Citation: Hai Yang LIU, Xiao YING, Xi Ming HU, Yun Li GU, Yi LIU, Jin Wang HUANG, Liang Nian JI. Formation of Amino Acid Bridged Zinc Bisporphyrinethylenediamine Linear Supramolecular Array:UV-visible and ¹H NMR evidence[J]. Chinese Chemical Letters, ;1999, 10(3): 209-212. shu

Formation of Amino Acid Bridged Zinc Bisporphyrinethylenediamine Linear Supramolecular Array:UV-visible and ¹H NMR evidence

a Department of Applied Chemistry, Department of Physics, South China University of technology, Guangzhou 510641;
b Department of Chemistry, Zhongshan University, Guangzhou 510275

Received Date: 6 October 1998

Fund Project: This work was supported by Guangdong Provincial Natural Science Foundation (No.984041, 960291) and Natural Science Foundation of South China University of Technology (No.B8-124-014).

Coordination behavior of bidentate ligand ethylenediamine with a new chiral zinc bisporphyrin O.O-C₂-AA-C₂-(TPP)₂ Zn₂ was investigated by Uv-Vis titration and ¹H-NMR spectroscopy.which further evidenced that O.O-C₂-AA-C₂-(TPP)₂Zn₂, tends to form linear assembly with ethylenediamine in chloroform.
- Chiral zinc bisporphyrin,
- bidentate ligand,
- supramolecular assembly
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