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Citation: XU Jin, WANG Xi-tao, FAN Can-can, QIAO Jing. Effect of Pd-modification on photocatalytic H2 evolution over Cd0.8Zn0.2S/SiO2 from glycerol solution[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(3): 323-327. shu

Effect of Pd-modification on photocatalytic H2 evolution over Cd0.8Zn0.2S/SiO2 from glycerol solution

  • 1.

    1. Institute of Management, Tianjin University of Technology, Tianjin 300384, China;

  • Corresponding author: WANG Xi-tao, 
  • Received Date: 6 August 2012
    Available Online: 27 October 2012

    Fund Project: 国家自然科学基金(20806059,21276190)。 (20806059,21276190)

  • A series of Pd/Cd0.8Zn0.2S/SiO2 photocatalysts were prepared by incipient wet impregnation. The catalysts were characterized by XRD, H2-TPR, XPS, and UV-vis DRS and used in the photocatalytic evolution of H2 from glycerol and water mixture; the effects of Pd loading on the surface structure, photo absorption and H2 evolution rate were investigated. The results showed that the chemical interaction between ZnS and CdS results in the formation of Cd0.8Zn0.2S solid solution on the surface of SiO2; after the modification with Pd, the light absorption region of Cd0.8Zn0.2S/SiO2 is expanded and the photo absorption efficiency is enhanced obviously. The loading of Pd exhibits significant influence on the rate of photocatalytic H2 evolution; over 0.5%Pd/Cd0.8Zn0.2S/SiO2 with a Pd loading of 0.5%, the maximum hydrogen production rates under UV light irradiation and under solar-simulated light irradiation reach 831 μmol·h-1 and 153 μmol·h-1, respectively, which are almost 4 times and 2 times higher than those obtained over unmodified Cd0.8Zn0.2S/SiO2 under UV and solar-simulated light irradiation, respectively. The superior photocatalytic performance of Pd/Cd0.8Zn0.2S/SiO2 can be partly related with the improvement of photo absorption, the enhancement in chemisorption and activation of H2O and the increase in separation efficiency of photo induced electron-hole arising from the Pd modification.
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    1. [1]

      [1] SHEN S, ZHAO L, GUO L. ZnmIn2S3+m (m=1-5, integer):A new series of visible-light-driven photocatalysts for splitting water to hydrogen[J]. Int J Hydrogen Energy, 2010, 35(19):10148-10154.

    2. [2]

      [2] YU JG, SHI L. One-pot hydrothermal synthesis and enhanced photocatalytic activity of trifluoroacetic acid modified TiO2 hollow microspheres[J]. J Mol Catal A, 2010, 326(1/2): 8-14.

    3. [3]

      [3] SHEN S, GUO L, CHEN X, REN F, MAO S S. Effect of Ag2S on solar-driven photocatalytic hydrogen evolution of nanostructured CdS[J]. Int J Hydrogen Energy, 2010, 35(13): 7110-7115.

    4. [4]

      [4] MAEDA K, DOMEN K. New non-oxide photocatalysts designed for overall water splitting under visible light[J]. J Phys Chem C, 2007, 111(22): 7851-7861.

    5. [5]

      [5] KUDO A. Recent progress in the development of visible lightdriven powdered photocatalysts for water splitting[J]. Int J Hydrogen Energy, 2007, 32(14):2673-2678.

    6. [6]

      [6] KOCA A, SAHIN M. Photocatalytic hydrogen production by direct sun light from sulfide/sulfite solution[J]. Int J Hydrogen Energy, 2002, 27(4): 363-367

    7. [7]

      [7] XU X, LU R, ZHAO X, XU S, LEI X, EVANS D G. Fabrication and photocatalytic performance of a ZnxCd1-xS solid solution prepared by sulfuration of a single layered double hydroxide precursor[J]. Appl Catal B, 2011, 102(1/2): 147-156.

    8. [8]

      [8] VILLORIA J A, NAVARRO YERGA R M, AL-ZAHRANI S M, FIERRO J L G. Photocatalytic hydrogen production on Cd1-xZnxS solid solutions under visible light: Influence of thermal treatment[J]. Ind Eng Chem Res, 2010, 49(15): 6854-6861.

    9. [9]

      [9] 彭绍琴, 黄亚辉, 安然, 李越湘. 复合光催化剂CdS-Pt/TiO2低温制备及可见光制氢性能[J]. 功能材料, 2011, 9(42): 1669-1672. (PENG Shao-qing, HUANG Ya-hui, AN Yan, LI Yue-xiang. Preparation of CdS-Pt/TiO2 composite photocatalyst by low temperature method and its performance for photocatalytic hydrogen evolution under visible light irradiation[J]. Journal of Functional Materials, 2011, 9(42): 1669-1672.)

    10. [10]

      [10] 周鹏, 赵成坚, 董文平, 吕功煊. 高分子修饰Pt/ZnS-CdS/SiO2催化剂表面官能团调变与光催化制氢活性关系的研究[J]. 分子催化, 2012, 26(3): 265-274. (ZHOU Peng, ZHAO Chen-jian, DONG Wen-ping, LV Gong-xuan. Studies on photocatalytic hydrogen production relating to the surface functional groups modulation of polymer-modified Pt/ZnS-CdS/SiO2[J]. Journal of Molecular Catalysis(China), 2012, 26(3): 265-274.)

    11. [11]

      [11] SANG H X, WANG X T, FAN C C, WANG F. Enhanced photocatalytic H2 production from glycerol solution over ZnO/ZnS core/shell nanorods prepared by a low temperature route [J]. Int J Hydrogen Energy, 2012, 37(2), 1348-1355.

    12. [12]

      [12] CELEBI S, ERDAMAR A J. Synthesis and characterization of poly(acrylic acid) stabilized cadmium sulfide quantum dots[J]. J Phys Chem B, 2007, 111(44): 12668-12675.

    13. [13]

      [13] DESHPANDE A, SHAH P, GHOLAP R S. Interfacial and physico-chemical properties of polymer-supported CdS center dot ZnS nanocomposites and their role in the visible-light mediated photocatalytic splitting of water[J]. J Colloid Interface Sci, 2009, 333(1): 263-268.

    14. [14]

      [14] 李静玲, 陈文哲, 吴波, 黄世震, 林伟, 李世平, 曹小霞, 翁晴, 王敏. 银掺杂TiO2纳米管制备与性能研究[J]. 功能材料, 2012, 8(43): 953-957. (LI Jing-ling, CHEN Wen-zhe, WU Bo, HUANG Shi-zhen, LIN Wei, LI Shi-ping, CAO Xiao-xia, WENG Qing, WANG Min. Synthesis and characterization of Ag-doped TiO2 nanotubes[J]. Journal of Functional Materials, 2012, 8(43): 953-957.)

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