Citation: Qian Jiang, Lu-Tao He, Shun-Zhong Luo, Yan-Qiu Yang, Liang Yang, Wen Feng, Li-Hua Yuan. Synthesis of a crescent aromatic oligothioamide and its high selectivity in recognizing copper(Ⅱ) ions[J]. Chinese Chemical Letters, ;2013, 24(10): 881-884. shu

Synthesis of a crescent aromatic oligothioamide and its high selectivity in recognizing copper(Ⅱ) ions

1.
a Key Laboratory for Radiation Physics and Technology of Ministry of Education, College of Chemistry, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, China;
2.
b Institute of Nuclear Physics and Chemistry, CAEP, Mianyang 621900, China

Corresponding author: Wen Feng,
Received Date: 1 April 2013
Available Online: 13 May 2013
Fund Project: This work was supported by the National Natural Science Foundation (No. 21172158) (No. 21172158) NSAF (No. 11076018) (No. 11076018) the National Fund of China for Fostering Talents in Basic Science (No. J1210004) (No. 2011FZ0048)Open Project of Key Laboratory for Radiation Physics and Technology of Ministry of Education (No. 2010-08). Analytical & Testing Center of Sichuan University is acknowledged for NMR analyses. (No. J1210004)

Functionalization of shape-persistent aromatic oligoamides still represents a difficult task nowadays. A crescent aromatic oligothioamide was synthesized by simple thionation of the corresponding oligoamide with the Lawesson's reagent. The results from UV-vis spectra of the molecule upon metal ion complexation demonstrated its higher selectivity in recognizing Cu²⁺ ions compared to the oligoamide precursor. The stoichiometry of the complex formed between the thioamide and Cu²⁺ was found to be 1:1 with a binding constant of (4.3±0.9)×10⁴ mol/L.
- Oligothioamide,
- Recognition,
- Copper(Ⅱ) ion,
- UV-vis spectra
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沈阳化工大学材料科学与工程学院沈阳 110142