Citation: MEI Li-bin, LIU Xin-min. Preparation, characterization and CO₂ adsorption of ion exchange resin supported solid amine adsorbents[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 880-888. shu

Preparation, characterization and CO₂ adsorption of ion exchange resin supported solid amine adsorbents

MEI Li-bin ,
LIU Xin-min ^*,,

Qingdao University of Science & Technology, Qingdao 266042, China

Corresponding author: LIU Xin-min, lxm220@qust.edu.cn
Received Date: 8 March 2017
Revised Date: 6 May 2017

Fund Project: the Shandong Province Science and Technology Development Project 2010GGX10709

Figures(10)

A series of solid amine adsorbents were prepared by using three different preparation methods with ion exchange resin (D001) as carrier and with tetraethylenepentamine (TEPA) as modifier. The sorbents were characterized by nitrogen adsorption/desorption, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA) techniques. The effects of TEPA loadings, adsorption temperatures, influent gas flow rates and CO₂ partial pressure on the CO₂ adsorption capacity in a fixed bed reactor were investigated. The results show that the solid amine adsorbent prepared by the coordination method has a better dispersibility and stability, and the maximum CO₂ adsorption capacity is 4 mmol/g when the TEPA loading is 40%, the adsorption temperature is 65 ℃ and the influent gas flow rate is 40 mL/min. The amount of CO₂ adsorption only decreases by 3.98% and remains almost unchanged after 10 cycles of desorption and desorption. The study of thermodynamics and kinetics indicates that the adsorption mechanism is dominated by both chemical and physical adsorption.
- ion exchange resin,
- tetraethylenepentamine,
- CO₂ adsorption
1. [1]
  TSENG R L, WU F C, JUANG R S. Adsorption of CO₂ at atmospheric pressure on activated carbons prepared from melamine-modified phenol-formaldehyde resins[J]. Sep Purif Technol, 2015,140(1):53-60.
2. [2]
  NILANTHA P W, MIETEK J. Activated carbon spheres for CO₂ adsorption[J]. ACS Appl Mater Interfaces, 2013,5(2):1849-1855.
3. [3]
  ARUNKUMAR S, ZHAO A, GEORGE K H, PARTHA S, RAJENDER G. Post-combustion CO₂ capture using solid Sorbents:A review[J]. Ind Eng Chem Res, 2012,51(10):1438-1463.
4. [4]
  FIGUEROA J D, FOUT T, PLASYNSKI S, MCILVERIED H, SRIVASTAVA R D. Advances in CO₂capture technology-The U.S. department of energy's carbon sequestration program:A review[J]. Int J Green Gas Con, 2008,2(7):9-20.
5. [5]
  WANG X, GUO Q J, KONG T T. Tetraethylenepentamine-modified MCM-41/silica gel with hierarchical mesoporous structure for CO₂capture[J]. Chem Eng J, 2015,273(3):472-480.
6. [6]
  KHATRI R A, CHUANG S C, SONG Y. Thermal and chemical stability of regenerable solid amine sorbent for CO₂ capure[J]. Energy Fuels, 2006,20(4):1514-1520. doi: 10.1021/ef050402y
7. [7]
  LIU Zhi-lin, TENG Yang, ZHANG Kai, CAO Yan, PAN Wei-ping. The CO₂adsorption and thermal stability of MCM-41 modified by different organic amines[J]. J Fuel Chem Technol, 2013,41(4):469-476.
8. [8]
  LEE S, FILBURN T P, GRAY M, PARK J W, SONG H J. Screening test of solid amine sorbents for CO₂ capture[J]. Ind Eng Chem Res, 2008,47(8):7419-7423.
9. [9]
  GRAY M L, HOFFMAN J S, HREHA D C, FAUTH D J, HEDGES S W, CHAMPAGNE K J, PENNLINE H W. Parametric study of solid amine sorbents for the capture of carbon dioxide[J]. Energy Fuels, 2009,23(9):4840-4844.
10. [10]
  ALESI W R, KITCHIN J R. Evaluation of a primary amine-functionalized ion-exchange resin for CO₂ capture[J]. Ind Eng Chem Res, 2012,51(5):6907-6915.
11. [11]
  ZHANG Xue-shi, LIU Xin-min. Preparation and performance of modified molecular sieve for carbon dioxide capture[J]. J Environ Eng, 2015,9(10):4995-4999. doi: 10.12030/j.cjee.20151060
12. [12]
  HU J X, WANG G C, JIANG T. Preparation and performance of sulphonated polystyrene[J]. Colloid Polym Sci, 2012,30(1):36-38.
13. [13]
  WANG X, CHEN L L, GUO Q J. Development of hybrid amine-functionalized MCM-41 sorbents for CO₂ capture[J]. Chem Eng J, 2015,260(9):573-581.
14. [14]
  CHEN Z H, DENG S B, WEI H R, WANG B, HUANG J, YU G. Polyethylenimine-impregnated resin for high CO₂ adsorption:An efficient adsorbent for capture from simulated flue gas and ambient air[J]. ACS Appl Mater Interfaces, 2013,5(6):6937-6945.
15. [15]
  CHEN Lin-lin, WANG Xia, GUO Qing-jie. Study on CO₂ adsorption properties of tetraethylenepentamine modified mesoporous silica gel[J]. J Fuel Chem Technol, 2015,43(1):108-115.
16. [16]
  MEILS S D, WANG S X, MARTHA A, ARLLANO T, ROBERT J F. CO₂ utilization with a novel dual function material (DFM) for capture and catalytic conversion to synthetic natural gas:An update[J]. J CO₂ Util, 2016,15(9):65-71.
17. [17]
  HUANG H Y, YANG R T, CHINN D, MUNSON C L. Amine-grafted MCM-48 and silica xerogel as superior sorbents for acidic gas removal from natural gas[J]. Ind Eng Chem Res, 2003,42(12):2427-2433. doi: 10.1021/ie020440u
18. [18]
  RODRIGO S G, ABDELHAMID S. Modeling adsorption of CO₂ on amine-functionalized mesoporous silica. 2:Kinetics and breakthrough curves[J]. Chem Eng J, 2010,161(7):182-190.
19. [19]
  LOGANATHAN S, TIKMANI M, EDUBILLI S. CO₂ adsorption kinetics on mesoporous silica under wide range of pressure and temperature[J]. Chem Eng J, 2014,256(11):1-8.
20. [20]
  ALIAKBAR H G, ABDELHAMID S. CO₂ capture on polyethylenimine-impregnated hydrophobic mesoporous silica:Experimental and kinetic modeling[J]. Chem Eng J, 2011,173(1):72-79. doi: 10.1016/j.cej.2011.07.038
1. [1]
  Xueqi Yang , Juntao Zhao , Jiawei Ye , Desen Zhou , Tingmin Di , Jun Zhang . 调节NNU-55(Fe)的d带中心以增强CO₂吸附和光催化活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100074-0. doi: 10.1016/j.actphy.2025.100074
2. [2]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-0. doi: 10.1016/j.actphy.2025.100055
3. [3]
  Wenjuan SHI , Yuke LU , Xiuyuan LI , Lei HOU , Yaoyu WANG . Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO₂ adsorption and catalytic conversion performance. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2455-2463. doi: 10.11862/CJIC.20250220
4. [4]
  Lingyu Chang , Yanfang Lang , Yuyan Zhu , Jie Wang , Ying Guo , Die Wang , Peng Ding , Yueming Zhou , Zhixiang Gong , Shujuan Liu . Machine Learning-Optimized Microcolumn Ion Exchange Chromatography for Trace Arsenic Determination. University Chemistry, 2026, 41(1): 76-84. doi: 10.12461/PKU.DXHX202506023
5. [5]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
6. [6]
  Feifan Zhao , Feiyan Xu , Jiaguo Yu . Interfacial stabilization of alkali metal oxides on carbon spheres for high-performance CO₂ chemisorption. Acta Physico-Chimica Sinica, 2026, 42(5): 100234-0. doi: 10.1016/j.actphy.2025.100234
7. [7]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
8. [8]
  Wenlong Wang , Wentao Hao , Lang He , Jia Qiao , Ning Li , Chaoqiu Chen , Yong Qin . Bandgap and adsorption engineering of carbon dots/TiO₂ S-scheme heterojunctions for enhanced photocatalytic CO₂ methanation. Acta Physico-Chimica Sinica, 2025, 41(9): 100116-0. doi: 10.1016/j.actphy.2025.100116
9. [9]
  Wenwen Ma , Lian Kong , Jinyang Chu , Li Ma , Ziqing Ma , Heyu Cheng , Xinyuan Li , Zhan Yu , Zhen Zhao . Digitalization-Driven Olefin Production: Digital Design of Catalysts for CO₂-Assisted Oxidation Dehydrogenation of Ethane to Ethylene. University Chemistry, 2026, 41(1): 363-372. doi: 10.12461/PKU.DXHX202506055
10. [10]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
11. [11]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
12. [12]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
13. [13]
  Zhipeng Bao , Yilin Wang , Yu Chen , Beirui Jia , Congcong Wang , Zean Xie , Xuehua Yu , Zhen Zhao . Digital and Intelligent Integration under the “Dual Carbon” Strategy: Plasma Reaction-Separation Coupling for CO₂ Hydrogenation to Methanol. University Chemistry, 2026, 41(1): 29-40. doi: 10.12461/PKU.DXHX202506009
14. [14]
  Tieping CAO , Yuejun LI , Dawei SUN . Surface plasmon resonance effect enhanced photocatalytic CO₂ reduction performance of S-scheme Bi₂S₃/TiO₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 903-912. doi: 10.11862/CJIC.20240366
15. [15]
  Hongli CHEN , Ziling XU , Shiwen DU , Ting WANG , Liguang WU . Controlled preparation of HKUST-1 based on polyvinylpyrrolidone and CO₂ separation performance of its doped mixed-matrix membranes. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 571-583. doi: 10.11862/CJIC.20250263
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
17. [17]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
18. [18]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
19. [19]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
20. [20]
  Mingming Zhang , Ting Xu , Ruonan Yin , Xueqiu Chen , Zheng-Jun Wang , Jun Li , Xin Wang , Huile Jin , Haibo Ke , Shun Wang , Jing-Jing Lv . Anode engineering for electrocatalytic CO₂ reduction reaction. Chinese Chemical Letters, 2026, 37(3): 110665-. doi: 10.1016/j.cclet.2024.110665

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(2146)
HTML views(465)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation, characterization and CO2 adsorption of ion exchange resin supported solid amine adsorbents

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation, characterization and CO₂ adsorption of ion exchange resin supported solid amine adsorbents