Citation: BAI Shao-fen, LIU Shun, LIU Xin-mei. Deactivation of Cu/ZrO₂ catalyst for methanol synthesis from CO₂ hydrogenation[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(11): 1341-1345. shu

Deactivation of Cu/ZrO₂ catalyst for methanol synthesis from CO₂ hydrogenation

1.
State Key Laboratory for Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, China University of Petroleum(East China), Qingdao 266555, China

Corresponding author: LIU Xin-mei,
Received Date: 5 April 2012
Available Online: 4 June 2012

The physical structure, microstructure and carbonaceous deposition of Cu/ZrO₂ catalysts for methanol synthesis from CO₂ hydrogenation were characterized by nitrogen sorption, X-ray diffraction (XRD), transmission electron microscope (TEM), and thermogravimetry and differential scanning calorimetry (TG-DSC) techniques. The results showed that the sintering of active components is the major factor for catalyst deactivation and the carbonaceous deposition is in the next place; the surface area has little effect on catalyst activation.
- Cu/ZrO₂ catalyst,
- methanol synthesis,
- deactivation factors
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沈阳化工大学材料科学与工程学院沈阳 110142

Deactivation of Cu/ZrO2 catalyst for methanol synthesis from CO2 hydrogenation

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通讯作者: 陈斌, bchen63@163.com

Deactivation of Cu/ZrO₂ catalyst for methanol synthesis from CO₂ hydrogenation