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Citation: ZHAO Kun, HE Fang, HUANG Zhen, WEI Guo-qiang, LI Hai-bin, ZHAO Zeng-li. Biomass pyrolysis/gasification using three dimensional ordered macroporous (3DOM) Fe2O3 as an oxygen carrier[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(3): 277-284. shu

Biomass pyrolysis/gasification using three dimensional ordered macroporous (3DOM) Fe2O3 as an oxygen carrier

  • 1.

    1. The Key Laboratory of Renewable Energy and Gas Hydrate of Chinese Academy of Sciences, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;

  • Corresponding author: HE Fang, 
  • Received Date: 11 September 2012
    Available Online: 10 December 2012

    Fund Project: 国家自然科学基金(51076154) (51076154)"十二五"国家科技支撑计划(2011BAD15B05)。 (2011BAD15B05)

  • Polystyrene spheres were prepared by soap free emulsion polymerization method,then three dimensional ordered macroporous (3DOM) oxides Fe2O3 were successfully prepared after impregnation and calcination using nitrates as raw materials and citric acid as complexing agent. The samples were characterized by the techniques of scanning electron microscopy (SEM), X-ray diffraction(XRD), BET and mercury porosimetry. Pyrolysis and gasification of biomass with Fe2O3 as oxygen carriers in helium atmosphere were carried out in a thermogravimetric analyzer coupled with mass spectrometry (TG-MS). The possibility of 3DOM Fe2O3 functioning as gasification agent in biomass gasification substituted for pure oxygen, oxygen-enriched air or steam were investigated. Furthermore, a comparison experiment was carried out by using analytically pure Fe2O3 to analysis the high-performance of 3DOM Fe2O3. The characterization results showed that 3DOM Fe2O3 presented a three-dimensional ordered macroporous morphology, its tiers were arranged alternatively and connected through three-dimensional pore structures. By contrast with the XRD pattern of analytically pure Fe2O3. TG-MS results showed that Fe2O3 contributed to biomass gasification in high temperature stage. When used 3DOM Fe2O3 as oxygen carrier, the maximum weight loss and maximum weight loss rate raised 7.1% and 0.29%/min in the gasification stage, respectively, meanwhile two generation peaks of CO, CO2, and CH4 appeared in the MS curves.
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