Citation: JIAO Shuke, LU Chongxian, JIANG Jian. CONFIGURATION OF VO(OR)2Cl-Al(i-Bu)3 CATALYST SYSTEM AND CHARGE DISTRIBUTION OF VANADIUM CENTRAL ION[J]. Chinese Journal of Polymer Science, ;1987, 5(1): 66-75. shu

CONFIGURATION OF VO(OR)2Cl-Al(i-Bu)3 CATALYST SYSTEM AND CHARGE DISTRIBUTION OF VANADIUM CENTRAL ION

Received Date: 1 April 1986

According to the caiculation of quantum chemistry it come be deduced that conngurauons or the catalysts VO(OR)2Cl-Al (i-Bu)3, for the alternating Copolymerization of butadiene with propene, the highest reactive configuration was A. When the catalyst complex forms the configuration A, the energy of the system was the lowest; the central vanadium atom had relatively high positive charge and whose frontier orbital overlapped easily with the frontier orbital of butadiene to form coordination complex, so it was concluded from the experimental results and calculations that the configuration of the catalyst of relatively high actibity was A.
1. [1]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
2. [2]
  Le Li , Shaofeng Jia , Shi Yue , Yuanyuan Yang , Chao Tan , Conghui Wang , Hengwei Qiu , Yongqiang Ji , Minghui Cao , Zige Tai , Dan Zhang . Vanadium doping inhibit the Jahn−Teller effect of Mn³⁺ for high-performance aqueous zinc ion battery. Chinese Chemical Letters, 2025, 36(10): 111009-. doi: 10.1016/j.cclet.2025.111009
3. [3]
  Yan Zhao , Zhenming Tian , Qisen Jia , Ting Yao , Jiashu Li , Yanan Wang , Xuejing Cui , Jing Liu , Xin Chen , Luhua Jiang . Crystal orientation dependent charge transfer dynamics and interfacial water configuration boosting photoelectrocatalytic water oxidation to H2O2. Chinese Journal of Structural Chemistry, 2025, 44(7): 100619-100619. doi: 10.1016/j.cjsc.2025.100619
4. [4]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
5. [5]
  Guanyang Zeng , Xingqiang Liu , Liangqiao Wu , Zijie Meng , Debin Zeng , Changlin Yu . Novel visible-light-driven I- doped Bi2O2CO3 nano-sheets fabricated via an ion exchange route for dye and phenol removal. Chinese Journal of Structural Chemistry, 2024, 43(12): 100462-100462. doi: 10.1016/j.cjsc.2024.100462
6. [6]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
7. [7]
  Yutong Chen , Shuting Guo , Mingrui Fan , Songlin Yang , Qiuxia Lin , Jiafeng Zou , Junyuan Xu , Tongtong Zheng , Kangtai He , Feng Gao , Yanzuo Chen . Exosome-liposome hybrid system with antioxidant and anti-inflammatory activities targeting glial cells for the treatment of central nervous system diseases. Chinese Chemical Letters, 2026, 37(9): 112027-. doi: 10.1016/j.cclet.2025.112027
8. [8]
  Yuhan Wu , Qing Zhao , Zhijie Wang . Layered vanadium oxides: Promising cathode materials for calcium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(5): 100271-100271. doi: 10.1016/j.cjsc.2024.100271
9. [9]
  Yumei Wu , Wenbin Li , Qi Dong , Jianhua Zhang , Xing Huang , Haofei Yang , Siwen Zhang , Jingjing Wang , Xifei Li . Synergistic pre-intercalation and coating engineering to realize stable Zn²⁺/H⁺ storage in vanadium oxide cathodes for zinc-ion batteries. Chinese Chemical Letters, 2026, 37(9): 111456-. doi: 10.1016/j.cclet.2025.111456
10. [10]
  Huahong ZHANG , Yang ZHAO , Rui NING , Shuixing WU , Xiaopeng ZHANG . Coordination equilibrium between cyclometalated Pt(Ⅱ) complexs [Pt(κ³-N^C^N′)(CNXyl)]Cl and [Pt(κ²-N^C^N′)(CNXyl)Cl]. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1840-1850. doi: 10.11862/CJIC.20250136
11. [11]
  Gang Hu , Chun Wang , Qinqin Wang , Mingyuan Zhu , Lihua Kang . The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein. Chinese Chemical Letters, 2025, 36(2): 110298-. doi: 10.1016/j.cclet.2024.110298
12. [12]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
13. [13]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
14. [14]
  Shuhao FENG , Feibing XIONG , Yaqing LIN , Han SU , Xu HAN . Preparation and luminescent properties of alkaline metal doped Cd₃Al₂Ge₃O₁₂: Pr³⁺ orange phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 284-296. doi: 10.11862/CJIC.20250171
15. [15]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
16. [16]
  Qiyue Luo , Chen Liu , Siwu Li , Chaochao Wei , Zhongkai Wu , Lin Li , Ziling Jiang , Liping Li , Guangshe Li , Shijie Cheng , Chuang Yu . Charge carrier distribution enabling superior electrochemical performance for all-solid-state lithium batteries over wide temperature range. Chinese Chemical Letters, 2026, 37(7): 111113-. doi: 10.1016/j.cclet.2025.111113
17. [17]
  Fuhong WAN , Zhaosheng LI , Jian CUI , Xin SU , Yi′neng HUANG . First-principles study of the cation size effect on birefringence in K₃RE(VO₄)₂ (RE=Sc, Y, La, Lu). Chinese Journal of Inorganic Chemistry, 2026, 42(8): 1658-1668. doi: 10.11862/CJIC.20260009
18. [18]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
19. [19]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
20. [20]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1750)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return