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Citation: WU Hao, WANG Meng, LIU Hao, YANG Hong-min. Influence of SO2 on the cyclic calcination and carbonation of calcium-based sorbent for CO2 capture[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(3): 368-373. shu

Influence of SO2 on the cyclic calcination and carbonation of calcium-based sorbent for CO2 capture

  • 1.

    School of Energy and Mechanical Engineering, Nanjing Normal University, Nanjing 210042, China

  • Corresponding author: YANG Hong-min, 
  • Received Date: 6 September 2012
    Available Online: 8 November 2012

    Fund Project: 国家自然科学基金(50976049) (50976049)江苏省自然科学基金(BK2011788)。 (BK2011788)

  • The effects of SO2 on the cyclic calcination and carbonation characteristics and the cycling stability of calcium-based CaCO3 sorbent for CO2 capture were investigated in a cycling calcination/carbonation system. The results indicated that the capacity of CaCO3 sorbent for CO2 capture decreases with the increase of the number of calcination/carbonation cycling and the addition of SO2 will further reduce the capacity for CO2 capture; moreover, the decrease of the capacity for CO2 capture may be aggravated at higher SO2 concentration. After 10th cycling, the carbonation conversions of the sorbent under SO2 concentration of 0, 0.1% and 0.2% are 25.5%, 16.9% and 5.2%, respectively. SEM characterization results revealed that sulfate products are formed on the surface of CaCO3 particles in the presence of SO2; the sulfate products block the sorbent holes and then reduce the diffusion rate of CO2 into the sorbent, which may then reduce the capacity of the calcium-based sorbent for CO2 capture.
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