XU Chun-ming, YANG Chao-he. Petroleum refining engineering[M]. Fourth Edition.Beijing: Petroleum Industry Publishing House, 2009.)
9. [9]
  [9] BROWN H C, BROWN C A. New, Highly active metal catalysts for the hydrolysis of borohydride[J]. Journal of American Chemical, 1962, 84(8): 1493-1494.
10. [10]
  [10] WEITKAMP J. Catalytic hydrocracking-mechanisms and versatility of the process[J]. Chem Cat Chem, 2012, 4(3): 292-306.
11. [11]
  [11] TRAN N H, BARTLETT J R, KANNANGARA G S K, MILEV A S, H. VOLK B H, WILSON M A. Catalytic upgrading of biorefinery oil from micro-algae[J]. Fuel, 2010, 89(2): 265-274.
12. [12]
  [12] 苏贻勋, 李林. 催化裂化柴油中芳烃结构与十六烷值的关系[J]. 齐鲁石油化工, 1993, 21(3): 222-224. (SU Yi-xun, LI Lin. Relationship of aromatics structure composed and cetane number on FCC diesel[J]. Qilu Petrochemical, 1993, 21(3): 222-224.)
13. [13]
  [13] 陆强, 李文志, 张栋, 朱锡锋. 锯末快速热解气的在线催化裂解[J]. 化工学报, 2009, 60(2): 351-357. (LU Qiang, LI Wen-zhi, ZHANG Dong, ZHU Xi-feng. In situ catalytic cracking of sawdust fast pyrolysis vapors[J]. Journal of Chemical Industry and Engineering(China), 2009, 60(2): 351-357.
14. [14]
  [14] SANTILLAN-JIMENEZ E, CROCKER M. Catalytic deoxygenation of fatty acids and their derivatives to hydrocarbon fuels via decarboxylation/decarbonylation[J]. J Chem Technol Biotechnol, 2012, 87(8): 1041-1050.
15. [15]
  [15] DIEBOLD J P. A review of the chemical and physical mechanisms of the storage stability of fast pyrolysis bio-oils. Golden, Colorado: National Renewable Energy Laboratory, 2000.
1. [1]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
2. [2]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
3. [3]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
4. [4]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
5. [5]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
6. [6]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
7. [7]
  Guowen Xing , Guangjian Liu , Le Chang . Five Types of Reactions of Carbonyl Oxonium Intermediates in University Organic Chemistry Teaching. University Chemistry, 2025, 40(4): 282-290. doi: 10.12461/PKU.DXHX202407058
8. [8]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
9. [9]
  Jiabo Huang , Quanxin Li , Zhongyan Cao , Li Dang , Shaofei Ni . Elucidating the Mechanism of Beckmann Rearrangement Reaction Using Quantum Chemical Calculations. University Chemistry, 2025, 40(3): 153-159. doi: 10.12461/PKU.DXHX202405172
10. [10]
  Qian Huang , Zhaowei Li , Jianing Zhao , Ao Yu . Quantum Chemical Calculations Reveal the Details Below the Experimental Phenomenon. University Chemistry, 2024, 39(3): 395-400. doi: 10.3866/PKU.DXHX202309018
11. [11]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
12. [12]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
13. [13]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
14. [14]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
15. [15]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
16. [16]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
17. [17]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
18. [18]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
19. [19]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
20. [20]
  Haodong JIN , Qingqing LIU , Chaoyang SHI , Danyang WEI , Jie YU , Xuhui XU , Mingli XU . NiCu/ZnO heterostructure photothermal electrocatalyst for efficient hydrogen evolution reaction. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1068-1082. doi: 10.11862/CJIC.20250048

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(534)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142