Citation: WEI Shao-qing, TENG Yang, LI Xiao-hang, SU Yin-jiao, YANG Wei, ZHANG Kai. Comparison of mercury emission from around 300 MW coal-fired power generation units between pulverized boiler and circulating fluidized-bed boiler[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(8): 1009-1016. shu

Comparison of mercury emission from around 300 MW coal-fired power generation units between pulverized boiler and circulating fluidized-bed boiler

  • Corresponding author: ZHANG Kai, kzhang@ncepu.edu.cn
  • Received Date: 24 January 2017
    Revised Date: 27 June 2017

    Fund Project: the Major Special Project of Shanxi Province MD2015-01the National Natural Science Foundation of China U1610254The project was supported by the National Natural Science Foundation of China(U1610254), the Major Special Project of Shanxi Province (MD2015-01) and the Fundamental Research Funds for the Central Universities(2017MS020)the Fundamental Research Funds for the Central Universities 2017MS020

Figures(5)

  • The mercury emission characteristics are investigated and compared at a coal-fired power plant with 330 MW pulverized coal (PC) boiler and a coal-fired power plant with 350 MW circulating fluidized bed (CFB) boiler. EPA 30B method and Ontario method were used to test the mercury concentration in flue gas at the inlet of dust extraction unit, outlet of dust extraction unit, outlet of desulfurization unit, and outlet of wet dust extraction unit. The feed coal, bottom ash, fly ash and gypsum sample were collected at the same time together with gas sampling. The effect of the existing air pollution control device on mercury control was discussed toward PC and CFB units based on the mercury distribution data. The results show that the mercury concentration at fabric filter (FF) outlet of CFB power plant is decreased to 0.43 μg/m3 and the mercury removal efficiency of FF reaches 98.9%. A predominating portion of mercury is enriched in fly ash. With respect to a PC power plant, the mercury concentrations at inlet and outlet of ESP are both higher than those in the CFB power plant, and the mercury concentration gradually drops from electrostatic precipitator (ESP) inlet to wet flue gas desulfurization (WFGD) outlet. The mercury concentration reaches a low value of 0.42 μg/m3 at the WFGD outlet, and the mercury removal efficiency of ESP and WFGD is 75.0% and 22.4%, respectively, which can meet the ultra low mercury emission controlling.
  • 加载中
    1. [1]

      YANG Ai-yong, YAN Zhicao, HUI Runtang, SHEN Zhiyong, ZHUANG Ke. The abundance, distribution, and modes of occurrence of Hg in Chinese coals[J]. Sci Technol Eng, 2105,15(32):93-100.  

    2. [2]

      Ministry of Environmental Protection. GB13223—2011 Pollutant emission standard in thermal power plant[S]. Beijing: Standards Press of China, 2011.

    3. [3]

      WU S, YANG W, ZHOU J, WANG H, XIE Z. Effects of properties of activated carbon on its activity for mercury removal and mercury desorption from used activated carbons[J]. Energy Fuels, 2015,29(3):1946-1950. doi: 10.1021/ef502868s

    4. [4]

      WANG S, ZHANG Y, GU Y, WANG J, LIU Z, ZHANG Y, CAO Y, ROMERO C E, PAN W. Using modified fly ash for mercury emissions control for coal-fired power plant applications in China[J]. Fuel, 2016,181:1230-1237. doi: 10.1016/j.fuel.2016.02.043

    5. [5]

      HONG Ya-guang, DUAN Yu-feng, ZHU Chun, SHE Min, DU Hong-fei. Experimental study on mercury adsorption of S-impregnated coconut shell activated carbon by duct injection[J]. J Eng Thermophys, 2015, 36(5): 1135-1138.

    6. [6]

      ZHANG L, WANG S, MENG Y, HAO J. Influence of Mercury and Chlorine Content of Coal on Mercury Emissions from Coal-Fired Power Plants in China[J]. Environ Sci Technol, 2012,46(11):6385-6392. doi: 10.1021/es300286n

    7. [7]

      XU Yue-yang, XUE Jian-ming, WANG Hong-liang, LI Bing, GUAN Yi-ming, LIU Jun. Research on mercury collaborative control by conventional pollutants purification facilities of coal-fired power plants[J]. Proc Chin Soc Electrical Eng, 2014,34(23):3924-3931.  

    8. [8]

      CHENG Le-ming, ZHOU Xing-long, ZHENG Cheng-hang, WANG Qin-hui, FANG Meng-xiang, SHI Zheng-lun, LUO Zhong-yang, CEN Ke-fa. Development of large-scale circulating fluidized bed boiler[J]. J Power Eng, 2008,28(6):817-826.  

    9. [9]

      HU Y, CHENG H. Control of mercury emissions from stationary coal combustion sources in China: Current status and recommendations[J]. Environ Pollut, 2016,218:1209-1221. doi: 10.1016/j.envpol.2016.08.077

    10. [10]

      CHEN B, LI J S, CHEN G Q, WEI W D, YANG Q, YAO M T, SHAO J A, ZHOU M, XIA X H, DONG K Q, XIA H H, CHEN H P. China's energy-related mercury emissions: Characteristics, impact of trade and mitigation policies[J]. J Clean Prod, 2017,141:1259-1266. doi: 10.1016/j.jclepro.2016.09.200

    11. [11]

      YU L, YIN L, XU Q, XIONG Y. Effects of different kinds of coal on the speciation and distribution of mercury in flue gases[J]. J Energy Inst, 2015,88(2):136-142. doi: 10.1016/j.joei.2014.06.006

    12. [12]

      RALLO M, HEIDEL B, BRECHTEL K, MAROTO-VALER M M. Effect of SCR operation variables on mercury speciation[J]. Chem Engineer J, 2012,198-199:87-94. doi: 10.1016/j.cej.2012.05.080

    13. [13]

      EOM Y, JEON S, NGO T, KIM J, LEE T. Heterogeneous mercury reaction on a selective catalytic reduction (SCR) catalyst[J]. Catal Lett, 2008,121(3/4):219-225.  

    14. [14]

      ZHOU Z, LIU X, ZHAO B, CHEN Z, SHAO H, WANG L, XU M. Effects of existing energy saving and air pollution control devices on mercury removal in coal-fired power plants[J]. Fuel Process Technol, 2015,131:99-108. doi: 10.1016/j.fuproc.2014.11.014

    15. [15]

      CAO Y, CHENG Q, CHEN C, LIU M, WANG C, PAN W. Abatement of mercury emissions in the coal combustion process equipped with a fabric filter baghouse[J]. Fuel, 2008,87:3322-3330. doi: 10.1016/j.fuel.2008.05.010

    16. [16]

      PUDASAINEE D, KIM J, YOON Y, SEO Y. Oxidation, reemission and mass distribution of mercury in bituminous coal-fired power plants with SCR, CS-ESP and wet FGD[J]. Fuel, 2012,93:312-318. doi: 10.1016/j.fuel.2011.10.012

    17. [17]

      ZHANG L, ZHUO Y, CHEN L, XU X, CHEN C. Mercury emissions from six coal-fired power plants in China[J]. Fuel Process Technol, 2008,89(11):1033-1040. doi: 10.1016/j.fuproc.2008.04.002

    18. [18]

      DUAN Yu-feng, JIANG Yi-man, YANG Li-guo, WANG Yun-jun. Experimental study on mercury emission and adsorption in circulating fluidized bed boiler[J]. Proc Chin Soc Electrical Eng, 2014,28(32):1-5.  

    19. [19]

      CHENG C, CAO Y, ZHANG K, PAN W. Co-effects of sulfur dioxide load and oxidation air on mercury re-emission in forced-oxidation limestone flue gas desulfurization wet scrubber[J]. Fuel, 2013,116:505-511.  

    20. [20]

      YUE C, WANG J, HAN L, CHANG L, HU Y, WANG H. Effects of pretreatment of Pd/AC sorbents on the removal of Hg0 from coal derived fuel gas[J]. Fuel Process Technol, 2015,135:125-132. doi: 10.1016/j.fuproc.2014.11.038

    21. [21]

      RRUPP E C, WILCOX J. Mercury chemistry of brominated activated carbons-Packed-bed breakthrough experiments[J]. Fuel, 2014,117:351-353. doi: 10.1016/j.fuel.2013.09.017

    22. [22]

      CHANG J C S, ZHAO Y. Pilot plant testing of elemental mercury reemission from a wet scrubber[J]. Energy Fuels, 2007,22(1):338-342.  

    23. [23]

      XIN M, GUSTIN M S, LADWIG K. Laboratory study of air-water-coal combustion product (fly ash and FGD solid) mercury exchange[J]. Fuel, 2006,85(16):2260-2267. doi: 10.1016/j.fuel.2006.01.029

  • 加载中
    1. [1]

      Hongbo Zhang Yihong Tang Suxia Zhang Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013

    2. [2]

      Yixian Zhou Xiaodong Shen Lina Zhu . Polycyclic Aromatic Hydrocarbons (PAHs) as Environmental Pollutants: Recent Advances in Adsorptive Removal Technologies. University Chemistry, 2026, 41(4): 239-249. doi: 10.12461/PKU.DXHX202502084

    3. [3]

      Xinxin YUYongxing LIUXiaohong YIMiao CHANGFei WANGPeng WANGChongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438

    4. [4]

      Zhiqiang XINGJinling LIUMingmin SULei ZHANGLijun YANG . CoNi dual-single-atom catalyst for electrocatalytic H2O2 production and in situ electro-Fenton degradation of pollutants. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2479-2490. doi: 10.11862/CJIC.20250181

    5. [5]

      Qingtao CHENXiangdong SHIXianghai RAOJiong LIXiaoyun QINYiwen GUANBinyan ZOUGuixia LIUFenghua CHEN . Employing polydopamine as an electron bridge to construct an S-scheme heterojunction and flexible film for highly efficient photocatalytic degradation of water pollutants. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 747-759. doi: 10.11862/CJIC.20250286

    6. [6]

      Yuanqing WangYusong PanHongwu ZhuYanlei XiangRong HanRun HuangChao DuChengling Pan . Enhanced Catalytic Activity of Bi2WO6 for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050

    7. [7]

      Changjun YouChunchun WangMingjie CaiYanping LiuBaikang ZhuShijie Li . Improved Photo-Carrier Transfer by an Internal Electric Field in BiOBr/N-rich C3N5 3D/2D S-Scheme Heterojunction for Efficiently Photocatalytic Micropollutant Removal. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-0. doi: 10.3866/PKU.WHXB202407014

    8. [8]

      Anqi LIWenjing YANGXueming LIYanfong REN . Performance and mechanism of a foam Ti/FeCo-Fe2O3-CoFe2O4/SnO2-Sb anode for synergistic activation of peroxymonosulfate toward degradation of organic pollutants. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 944-958. doi: 10.11862/CJIC.20250323

    9. [9]

      Jing Wang Pingping Li Yuehui Wang Yifan Xiu Bingqian Zhang Shuwen Wang Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097

    10. [10]

      Gaihua Li Donglian Liu Xiuge Wang Shuang Liu Ning Zhang Xuerui Tian . Teaching Design of Elemental Chemistry under the Concept of “Curriculum Ideology and Politics”: a Case of Mercury. University Chemistry, 2026, 41(2): 45-53. doi: 10.12461/PKU.DXHX202502025

    11. [11]

      Haobin Zhou Shuai Du Xuesong Guo Yue Wang Qin Zhong Tong Wang Yuzhi Wang Shuangyan Huan Hailong Yan Kun Li . 阳极溶出伏安法测定水中微量镉的无汞化改进. University Chemistry, 2026, 41(5): 275-284. doi: 10.12461/PKU.DXHX202511142

    12. [12]

      Hanmei LüXin ChenQifu SunNing ZhaoXiangxin Guo . Uniform Garnet Nanoparticle Dispersion in Composite Polymer Electrolytes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305016-0. doi: 10.3866/PKU.WHXB202305016

    13. [13]

      Han Ren Xingrui He Xiangfeng Zeng Zeyi Long Guifeng Wang Qixin Zhang Xiaochuan Zou . From Ancient Alchemical Furnaces to Contemporary Technological Wonders. University Chemistry, 2026, 41(2): 328-334. doi: 10.12461/PKU.DXHX202503111

    14. [14]

      Zhicheng JUWenxuan FUBaoyan WANGAo LUOJiangmin JIANGYueli SHIYongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    15. [15]

      Wan Li Mei Shi Yanping Ren Faqiong Zhao Min Hu Xiuyun Wang Juanjuan Song Yongxian Fan Dongcheng Liu Xiuqiong Zeng Wenwei Zhang Weihong Li Xiaohang Qiu Yong Fan Jianrong Zhang Shuyong Zhang . Suggestions on Heating and Heating Instruments (Part V): Solid-State Synthesis and High-Temperature Heating Using Muffle and Tube Furnaces. University Chemistry, 2026, 41(3): 182-190. doi: 10.12461/PKU.DXHX202507046

    16. [16]

      Jiahe PengDongxiao WenJizhou Jiang . Sustainable production of aviation fuel cycloalkanes from plastic waste under ambient-pressure conditions. Acta Physico-Chimica Sinica, 2026, 42(9): 100341-0. doi: 10.1016/j.actphy.2026.100341

    17. [17]

      Yan ZHAOXiaokang JIANGZhonghui LIJiaxu WANGHengwei ZHOUHai GUO . Preparation and fluorescence properties of Eu3+-doped CaLaGaO4 red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242

    18. [18]

      Jinmei Zhou Huamin Li Yiru Wang Wenwei Zhang Xiuqiong Zeng Juanjuan Song Yongxian Fan Dongcheng Liu Yanping Ren Faqiong Zhao Mei Shi Min Hu Wan Li Xiuyun Wang Weihong Li Xiaohang Qiu Yong Fan Jianrong Zhang Shuyong Zhang . Suggestions on Operational Standards for Heating and Heating Instruments (Part IV): Microwave Heating and the Use of Microwave Ovens, Microwave Reactor and Microwave Digester. University Chemistry, 2026, 41(3): 172-181. doi: 10.12461/PKU.DXHX202507043

    19. [19]

      Han ZHANGJianfeng SUNJinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na3CrF6 phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098

    20. [20]

      Xiaokang JIANGJunliang MAYan ZHAOFeng GAOChangli LIUXingshen ZHAOHengwei ZHOU . Preparation and luminescent properties of Sm3+-doped La2MgZrO6 phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 263-270. doi: 10.11862/CJIC.20250236

Metrics
  • PDF Downloads(0)
  • Abstract views(1700)
  • HTML views(196)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return