Citation: Yun-Ming Wang, Bing-Tao Tang, Wei Ma, Shu-Fen Zhang, De-Feng Zhao. An unusual substitution reaction of an aromatic sulfonic group based on 3-carbonyl-4-phenolsulfonic acid[J]. Chinese Chemical Letters, ;2013, 24(07): 613-616. shu

An unusual substitution reaction of an aromatic sulfonic group based on 3-carbonyl-4-phenolsulfonic acid

1.
a State Key Laboratory of Fine Chemicals, Dalian University of Technology (West Campus), Dalian 116024, China;
b Jihua Group Co.
b Jihua Group Co., Ltd., Dalian 116024, China

Corresponding author: Bing-Tao Tang,
Received Date: 22 January 2012
Available Online: 28 March 2013

An unusual substitution reaction of an aromatic sulfonic group based on 3-carbonyl-4-phenolsulfonic acid was discovered in a diazo-coupling process. The reaction occurred under mild reaction conditions (pH 8.0-9.0, 0-5℃, solvent: water) within a short reaction time (1 h). A plausible substitution reaction mechanism by phenol-ketone resonance was proposed.
- Aromatic sulfonic groups,
- Substitution reaction,
- Diazo-coupling,
- Diazonium salt
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沈阳化工大学材料科学与工程学院沈阳 110142