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Citation: ZHENG Hua-yan, LIU Yuan-yuan, DONG Rui-min, MENG Fan-hui, LI Zhong. Effects of water on catalytic performance of Cu+/S2O82-/γ-Al2O3 for oxidative carbonylation of methanol to dimethyl carbonate[J]. Journal of Fuel Chemistry and Technology, ;2013, 41(1): 110-115. shu

Effects of water on catalytic performance of Cu+/S2O82-/γ-Al2O3 for oxidative carbonylation of methanol to dimethyl carbonate

  • 1.

    Key Laboratory of Coal Science and Technology, Ministry of Education and Shanxi Province, Taiyuan University of Technolgy, Taiyuan 030024, China

  • Corresponding author: LI Zhong, 
  • Received Date: 27 April 2012
    Available Online: 5 June 2012

    Fund Project: 国家自然科学基金(20976113, 20936003) (20976113, 20936003) 山西省归国留学基金(20100038)。 (20100038)

  • Effects of H2O on the catalyst Cu+/S2O82-/γ-Al2O3 of DMC synthesis in slurry reactor were investigated under the conditions of 120℃ and 3.0 MPa. The results showed that the introduction of water into reaction system led to quick catalyst deactivation. The catalysts were characterized by the Elemental Analysis, XRD, DTG, Py-FT-IR and NH3-TPD. The results showed that active component Cu and CuCl, loading on the surface of S2O82-/γ-Al2O3 support, reacted with O2 and H2O, then formed Cu2(OH)3Cl which was essentially inactive for oxidative carbonylation of methanol to dimethyl carbonate. The catalyst deactivation rate speeded up with increasing water injection.
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    1. [1]

      [1] ONO Y. Catalysis in the production and reactions of dimethyl carbonate, an environmentally benign building block [J]. Appl Catal A, 1997, 155(2): 133-166.

    2. [2]

      [2] PACHECO M A, MARSHALL C L. Review of dimethyl carbonate (DMC) manufacture and its characteristics as a fuel additive[J]. Energy Fuels, 1997, 11(1): 2-29.

    3. [3]

      [3] 莫婉玲, 熊辉, 李光兴. 甲醇羰基化催化剂的合成、表征及溶解性研究[J]. 燃料化学学报,2001, 29(2): 165- 168. (MO Wan-ling,XIONG Hui,LI Guang-xing. Synthesis, characterization and solubility of methanol carbonylation catalyst Cu(OCH3)Cl[J]. Journal of Fuel Chemistry and Technology,2001, 29(2): 165-168.)

    4. [4]

      [4] BHATTACHARYA A.Fuel oxygenates: Organic carbonate synthesis[J].Prepr Pap Am Chem SOC, Div Fuel Chem, 1995, 40(1), 119-122.

    5. [5]

      [5] 王东升, 谭猗生, 韩怡卓, 椿范立. CO2对浆态床一步法合成二甲醚铜基催化剂稳定性的影响[J]. 催化学报, 2008, 29(1): 63-68. (WANG Dong-sheng, TAN Yi-sheng, HAN Yi-zhuo,CHUN Fan-li. Effect of CO2 on stability of Cu-based catalyst for dimethyl ether synthesis in slurry phase[J]. Chinese Journal of Catalysis, 2008, 29(1): 63-68.)

    6. [6]

      [6] ROMANO U, TESEL R, MAURIM M, REBORA P. Synthesis of dimethyl carbonate from methanol carbon monoxide, and oxygen catalyzed by copper compounds[J]. Ind Eng Chem Prod Res Dev, 1980, 19(3): 396-403.

    7. [7]

      [7] HAN M S, LEE B G, SUH I, KIM H S, AHN B S, HONG S I. Synthesis of dimethyl carbonate by vapor phase oxidative carbonylation of methanol over Cu-based catalysts[J]. J Mol Catal A, 2001, 170(1/2): 225-234.

    8. [8]

      [8] YANG P, CAO Y, DAI W-L, DENG J-F, FAN K-N. Effect of chemical treatment of activated carbon as a support for promoted dimethyl carbonate synthesis by vapor phase oxidative carbonylation of methanol over Wacker-type catalysts [J]. Appl Catal A, 2003, 243(2): 323-331.

    9. [9]

      [9] RICHTER M. Gas-phase carbonylation of methanol to dimethyl carbonate on chloride-free Cu-precipitated zeolite Y at normal pressure[J]. J Catal, 2007, 245(1): 11-24.

    10. [10]

      [10] KING S T. Reaction mechanism of oxidative carbonylation of methanol to dimethyl carbonate in Cu-Y zeolite[J]. J Catal, 1996, 161(2): 530-538.

    11. [11]

      [11] LI Z, XIE K, SLADE R C T. Studies of the interaction between CuCl and HY zeolite for preparing heterogeneous Cu+ catalyst[J]. Appl Catal A, 2001, 209(1/2): 107-115.

    12. [12]

      [12] 李忠, 孟凡会, 任军, 郑华艳, 谢克昌. CuCl/ SiO2-Al2O3催化剂的表面结构及甲醇氧化羰基化催化性能[J]. 催化学报,2008, 29(7): 643-648. (LI Zhong, MENG Fan-hui, REN Jun, XIE Ke-chang. Surface structure and catalytic performance of CuCl/SiO2-Al2O3 catalysts for methanol oxidative carbonylation[J]. Chinese Journal of Catalysis, 2008, 29(7): 643-648.)

    13. [13]

      [13] 郑华艳, 任军, 周媛, 牛燕燕, 李忠. Cu+/SiO2-ZrO2催化剂的制备及其催化甲醇氧化羰基化性能[J]. 燃料化学学报, 2011, 39(4): 282-286. (ZHENG Hua-yan, REN Jun, ZHOU Yuan, NIU Yan-yan, LI Zhong. Preparation of Cu+ /SiO2-ZrO2 catalysts for oxidative carbonylation of methanol to dimethyl carbonate[J]. Journal of Fuel Chemistry and Technology, 2011, 39(4): 282-286.)

    14. [14]

      [14] REN J, LIU S, LI Z, XING L, KE X. Oxidative carbonylation of methanol to dimethyl carbonate over CuCl/SiO2-TiO2 catalysts prepared by microwave heating: The effect of support composition[J]. Appl Catal A, 2009, 366(1): 93-101.

    15. [15]

      [15] 李忠, 黄海彬, 谢克昌. Cu(Ⅰ)/SO42-/ZnO和Cu(Ⅰ)/S2O82-/ZnO催化剂的制备与表征[J]. 高等学校化学学报, 2008, 29(8): 1609-1615. (LI Zhong, HUANG Hai-bin, XIE Ke-chang. Preparation and characterization of Cu(Ⅰ) /SO42-/ZnO and Cu(Ⅰ)/S2O82-/ZnO catalysts[J]. Chemical Research of Chinese Universities, 2008, 29(8): 1609-1615.)

    16. [16]

      [16] 李忠, 刘媛媛, 郑华艳, 黄海彬, 阴丽华. 固体酸负载Cu+催化剂表征及催化甲醇氧化羰基化[J]. 化工学报, 2010, 61(6): 1443-1449. (LI Zhong, LIU Yuan-yuan, ZHENG Hua-yan, HUANG Hai-bin, YIN Li-hua. Characterization and catalytic performance of Cu+/ solid acids catalysts in oxidative carbonylation of methanol[J]. Journal of Chemical Industry and Engineering(China), 2010, 61(6): 1443-1449.)

    17. [17]

      [17] ROMANO U, TESEI R, CIPRIANNI G. Method for the preparation of esters of carbonic acid: US, 4218391[P]. 1980-08-19.

    18. [18]

      [18] FLEET M E. The crystal stucture of paratacamite Cu2(OH)3Cl[J]. Acta Crystallogr B, 1975, 31(1):183-187.

    19. [19]

      [19] 辛勤, 梁长海. 固体催化剂的研究方法 第八章 红外光谱法(中)[J]. 石油化工, 2001, 30(2):157-167. (XIN Qin,LIANG Chang-hai. The research method of solid catalyst: Infrared spectroscopy[J]. Petrochemical Technology, 2001, 30(2): 157-167.)

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