Citation: LIU Yang, HE Kun, LI Xian-qing, HAN Rui, WANG Zhe, XU Hong-wei. Performance of various catalysts in hydropyrolysis of organic matters and reaction mechanisms[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(1): 53-59. shu

Performance of various catalysts in hydropyrolysis of organic matters and reaction mechanisms

LIU Yang ^1,2,3 ,
HE Kun ³ ,
LI Xian-qing ^1,2,*,, ,
HAN Rui ² ,
WANG Zhe ^1,2 ,
XU Hong-wei ^1,2

1.
State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology (Beijing), Beijing 100083, China
2.
College of Geoscience and Surveying Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
3.
Key Laboratory of Petroleum Geochemistry, China National Petroleum Corporation, Beijing 100083, China

Corresponding author: LI Xian-qing, lixq@cumtb.edu.cn
Received Date: 28 July 2015
Revised Date: 9 November 2015

Fund Project: The project was supported by the National Natural Science Foundation of China 41572125National Special Fund for Research in the Public Interest 201311022Important National Science & Technology Specific Projects of China during the 12th Five-year Plan Period 2011ZX05007-002Independent Scientific Research Project of State Key Lab-oratory of Coal Resources and Safe Mining SKLCRSM10B04Important National Science & Technology Specific Projects of China during the 12th Five-year Plan Period 2011ZX05033-004

Figures(6)

The hydropyrolysis of organic matters was comparatively conducted over various catalysts including ZnCl₂, NiCl₂, Fe₂O₃, NaY and MoS₂ and the reaction mechanisms over different catalysts were then investigated. The results indicate that the yield and composition of liquid products from hydropyrolysis are related to the type of catalyst, though various catalysts do not have significant difference in the product biomarker parameters. Meanwhile, for the organic matters with different maturities and types, various catalysts are also quite different in their actual performance. The element analysis, infrared spectra and X-ray diffractograms of the solid residues illustrate that various catalysts are obviously different in the catalytic reaction mechanism. In comparison with NiCl₂, mass transfer is an important factor in the ZnCl₂ system, besides the catalytic cracking and catalytic hydrogenation. With Fe₂O₃ as the catalyst, the formation of H free radical by the adsorption of H₂ at the surface active O sites may promote the hydrogenation of organic matters. MoS₂ as the catalyst may involve two mechanisms, viz., the hydrogenation over transition metal Mo and the initiation of free radicals from H₂S intermediates.
- organic matters,
- hydropyrolysis,
- biomarkers,
- catalytic reaction mechanism
1. [1]
  LI Bao-qing. Hydropyrolysis of Chinese coals Ⅱ. Thermogravimetric study on catalytic and non-catalytic hydropyrolysis of Xianfeng lignite[J]. J Fuel Chem Technol, 1995,23(2):186-191.
2. [2]
  LI Bao-qing. Hydropyrolysis of Chinese coals Ⅲ. Catalytic and non-catalytic hydropyrolysis under H₂-CH₄ of Shenfu bituminous coal[J]. J Fuel Chem Technol, 1995,23(2):192-196.
3. [3]
  PETERS K E, MOLDOWAN J M. The bionmarker guide: Interpreting molecular fossoils in petroleum and ancient sediments[M]. New Jersey: Prentice Hall, 1993: 170-176.
4. [4]
  FU Jia-mo, SHENG Guo-ying, XU Jia-you, JIA Rong-fen, FAN Shan-fa, PENG Ping-an, EGLINTON G, GOWAR A P. Application of biomarker compounds in assessment of paleoenvironxnents of Chinese terrestrial sediments[J]. Geochimica, 1991,20(1):1-12.
5. [5]
  LOVE G D, SNAPE C E, CAM A D. Release of covalently-bound alkane biomarkers in high yields from kerogen via catalytic hydropyrolysis[J]. Org Geochem, 1995,23(10):981-986. doi: 10.1016/0146-6380(95)00075-5
6. [6]
  IKENAGA N, KAN-NAN S, SAKODA T, SUZUKI T. Coal hydroliquefaction using highly dispersed catalyst precursors[J]. Catal Today, 1997,39(1/2):99-109.
7. [7]
  INUKAI Y. Hydroliquefaction of Illinois NO.6 coal with petroleum atmospheric residue using oil-soluble molybdenum catalyst[J]. Fuel Process Technol, 1995,43(2):157-167. doi: 10.1016/0378-3820(95)00017-2
8. [8]
  YUE Chang-tao, LI Shu-yuan, XU Ming, ZHONG Ning-ning. Simulation experiments on the TSR system of diesel and mangnesium sulfate[J]. Pet Geol Exp, 2010,32(6):610-614.
9. [9]
  ROCHA J D, BROWN S D, LOVE G D, SNAPE C E. Hydropyrolysis: A versatile technique for solid fuel liquefaction, sulfur speciation and biomarker release[J]. J Anal Appl Pyrolysis, 1997,40-41:91-103. doi: 10.1016/S0165-2370(97)00041-7
10. [10]
  RUSSELL C A, SNAPE C E, MEREDITH W. The potential of bound biomarker prfiles released from catalytic hydropymlysis to reconstruction basin charging history for oils[C]. Abstract for 21th International Meeting on Organic Geochemistry K rakow. 2003: 160-161.
11. [11]
  LOCKHART R S, MEREDIT H W, LOVE G D. Release of bound aliphatic biomarkers via hydropyrolysis from Type Ⅱ kerogen at high maturity[J]. Org Geochem, 2008,39(8):1119-1124. doi: 10.1016/j.orggeochem.2008.03.016
12. [12]
  HE K, ZHANG S C, MI J K. Mechanism of catalytic hydropyrolysis of sedimentary organic matter with MoS₂[J]. Pet Sci, 2011,8(2):134-142. doi: 10.1007/s12182-011-0126-0
13. [13]
  ZELENSKI C M, DORHOUT P K. Template synthesis of near-monodisperse microscale nanofibers and nanotubes of MoS₂[J]. J Am Chem Soc, 1998,120(4):734-742. doi: 10.1021/ja972170q
14. [14]
  FARAG H, EI-HEDAWY A, SAKAISHI K, KISHIDA M, MOCHIDA I. Catalytic activity of synthesized nanosized molybdenum disulfide for the hydrodesulfurization of dibenzthiophene: Effect of H₂S partial pressure[J]. Appl Catal B: Environ, 2009,91(1/2):189-197.
15. [15]
  SONG J H, CHEN P L, KIM S H. Catalytic cracking of n-hexane over MoO₂[J]. J Mol Catal A, 2002,184(1/2):197-202.
16. [16]
  PINTO F, GULYURTLU I, LOBO L S, CABRITA I. The effect of catalyst blending on coal hydropyrolysis[J]. Fuel, 1999,78(7):761-768. doi: 10.1016/S0016-2361(98)00212-9
17. [17]
  SONG C S, NOMURA M, MIYAKE M. Coal hydroliquefaction using MoCl₃-and NiCl₂-containing salts as catalysts: Difference in catalysis between solid and molten catalysis[J]. Fuel, 1986,65(7):922-926. doi: 10.1016/0016-2361(86)90199-7
18. [18]
  WANG L, CHEN P. Mechanism study of iron-based catalysts in co-liquefaction of coal with waste plastics[J]. Fuel, 2002,81(6):811-815. doi: 10.1016/S0016-2361(01)00201-0
19. [19]
  HE K, DONG Y M, LI Z. Catalytic ozonation of phenol in water with natural brucite and magnesia[J]. J Hazard Mater, 2008,159(2/3):587-592.
20. [20]
  HE K, DONG Y M, LIN Y. A facile hydrothermal method to synthesize nanosized Co₃O₄/CeO₂ and study of its catalytic characteristic in catalytic ozonation of phenol[J]. Catal Lett, 2009,133(1):209-213.
21. [21]
  PRIYANTO U, SAKANISHI K, OKUMA O, MOCHIDA I. Liquefaction of Tanito Harum coal with bottom recycle using FeNi and FeMoNi catalysts supported on carbon nanoparticles[J]. Fuel Process Technol, 2002,79(1):51-62. doi: 10.1016/S0378-3820(02)00101-7
22. [22]
  SONG C, SAINI A K, YONEYAMA Y. A new process for catalytic liquefaction of coal using dispersed MoS₂ catalytic generated in situ with added H₂O[J]. Fuel, 2000,79(3/4):249-261.
23. [23]
  BOONE W P, EKERDT J G. Hydrodesulfurization studies with a single-layer molybdenum disulfite catalyst[J]. J Catal, 2000,193(1):96-102. doi: 10.1006/jcat.2000.2884
24. [24]
  ZHANG T W, AMRANI A, ELLIS G S, MA Q S, TANG Y C. Experimental investigation on thermochemical sulfate reduction by H₂S initiation[J]. Geochim Cosmochim Acta, 2008,72(14):3518-3530. doi: 10.1016/j.gca.2008.04.036
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