Citation: Xi Wang, Yi-Jun Yang, Ying Ma, Jian-Nian Yao. Controlled synthesis of multi-shelled transition metal oxide hollow structure through one-pot solution route[J]. Chinese Chemical Letters, ;2013, 24(01): 1-6. shu

Controlled synthesis of multi-shelled transition metal oxide hollow structure through one-pot solution route

1.
Beijing National Laboratory for Molecular Sciences(BNLMS), CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Ying Ma, Jian-Nian Yao,
Received Date: 22 November 2012
Available Online: 24 December 2012

As one type of promising candidates for environmental and energy-related systems,multi-shelled transition metal oxide hollow structures(MS-TMOHSs)have drawn great scientific and technical interest in the past few years.This article highlights recent advances in one-pot solution synthesis of MS-TMOHSs.We begin it with an overview of synthetic strategies that have been exploited to achieve these peculiar structures.We then focus on one-pot solution approaches in the following four sections:i)soft templates directed growth;ii)Ostwald ripening;iii)controlled etching;and iv)gas bubble assisted growth.After giving a brief discussion on the unique properties and applications of these multi-shelled hollow structures,we conclude this review with the general challenges and the potential future directions of this exciting area of research.
- Transition metal oxides,
- Multi-shelled hollow structures,
- Synthesis,
- Application
1. [1]
  [1] X.W.Lou,L.A.Archer,Z.Yang,Hollow micro-/nanostructures:synthesis and applications,Adv.Mater.20(2008)3987-4019.
2. [2]
  [2] J.Liu,F.Liu,J.Wu,et al.,Recent developments in the chemical synthesis of inorganic porous capsules,J.Mater.Chem.19(2009)6073-6084.
3. [3]
  [3] G.Réthoré,A.Pandit,Use of templates to fabricate nanoscale spherical structures for defined architectural control,Small 6(2010)488-498.
4. [4]
  [4] J.Hu,M.Chen,X.Fang,et al.,Fabrication and application of inorganic hollow spheres,Chem.Soc.Rev.40(2011)5472-5491.
5. [5]
  [5] J.Liu,D.Xue,Hollow nanostructured anode materials for Li-ion batteries,Nano-scale Res.Lett.5(2010)1525-1534.
6. [6]
  [6] X.Wang,W.Tian,T.Zhai,et al.,Cobalt(Ⅱ,Ⅲ)oxide hollow structures:fabrication, properties and applications,J.Mater.Chem.22(2012)23310-23326.
7. [7]
  [7] X.Lai,J.E.Halpert,D.Wang,Recent advances in micro-/nano-structured hollow spheres for energy applications:from simple to complex systems,Energy Environ. Sci.5(2012)5604-5618.
8. [8]
  [8] Y.Zhao,L.Jiang,Hollow micro/nanomaterials with multilevel interior structures, Adv.Mater.21(2009)3621-3638.
9. [9]
  [9] H.Zeng,Synthesis and self-assembly of complex hollow materials,J.Mater.Chem. 21(2011)7511-7526.
10. [10]
  [10] M.Yang,J.Ma,C.L.Zhang,et al.,General synthetic route toward functional hollow spheres with double-shelled structures,Angew.Chem.Int.Ed.44(2005) 6727-6730.
11. [11]
  [11] M.Yang,J.Ma,Z.Niu,et al.,Synthesis of spheres with complex structures using hollow latex cages as templates,Adv.Funct.Mater.15(2005)1523-1528.
12. [12]
  [12] X.W.Lou,C.Yuan,L.A.Archer,Double-walled SnO₂ nano-cocoons with movable magnetic cores,Adv.Mater.19(2007)3328-3332.
13. [13]
  [13] X.W.Lou,C.Yuan,L.A.Archer,Shell-by-shell synthesis of tin oxide hollow colloids with nanoarchitectured walls:cavity size tuning and functionalization,Small 3 (2007)261-265.
14. [14]
  [14] J.Qiu,F.Zhuge,X.Li,et al.,Coaxial multi-shelled TiO₂ nanotube arrays for dye sensitized solar cells,J.Mater.Chem.22(2012)3549-3554.
15. [15]
  [15] H.X.Yang,J.F.Qian,Z.X.Chen,et al.,Multilayered nanocrystalline SnO₂ hollow microspheres synthesized by chemically induced self-assembly in the hydrother-mal environment,J.Phys.Chem.C 111(2007)14067-14071.
16. [16]
  [16] C.Z.Wu,X.D.Zhang,B.Ning,et al.,Shape evolution of new-phased lepidocrocite VOOH from single-shelled to double-shelled hollow nanospheres on the basis of programmed reaction-temperature strategy,Inorg.Chem.48(2009) 6044-6054.
17. [17]
  [17] Y.Zeng,X.Wang,H.Wang,et al.,Multi-shelled titania hollow spheres fabricated by a hard template strategy:enhanced photocatalytic activity,Chem.Commun. 46(2010)4312-4314.
18. [18]
  [18] J.Guan,F.Mou,Z.Sun,et al.,Preparation of hollow spheres with controllable interior structures by heterogeneous contraction,Chem.Commun.46(2010) 6605-6607.
19. [19]
  [19] F.Z.Mou,J.G.Guan,W.D.Shi,et al.,Oriented contraction:a facile nonequilibrium heat-treatment approach for fabrication of maghemite fiber-in-tube and tube-in-tube nanostructures,Langmuir 26(2010)15580-15585.
20. [20]
  [20] W.Cho,Y.H.Lee,H.J.Lee,et al.,Multi ball-in-ball hybrid metal oxides,Adv.Mater. 23(2011)1720-1723.
21. [21]
  [21] X.Lai,J.Li,B.A.Korgel,et al.,General synthesis and gas-sensing properties of multiple-shell metal oxide hollow microspheres,Angew.Chem.Int.Ed.50(2011) 2738-2741.
22. [22]
  [22] X.Wu,G.Q.Lu,L.Wang,Shell-in-shell TiO₂ hollow spheres synthesized by one-pot hydrothermal method for dye-sensitized solar cell application,Energy Envi-ron.Sci.4(2011)3565-3572.
23. [23]
  [23] Y.L.Ding,X.B.Zhao,J.Xie,et al.,Double-shelled hollow microspheres of LiMn₂O₄ for high-performance lithium ion batteries,J.Mater.Chem.21 (2011)9475-9479.
24. [24]
  [24] L.Wang,Z.Lou,T.Fei,et al.,Zinc oxide core-shell hollow microspheres with multi-shelled architecture for gas sensor applications,J.Mater.Chem.21(2011) 19331-19336.
25. [25]
  [25] L.Zhou,D.Zhao,X.W.Lou,Double-shelled CoMn₂O₄ hollow microcubes as high-capacity anodes for lithium-ion batteries,Adv.Mater.24(2012)745-748.
26. [26]
  [26] Z.Dong,X.Lai,J.E.Halpert,et al.,Accurate control of multishelled ZnO hollow microspheres for dye-sensitized solar cells with high efficiency,Adv.Mater.24 (2012)1046-1049.
27. [27]
  [27] G.Zhang,L.Yu,H.B.Wu,et al.,Formation of ZoMn₂O₄ ball-in-ball hollow microspheres as a high-performance anode for lithium-ion batteries,Adv.Mater. 24(2012)4609-4613.
28. [28]
  [28] H.L.Xu,W.Z.Wang,Template synthesis of multishelled Cu₂O hollow spheres with a single-crystalline shell wall,Angew.Chem.Int.Ed.46(2007)1489-1492.
29. [29]
  [29] H.L.Xu,W.Z.Wang,L.Zhou,A growth model of single crystalline hollow spheres: oriented attachment of Cu₂O nanoparticles to the single crystalline shell wall, Cryst.Growth Des.8(2008)3486-3489.
30. [30]
  [30] W.Z.Wang,Y.Tu,P.C.Zhang,et al.,Surfactant-assisted synthesis of double-wall Cu₂O hollow spheres,CrystEngComm1(2011)1838-1842.
31. [31]
  [31] X.Wang,X.Wu,Y.Guo,et al.,Synthesis and lithium storage properties of Co₃O₄ nanosheet-assembled multishelled hollow spheres,Adv.Funct.Mater.20(2010) 1680-1686.
32. [32]
  [32] X.Wang,Y.Zhong,T.Zhai,et al.,Multishelled Co₃O₄-Fe₃O₄ hollow spheres with even magnetic phase distribution:synthesis,magnetic properties and their application in water treatment,J.Mater.Chem.21(2011)17680-17687.
33. [33]
  [33] W.Ostwald,On the assumed isomerism of red and yellow mercury oxide and the surface-tension of solid bodies,Z.Phys.Chem.34(1900)495-503.
34. [34]
  [34] J.Liu,H.Xia,D.Xue,et al.,Double-shelled nanocapsules of V2O5-based composites as high-performance anode and cathode materials for Li ion batteries,J.Am. Chem.Soc.131(2009)12086-12087.
35. [35]
  [35] J.J.Ma,K.Qian,W.X.Huang,et al.,Facile one-step synthesis of double-shelled CeO₂ hollow spheres and their optical and catalytic properties,Bull.Chem.Soc. Jpn.83(2010)1455-1461.
36. [36]
  [36] L.Han,R.Liu,C.Li,et al.,Controlled synthesis of double-shelled CeO₂ hollow spheres and enzyme-free electrochemical bio-sensing properties for uric acid,J. Mater.Chem.22(2012)17079-17085.
37. [37]
  [37] P.Hu,N.Han,X.Zhang,et al.,Fabrication of ZnO nanorod-assembled multishelled hollow spheres and enhanced performance in gas sensor,J.Mater.Chem.21 (2011)14277-14284.
38. [38]
  [38] J.Wu,D.Xue,Hierarchical integration of ZnO nanocrystals into multishelled superstructures,Nanosci.Nanotechnol.Lett.3(2011)371-377.
39. [39]
  [39] Y.Xiong,B.Wiley,J.Chen,et al.,Corrosion-based synthesis of single-crystal Pd nanoboxes and nanocages and their surface plasmon properties,Angew.Chem. Int.Ed.44(2005)7913-7917.
40. [40]
  [40] D.Kim,J.Park,K.Ået al.,Synthesis of hollow iron nanoframes,J.Am.Chem.Soc. 129(2007)5812-5813.
41. [41]
  [41] X.Wang,H.Fu,A.Peng,et al.,One-pot solution synthesis of cubic cobalt nanoskeletons,Adv.Mater.21(2009)1636-1640.
42. [42]
  [42] C.J.Jia,L.D.Sun,Z.G.Yan,et al.,Iron oxide tube-in-tube nanostructures,J.Phys. Chem.C 111(2007)13022-13027.
43. [43]
  [43] Z.C.Wu,M.Zhang,K.Yu,et al.,Self-assembled double-shelled ferrihydrite hollow spheres with a tunable aperture,Chem.Eur.J.14(2008)5346-5352.
44. [44]
  [44] X.Wang,M.Liao,Y.Zhong,et al.,ZnO hollow spheres with double-yolk egg structure for high-performance photocatalysts and photodetectors,Adv.Mater. 24(2012)3421-3425.
45. [45]
  [45] J.Qian,P.Liu,Y.Xiao,et al.,TiO₂-coated multilayered SnO₂ hollow microspheres for dye-sensitized solar cells,Adv.Mater.21(2009)3663-3667.
46. [46]
  [46] J.H.Ju,K.S.Ryu,Synthesis and performance of CuO with C complex hollow structure as anode material for lithium secondary batteries,J.Electrochem. Soc.158(2011)A814-A817.
47. [47]
  [47] H.Zhang,Q.Zhu,Y.Zhang,et al.,One-pot synthesis and hierarchical assembly of hollow Cu₂O microspheres with nanocrystals-composed porous multishell and their gas-sensing properties,Adv.Funct.Mater.17(2007)2766-2771.
48. [48]
  [48] J.Cao,Y.C.Zhu,L.Shi,et al.,Double-shelled Mn₂O₃ hollow spheres and their application in water treatment,Eur.J.Inorg.Chem.26(2010)1172-1176.
1. [1]
  Yaxin Sun , Huiyu Li , Shiquan Guo , Congju Li . Metal-based cathode catalysts for electrocatalytic ORR in microbial fuel cells: A review. Chinese Chemical Letters, 2024, 35(5): 109418-. doi: 10.1016/j.cclet.2023.109418
2. [2]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
3. [3]
  Yulong Shi , Fenbei Chen , Mengyuan Wu , Xin Zhang , Runze Meng , Kun Wang , Yan Wang , Yuheng Mei , Qionglu Duan , Yinghong Li , Rongmei Gao , Yuhuan Li , Hongbin Deng , Jiandong Jiang , Yanxiang Wang , Danqing Song . Chemical construction and anti-HCoV-OC43 evaluation of novel 10,12-disubstituted aloperine derivatives as dual cofactor inhibitors of TMPRSS2 and SR-B1. Chinese Chemical Letters, 2024, 35(5): 108792-. doi: 10.1016/j.cclet.2023.108792
4. [4]
  Huiju Cao , Lei Shi . sp¹-Hybridized linear and cyclic carbon chain. Chinese Chemical Letters, 2025, 36(4): 110466-. doi: 10.1016/j.cclet.2024.110466
5. [5]
  Jia Fu , Shilong Zhang , Lirong Liang , Chunyu Du , Zhenqiang Ye , Guangming Chen . PEDOT-based thermoelectric composites: Preparation, mechanism and applications. Chinese Chemical Letters, 2024, 35(9): 109804-. doi: 10.1016/j.cclet.2024.109804
6. [6]
  Haojie Song , Laiyu Luo , Siyu Wang , Guo Zhang , Baojiang Jiang . Advances in poly(heptazine imide)/poly(triazine imide) photocatalyst. Chinese Chemical Letters, 2024, 35(10): 109347-. doi: 10.1016/j.cclet.2023.109347
7. [7]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
8. [8]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
9. [9]
  Tiantian Zheng , Huiyi Wang , Huimin Li , Xuanhe Liu , Hong Shang . Anti-Counterfeiting National Salvation Chronicle of 006. University Chemistry, 2024, 39(9): 254-258. doi: 10.3866/PKU.DXHX202307032
10. [10]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
11. [11]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
12. [12]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
13. [13]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
14. [14]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
15. [15]
  Jimin HOU , Mengyang LI , Chunhua GONG , Shaozhuang ZHANG , Caihong ZHAN , Hao XU , Jingli XIE . Synthesis, structures, and properties of metal-organic frameworks based on bipyridyl ligands and isophthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 549-560. doi: 10.11862/CJIC.20240348
16. [16]
  Ning Zhang , Mengjie Qin , Jiawen Zhu , Xuejing Lou , Xiao Tian , Wende Ma , Youmei Wang , Minghua Lu , Zongwei Cai . Thickness-controllable synthesis of metal-organic framework based hollow nanoflowers with magnetic core via liquid phase epitaxy for phosphopeptides enrichment. Chinese Chemical Letters, 2025, 36(4): 110177-. doi: 10.1016/j.cclet.2024.110177
17. [17]
  Xiaomeng Hu , Jie Yu , Lijie Sun , Linfeng Zhang , Wei Zhou , Dongpeng Yan , Xinrui Wang . Synthesis of an AVB@ZnTi-LDH composite with synergistically enhance UV blocking activity and high stability for potential application in sunscreen formulations. Chinese Chemical Letters, 2024, 35(11): 109466-. doi: 10.1016/j.cclet.2023.109466
18. [18]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
19. [19]
  Tao Zhou , Jing Zhou , Yunyun Liu , Jie-Ping Wan , Fen-Er Chen . Transition metal-free tunable synthesis of 3-(trifluoromethylthio) and 3-trifluoromethylsulfinyl chromones via domino C–H functionalization and chromone annulation of enaminones. Chinese Chemical Letters, 2024, 35(11): 109683-. doi: 10.1016/j.cclet.2024.109683
20. [20]
  Wenxuan Yang , Long Shang , Xiaomeng Liu , Sihan Zhang , Haixia Li , Zhenhua Yan , Jun Chen . Ultrafast synthesis of nanocrystalline spinel oxides by Joule-heating method. Chinese Chemical Letters, 2024, 35(11): 109501-. doi: 10.1016/j.cclet.2024.109501

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(702)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142