基于柔性四羧酸及4,4'-联吡啶的sqc422型钴(Ⅱ(Ⅱ)配位聚合物

邱文革 邓芳 刘虎冰 訾学红 张桂臻 何洪 李建荣

引用本文: 邱文革, 邓芳, 刘虎冰, 訾学红, 张桂臻, 何洪, 李建荣. 基于柔性四羧酸及4,4'-联吡啶的sqc422型钴(Ⅱ(Ⅱ)配位聚合物[J]. 无机化学学报, 2013, 29(10): 2021-2026. doi: 10.3969/j.issn.1001-4861.2013.00.335 shu
Citation:  QIU Wen-Ge, DENG Fang, LIU Hu-Bing, ZI Xue-Hong, ZHANG Gui-Zhen, HE Hong, LI Jian-Rong. A sqc422-Type Coordination Polymer Based on Flexible Tetracarboxylate and 4,4'-Bipyridine Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(10): 2021-2026. doi: 10.3969/j.issn.1001-4861.2013.00.335 shu

基于柔性四羧酸及4,4'-联吡啶的sqc422型钴(Ⅱ(Ⅱ)配位聚合物

  • 基金项目:

    国家自然科学基金(No.21007002)资助项目。 (No.21007002)

摘要: 采用水热法合成了一种基于1,3-二[3,5-(二羧基)苯氧基]-2-羟基丙烷(H4L)和4,4'-联吡啶(Bipy)的Co(Ⅱ(Ⅱ)配合物:[Co2(L)(Bipy)2]n(1),并利用红外光谱(IR)、紫外-可见光谱(UV-Vis)、热重分析(TGA)、单晶X-射线衍射、粉末X射线衍射(XRD)及元素分析对其结构进行了表征。配合物1属单斜晶系,C2/c空间群。在配合物1中,由2个六配位钴原子组成的双核原子簇可简化为八面体型6-连接点,连接4个羧酸配体分子L和其他2个双核原子簇。羧酸配体L可简化为四面体型4-连接点,连接4个双核原子簇。平行排列的2个联吡啶分子连接两个相邻双核原子簇,相当于“双桥”,简化为拓扑回路的边。因此,配合物1的骨架描述为sqc422拓扑网络。

English

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  • 收稿日期:  2013-01-04
  • 网络出版日期:  2013-05-27
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