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Citation: WEI Qiang, XU Yan, ZHANG Xiao-qing, ZHAO Chuan-chuan, DAI Xiao-yan, YIN Yong-xiang. CH4-CO2 reforming by combination of plasma and catalysts[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(3): 328-334. shu

CH4-CO2 reforming by combination of plasma and catalysts

  • 1.

    Center of Plasma Application, School of Chemical Engineering, Sichuan University, Chengdu 610065, China

  • Corresponding author: YIN Yong-xiang, 
  • Received Date: 13 August 2012
    Available Online: 21 November 2012

  • To reduce the energy consumption of CO2 reforming of CH4, the synergies of thermal plasma and catalysts in the reforming process was studied in three elaborate modes: plasma only, combination of plasma and catalysts (CPC), and CPC with part of feed gases introduced into plasma discharge region. The optimal specific energy of 193 kJ/mol and energy conversion efficiency of 66.4% were achieved under the conditions of CH4/CO2 of 4/6, input power at 14.4 kW, feed gases of 5 m3/h in mode 3, when the conversions of CH4 and CO2 were 77.00% and 62.40%, and the selectivities of H2 and CO were 88.60% and 96.70%, respectively. These results were closed to that of CH4-H2O(g) reforming process. The excellent performance of the present process benefits from three different reaction courses: discharge reaction, thermochemical reaction and catalytic reaction.
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