Citation: Fangyuan Liu, Luyi Xu, Yang Xiu, Shengjie Wang. Non-Metallic Element Doped Titanium Dioxide[J]. Chemistry, ;2021, 84(2): 108-119, 148. shu

Non-Metallic Element Doped Titanium Dioxide

College of Chemical Engineering, China University of Petroleum, Qingdao, 266580

Corresponding author: Shengjie Wang, sjwang@upc.edu.cn
Received Date: 16 July 2020
Accepted Date: 1 September 2020

Figures(9)

Titanium dioxide attracts great attentions for its important applications in many fields, especially in photoelectronic conversion and photocatalysis due to its excellent light stability, non-toxicity and easy preparation. However, its relatively poor charge transport property and wide bandgap are two main limitations for its extensive application in light-responsive materials. To meet such challenges, two strategies including ion doping and going nanoscale are used and demonstrated to be effective in regulating its band gap structure and charge transport behavior. Ion doping can be divided into two categories, metal doping and nonmetal doping, according to the properties of the impurity elements. Besides, compared with traditional titanium dioxide, nano-sized titanium dioxide possesses larger surface areas and special nanosized effect, resulting in higher chemical activity and heat resistance. In this review, we focused on the research progress of non-metallic element doped titanium dioxide. Emphases was put on the relationship within the doping element, the band gap structure, visible light responsibility and photocatalytic performance of the hybrid titanium dioxide. Additionally, the application of non-metallic element doped titanium dioxide was also involved.
- Titanium dioxide,
- Non-metal doping,
- Band gap structure,
- Photoelectric conversion,
- Photocatalysis
1. [1]
  Hamad D, Dhib R, Mehrvar M. J. Polym. Environ., 2016, 24(1): 72~83.
2. [2]
  Bustillo-Lecompte C F, Ghafoori S, Mehrvar M. J. Environ. Chem. Eng., 2016, 4(1): 719~732.
3. [3]
  Nasirian M, Lin Y P, Bustillo-Lecompte C F, et al. Int. J. Environ. Sci. Technol., 2018, 15(9): 2009~2032.
4. [4]
  Malakootian M, Mesdaghinia A, Rezaei S. Journal of Kerman University of Medical Sciences, 2017, 24(2): 147~158.
5. [5]
  Wang S Q, Liu W B, Fu P, et al. Korean J. Chem. Eng., 2017, 34(5): 1584~1590.
6. [6]
  Chen D, Caruso R A. Adv. Funct. Mater., 2013, 23(11): 1356~1394.
7. [7]
  Wang H, Miyauchi M, Ishikawa Y, et al. J. Am. Chem. Soc., 2011, 133(47): 19102~19109.
8. [8]
  Su J J, Li Z D, Zhang Y Q, et al. RSC Adv., 2016, 6(20): 16177~16182.
9. [9]
  Ma Y, Wang X, Jia Y, et al. Chem. Rev., 2014, 114(19): 9987~10043.
10. [10]
  Abdelhaleem A, Chu W. Chem. Eng. J., 2018, 338(15): 411~421.
11. [11]
  Shehzad N, Tahir M, Johari K, et al. J. CO₂ Util., 2018, 26: 98~122.
12. [12]
  Sinhamahapatra A, Jeon J P, Yu J S. Energ. Environ. Sci., 2015, 8(12): 3539~3544.
13. [13]
  Zheng X Z, Li D Z, Li X F, et al. Appl. Catal. B, 2015, 168~169: 408~415.
14. [14]
  Khaki M R D, Shafeeyan M S, Raman A A A, et al. J. Environ. Manag., 2017, 198(2): 78~94.
15. [15]
  Huang L W, Fu W Y, Zhang Z Y. Mater. Lett., 2017, 209(15): 585~588.
16. [16]
  Behnajadym A, Eskandarloo H. Chem. Eng. J., 2013, 228(15): 1207~1213.
17. [17]
  Todorova N, Giannakopoulou T, Romanos G, et al. Int. J. Photoenergy, 2008, 534038.
18. [18]
  Mao C Y, Zuo F, Hou Y, et al. Angew. Chem. Int. Ed., 2014, 53(39): 10485~10489.
19. [19]
  Shayegan Z, Lee C S, Haghighat F. Chem. Eng. J., 2018, 334(15): 2408~2439.
20. [20]
  Yun J Y, Hwang S H, Jang J. ACS Appl. Mater. Inter., 2015, 7(3): 2055~2063.
21. [21]
  Wei Z, Janczarek M, Endo M, et al. Appl. Catal. B, 2018, 237(5): 574~587.
22. [22]
  Xie F Y, Li Y F, Dou J, et al. J. Power Sources, 2016, 336(30): 143~149.
23. [23]
  Sengupta D, Das P, Mondal B, et al. Renew. Sustain. Energ. Rev., 2016, 60: 356~376.
24. [24]
  Altin I, Sokmen M, Biykloglu Z. Desalin. Water Treat., 2016, 57(34): 16196~16207.
25. [25]
  Shao G S. J. Phys. Chem. C, 2009, 113(16): 6800~6808.
26. [26]
  Pap Z, Baia L, Mogyorósi K, et al. Catal. Commun., 2012, 17(5): 1~7.
27. [27]
  Mulmi D D, Thapa D, Dahal B, et al. Int. J. Mater. Sci. Eng., 2016, 4(3): 172~178.
28. [28]
  Zou M M, Xiong F Q, Ganeshraja A S, et al. Mater. Chem. Phys., 2017, 195(1): 259~267.
29. [29]
  Primc D, Bartsch M, Barreca D, et al. Sustain. Energy Fuels, 2017, 1(1): 199~206.
30. [30]
  Foura G, Chouchou N, Soualah A, et al. Catalysts, 2017, 7(11): 344.
31. [31]
  Freyria F S, Compagnoni M, Ditaranto N, et al. Catalysts, 2017, 7(7): 213.
32. [32]
  Shiba K, Kataoka T, Okuda M, et al. Royal Soc. Chem. Adv., 2016, 6(61): 55750~55754.
33. [33]
  Husain S, Alkhtaby L A, Giorgetti E, et al. J. Luminescence, 2016, 172: 258~263.
34. [34]
  Crisan M, Rǎileanu M, Drǎgan N, et al. Appl. Catal. A, 2015, 504(5): 130~142.
35. [35]
  Santos R d S, Faria G A, Giles C, et al. ACS Appl. Mater. Inter., 2012, 4(10): 5555~5561.
36. [36]
  Hinojosa-Reyes M, Camposeco-Olis R, Zanella R, et al. Chemosphere, 2017, 184: 992~1002.
37. [37]
  Obregon S, Lee S W, Rodriguez-gonzalez Ⅴ. Mater. Lett., 2016, 173(15): 174~177.
38. [38]
  Pham T D, Lee B K. Appl. Surf. Sci., 2014, 296(30): 15~23.
39. [39]
  Zhi J T, Yu X Q, Bao J J, et al. Korean J. Chem. Eng., 2016, 33(6): 1823~1830.
40. [40]
  Praveen P, Viruthagiri G, Mugundan S, et al. Spectrochim. Acta A, 2014, 120(24): 548~557.
41. [41]
  Ning X W, Wang X X, Yu X F, et al. J. Alloys Compd., 2016, 658(15): 177~182.
42. [42]
  Tshabalala Z P, Shingange K, Cummings F R, et al. J. Colloid Interf. Sci., 2017, 504(15): 371~386.
43. [43]
  Salazar-villanueva M, Cruz-López A, Zaldívar-Cadena A A, et al. Mater. Sci. Semicon. Proc., 2017, 58: 8~14.
44. [44]
  Wu M C, Chan S H, Jao M H, et al. Solar Energy Mater. Solar Cells, 2016, 157: 447~453.
45. [45]
  Nair R G, Mazumdar S, Modak B, et al. J. Photochem. Photobiol. A, 2017, 345(1): 36~53.
46. [46]
  Sui R H, Yong J L, Berlinguette C P. J. Mater. Chem., 2010, 20(3): 498~503.
47. [47]
  Lübke M, Johnson L, Makwana N M, et al. J. Power Sources, 2015, 294(30): 94~102.
48. [48]
  Li J L, Xu X T, Liu X J, et al. J. Alloys Compd., 2016, 679(15): 454~462.
49. [49]
  Cai Q B, Zhang Y Q, Liang C, et al. Electrochim. Acta, 2018, 261, (20): 227~235.
50. [50]
  Inturi S N R, Boningari T, Suidan M, et al. Appl. Catal. B, 2014, 144: 333~342.
51. [51]
  Bhethanabotal V C, Russell D R, Kuhn J N. Appl. Catal. B, 2017, 201: 156~164.
52. [52]
  Mazierski P, Mikolajczyk A, Bajorowicz B, et al. Appl. Catal. B, 2018, 233(5): 301~317.
53. [53]
  Shwetharani R, Sakar M, Fernando C A N, et al. Catal. Sci. Technol., 2019, 9(1): 12~46.
54. [54]
  Gao H T, Liu Y Y, Ding C H, et al. Int. J. Min. Metal. Mater., 2011, 18(5): 606~614.
55. [55]
  Zhang Q Y, Li Y, Ackerman E A, et al. Appl. Catal. A, 2011, 400: 195~202.
56. [56]
  Cho I S, Lee C H, Feng Y Z, Logar M, Rao P M, Cai L L, Kim D R, Sinclair R, Zheng X L. Nat. Commun., 2014, 5: 3204.
57. [57]
  Lu N, Quan X, Li J Y, et al. J. Phys. Chem. C, 2007, 111(32): 11836~11842.
58. [58]
  Simsek E B. Appl. Catal. B, 2017, 200: 309~322.
59. [59]
  Wang Y, Jia K, Pan Q, et al. ACS Sustain. Chem. Eng., 2019, 7(1): 117~122.
60. [60]
  Xiao Q, Ouyang L L. Chem. Eng. J., 2009, 148(2/3): 248~253.
61. [61]
  Lee Y F, Chang K H, Hu C C, et al. J. Mater. Chem., 2010, 20: 5682~5688.
62. [62]
  Sakthivel S, Kisch H. Angew. Chem. Int. Ed., 2003, 42(40): 4908~4911.
63. [63]
  Warkhade S W, Warkhade G S, Zodape S P, et al. Mater. Sci. Semicon. Proc., 2017, 63(1): 18~24.
64. [64]
  Zhou Q X, Xing A, Zhao D C, et al. Chemosphere, 2016, 165: 268~276.
65. [65]
  Li W J, Liang R, Zhou N Y, et al. ACS Omega, 2020, 5(17): 10042~10051.
66. [66]
  Huang M, Yu J H, Hu Q, et al. Appl. Surf. Sci., 2016, 389(15): 1084~1093.
67. [67]
  Bao N, Wei Z T, Ma Z H, et al. J. Hazard. Mater., 2010, 174(1/2/3): 129~136.
68. [68]
  Guo J F, Li S M, Duan L, et al. Integr. Ferroelectr., 2016, 168(1): 170~182.
69. [69]
  Chen C L, Wei Y L, Yuan G Z, et al. Adv. Funct. Mater., 2017, 27(31): 1701575.
70. [70]
  Du J, Li X Y, Li K, et al. J. Alloys Compd., 2016, 687(5): 893~897.
71. [71]
  Ansari S A, Khan M M, Ansari M O, et al. New J. Chem., 2016, 40: 3000~3009.
72. [72]
  Wang G M, Xiao X H, Li W Q, et al. Nano Lett., 2015, 15(7): 4692~4698.
73. [73]
  Asahi R, Morikawa T, Ohwaki T, et al. Science, 2001, 293(5528): 269~271.
74. [74]
  Kong X L, Peng Z B, Jia P P, et al. ACS Appl. Nano Mater. 2020, 3(2): 1373~1381.
75. [75]
  Kumar M P, Jagannathan R, Ravichandran S. Energy Fuels, 2020, 34(7): 9030~9036.
76. [76]
  Jiang G M, Cao J W, Chen M, et al. Appl. Surf. Sci., 2018, 458: 77~85.
77. [77]
  Gopal N O, Lo H H, Ke T F, et al. J. Phys. Chem. C, 2012, 116(30): 16191~16197.
78. [78]
  Feng X Y, Wang P F, Hou J, et al. J. Hazard. Mater., 2018, 351: 196~205.
79. [79]
  Feng H J, Zhang M H, Yu L E. J. Nanosci. Nanotechnol., 2013, 13(7): 4981~4989.
80. [80]
  Hosseinzadeh G, Rasoulnezhad H, Ghasemian N, et al, J. Aust. Ceram. Soc., 2019, 55(2): 387~394.
81. [81]
  Ni J F, Fu S D, Wu C, et al. Adv. Mater., 2016, 28(11): 2259~2265.
82. [82]
  Zhang Y, He X R, Tang J H, et al. ACS Appl. Mater. Inter., 2019, 11(47): 44170~44178.
83. [83]
  Wang W L, Wang Z F, Liu J J, et al. Sci. Rep., 2017, 7: 46610.
84. [84]
  Gurkan Y Y, Cinar Z. Chem. Eng. J., 2013, 214(1): 34~44.
85. [85]
  Xie W, Li R, Xu Q U. Sci. Rep., 2018, 8: 8752.
86. [86]
  Zheng J W, Bhattcahrayya A, Wu P, et al. J. Phys. Chem., 2010, 114(15): 7063~7069.
87. [87]
  Yu J C, Yu J G, Ho W K, et al. Chem. Mater., 2002, 14(9): 3808~3816.
88. [88]
  Xu J J, Ao Y H, Fu D G, et al. J. Phys. Chem. Solids, 2008, 69(10): 2366~2370.
89. [89]
  Zhang X Q, Wu Y P, Huang Y, et al. J. Alloys Compd., 2016, 681: 191.
90. [90]
  Wu G S, Wang J P, Thomas D F, et al. Langmuir, 2008, 24(7): 3503~3509.
91. [91]
  Wang X K, Wang C, Jiang W Q, et al. Chem. Eng. J., 2013, 189/190: 288~294.
92. [92]
  Xu H, Zhang Z, Zhang L Z, Zet al. J. Solid State Chem., 2008, 181(9): 2516~2522.
93. [93]
  Moitzheim S, Balder J E, Poodt P, et al. Chem. Mater., 2017, 29(23): 10007~10018.
94. [94]
  Liu G, Sun C H, Yan X X, et al. J. Mater. Chem., 2009, 19: 2822~2829.
95. [95]
  Chen D M, Jiang Z Y, Geng J Q, et al. Ind. Eng. Chem. Res., 2007, 46(9): 2271~2746.
96. [96]
  Mani A D, Muthusamy S, Anadan S, et al. J. Exp. Nanosci., 2015, 10: 115~125.
97. [97]
  Zhu H, Jing Y, Pal M, et al. Nanoscale, 2017, 9: 1539~1546.
98. [98]
  El-Sheikh S M, Khedr T M, Hakki A, et al. Sep. Purif. Technol., 2017, 173: 258~268.
99. [99]
  Luo H M, Takata T, Lee Y, et al. Chem. Mater., 2004, 16(5): 846~849.
100. [100]
  Elbanna O, Zhang P, Fujitsuka M, et al. Appl. Catal. B, 2016, 192: 80~87.
101. [101]
  Chen D M, Jiang Z Y, Geng J Q, et al. J. Nanopart. Res., 2009, 11(2): 303~313.
102. [102]
  Mukherjee K, Acharya K, Biswas A, et al. ACS Appl. Nano Mater., 2020, 3(2): 2016~2025.
103. [103]
  Siddiqa A, Masih D, Anjum D, et al. J. Environ. Sci., 2015, 37: 100~109.
104. [104]
  Hamadanian M, Reisi-Vanani A, Behpour M, et al. Desalination, 2011, 381(17): 319~324.
105. [105]
  Bessergenev V G, Mateus M C, Vasconcelos D A, et al. International J. Photoenergy, 2012, 767054.
106. [106]
  Dong F, Guo S, Wang H Q, Let al. J. Phys. Chem. C, 2011, 115(27): 13285~13292.
107. [107]
  Zhao Y X, Zhao X F, Run S, et al. Adv. Mater., 2019, 31(16): 1806482.
108. [108]
  Dong F, Wang H, Wu Z. J. Phys. Chem. C, 2009, 113(38): 16717~16723.
109. [109]
  Rami R D, Joyashish D, Vijayamohanan K, et al. Sci. Rep., 2015, (4): 4897.
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