Citation: Yue Sun, Fan Zhang, Li Zhang, Li Luo, Zhi-Long Zou, Xian-Liang Cao, Shi-Liang Tan, Jia-Hai Bi, De-Mei Tian, Hai-Bing Li. Synthesis of calix[4]arene derivatives via a Pd-catalyzed Sonogashira reaction and their recognition properties towards phenols[J]. Chinese Chemical Letters, ;2014, 25(2): 226-228. shu

Synthesis of calix[4]arene derivatives via a Pd-catalyzed Sonogashira reaction and their recognition properties towards phenols

1.
Key Laboratory of Pesticide and Chemical Biology of the Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China

Corresponding author: De-Mei Tian, Hai-Bing Li,
Received Date: 22 July 2013
Available Online: 26 September 2013
Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 21372092, 21072072, 21102051) (Nos. 21372092, 21072072, 21102051) PCSIRT (No. IRTO953) (No. IRTO953) Program for New Century Excellent Talent in University (No. NCET-10-0428) (No. NCET-10-0428) and State Key Laboratory of Chemo/Biosensing and Chemometrics (201003). (Nos. CCNU11C01002, CCNU13F005)

A novel series of calix[4]arene derivatives were synthesized via a Pd-catalyzed Sonogashira coupling reaction from para-substituted iodobenzene and 25,27-dipropargyl-calix[4]arene. Fluorescence studies found that nitro-phenols clearly exhibited quenching effects on 2c. Moreover, we minimized the free energy of the complexes by theoretical calculations. As the result, the π-π stacking interactions take place between the 4-nitrophenol and calix[4]arene, which may lead to the significant fluorescence quench.
- Calix[4]arene,
- Sonogashira coupling reaction,
- Fluorescent sensors,
- π-π stacking
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沈阳化工大学材料科学与工程学院沈阳 110142