Citation: WU Xian-shuang, HE Fang, WEI Guo-qiang, HUANG Zhen, ZHAO Kun, MENG Jun-guang, ZHAO Zeng-li, LI Hai-bin. Performance evaluation of Fe-Ni compound oxygen carriers derived from biochar template for chemical looping hydrogen generation[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(4): 500-512. shu

Performance evaluation of Fe-Ni compound oxygen carriers derived from biochar template for chemical looping hydrogen generation

WU Xian-shuang ^1,2,3 ,
HE Fang ^1,3,, ,
WEI Guo-qiang ^1,3 ,
HUANG Zhen ^1,3 ,
ZHAO Kun ^1,3 ,
MENG Jun-guang ^1,2,3 ,
ZHAO Zeng-li ^1,3 ,
LI Hai-bin ^1,3

1.
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou 510640, China

Corresponding author: HE Fang, hefang@ms.giec.ac.cn
Received Date: 13 December 2017
Revised Date: 12 March 2018

Fund Project: the Science and Technology Program of Guangzhou 201707010202The project was supported by the Science & Technology Research Project of Guangdong Province (2015A010106009, 2015A020215023) and the Science and Technology Program of Guangzhou (201707010202)the Science & Technology Research Project of Guangdong Province 2015A020215023the Science & Technology Research Project of Guangdong Province 2015A010106009

Figures(13)

Fe-Ni oxygen carriers (Fe-Ni/BC) were prepared by using pine biochar as a template, and compared with NiFe₂O₄ oxygen carriers synthesized by sol-gel method. The obtained oxygen carriers were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) surface area measurement, hydrogen-temperature programmed reduction (H₂-TPR), and thermos-gravimetric redox-cycling (TG-redox). Furthermore, the performance of chemical looping hydrogen generation was investigated in a fixed-bed reactor. The results show that the prepared Fe-Ni/BC is a mixed crystal of Ni_0.6Fe_2.4O₄ and Fe₂O₃, retaining the framework of biochar and having a macroporous structure. Fe-Ni/BC outperforms NiFe₂O₄/SG in oxygen release, because of small average particle size, high specific surface area and abundant surface absorbed oxygen. In the fixed-bed tests, Fe-Ni/BC exhibits a better capability of hydrogen production and anti-carbon deposition with the maximum rate of hydrogen production for Fe-Ni/BC, 1.58 times that for NiFe₂O₄/SG, and the relative concentration of H₂ produced by Fe-Ni/BC is more than 99.5%.
- biochar,
- oxygen carrier,
- chemical looping hydrogen generation
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