Citation: WANG Yan-juan, LIANG Fei-xue, BAI Jin, ZHANG Jian, WANG Hai-yan, WANG Bing. Study on the oxidative desulfurization performance of SiO₂-supported divanadium-substituted phosphotungstate hybrid material[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(9): 1099-1104. shu

Study on the oxidative desulfurization performance of SiO₂-supported divanadium-substituted phosphotungstate hybrid material

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Refining and Chemical Company, Petro-China Company Limited, Beijing 100007, China

Corresponding author: ZHANG Jian, zhangjian_lnpu@163.com
Received Date: 5 April 2016
Revised Date: 20 June 2016

Fund Project: the Natural Science Foundation of Liaoning Province 2015020590

Figures(6)

The Keggin type H₅PW₁₀V₂O₄₀ was synthesized by Na₂HPO₄, NaVO₃ and Na₂WO₄·12H₂O. The divanadium-substituted phosphotungstate hybrid material [Bmim]₅PW₁₀V₂O₄₀ was synthesized by reacting H₅PW₁₀V₂O₄₀ and 1-butyl-3-methylimidazolium bromide ([Bmim]Br). The FT-IR, XRD and UV-vis characterization results show that the [Bmim]₅PW₁₀V₂O₄₀ hybrid materials possess Keggin structure and the interactions between the [Bmim]⁺ and the [PW₁₀V₂O₄₀]^5-. The SiO₂-supported [Bmim]₅PW₁₀V₂O₄₀/SiO₂ was prepared and used for oxidative desulfurization of dibenzothiophene (DBT) with the H₂O₂ as the oxidant. The experimental results show that the DBT conversion can reach 100% in the [Bmim]₅PW₁₀V₂O₄₀/SiO₂-H₂O₂ oxidation system under the conditions of 40℃, oxigen/sulfur mol ratio 3.0 and 50 min reaction time. The catalyst was easily separated by centrifugation and could be reused for seven times without decreasing in oxidative desulfurization activity after drying treatment.
- divanadium-substituted phosphotungstate,
- H₂O₂,
- DBT,
- oxidative desulfurization,
- hybrid material
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Study on the oxidative desulfurization performance of SiO2-supported divanadium-substituted phosphotungstate hybrid material

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通讯作者: 陈斌, bchen63@163.com

Study on the oxidative desulfurization performance of SiO₂-supported divanadium-substituted phosphotungstate hybrid material