Citation: Ming-Zhao Wang, Ying Li, Jin-Jin Ji, Gai-Ling Huang, Xin Zhang, Si-Hui Li, Xiao-Jing Yang. Novel hybrids of Cu²⁺ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline (or bipyridine) intercalated in Mg/Al-NO₃-layered double hydroxide[J]. Chinese Chemical Letters, ;2013, 24(07): 593-596. shu

Novel hybrids of Cu²⁺ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline (or bipyridine) intercalated in Mg/Al-NO₃-layered double hydroxide

1.
College of Chemistry, Beijing Normal University, Beijing 100875, China

Corresponding author: Ming-Zhao Wang,
Received Date: 23 January 2013
Available Online: 7 March 2013

Four Cu²⁺ complexes of salicylidene-amino acid Schiff base with 1,10-phenanthroline (Phen) or 2,2'-bipyridine (Bipy) were successfully intercalated in interlayer galleries of Mg/Al-NO₃-layered double hydroxide (LDH) by the swelling-restored method. The hybrids were characterized by elemental analysis, X-ray diffraction, FT-IR spectra, UV-vis DRS, TG-DTA and SEM observation. Good protection of the complexes by LDH in neutral and weak acidic solutions was revealed by UV spectra, cyclic voltammograms and luminescence spectra.
- Layered double hydroxides,
- Ternary copper complexes,
- Intercalation,
- Characterization,
- Stability in solution
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Novel hybrids of Cu2+ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline (or bipyridine) intercalated in Mg/Al-NO3-layered double hydroxide

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通讯作者: 陈斌, bchen63@163.com

Novel hybrids of Cu²⁺ ternary complexes of salicylidene-amino acid Schiff base with phenanthroline (or bipyridine) intercalated in Mg/Al-NO₃-layered double hydroxide