Citation: Nan Xiao, Songsong Li, Xuli Li, Lei Ge, Yangqin Gao, Ning Li. The roles and mechanism of cocatalysts in photocatalytic water splitting to produce hydrogen[J]. Chinese Journal of Catalysis, ;2020, 41(4): 642-671. doi: S1872-2067(19)63469-8 shu

The roles and mechanism of cocatalysts in photocatalytic water splitting to produce hydrogen

Nan Xiao ^a,b, ,
Songsong Li ^b ,
Xuli Li ^b ,
Lei Ge ^a,b ,
Yangqin Gao ^b ,
Ning Li ^b

a State Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, China University of Petroleum Beijing, Beijing 102249, China;
b Department of Materials Science and Engineering, College of New Energy and Materials, China University of Petroleum Beijing, Beijing 102249, China

Received Date: 26 September 2019
Revised Date: 17 October 2019

Fund Project: This work was financially supported by the National Natural Science Foundation of China (51572295, 21273285 and 21003157), Beijing Nova Program (2008B76), and Science Foundation of China University of Petroleum, Beijing (KYJJ2012-06-20 and 2462016YXBS05).

Photocatalytic hydrogen (H₂) evolution via water spilling over semiconductors has been considered to be one of the most promising strategies for sustainable energy supply in the future to provide non-pollution and renewable energy. The key to efficient conversion of solar-chemical energy is the design of an efficient structure for high charge separation and transportation. Therefore, cocatalysts are necessary in boosting photocatalytic H₂ evolution. To date, semiconductor photocatalysts have been modified by various cocatalysts due to the extended light harvest, enhanced charge carrier separation efficiency and improved stability. This review focuses on recent developments of cocatalysts in photocatalytic H₂ evolution, the roles and mechanism of the cocatalysts are discussed in detail. The cocatalysts can be divided into the following categories:metal/alloy cocatalysts, metal phosphides cocatalysts, metal oxide/hydroxide cocatalysts, carbon-based cocatalysts, dual cocatalysts, Z-scheme cocatalysts and MOFs cocatalysts. The future research and forecast for photocatalytic hydrogen generation are also suggested.
- Cocatalysts,
- Photocatalytsts,
- Hydrogen evolution,
- Charge separation,
- Water splitting
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
73. [73]
74. [74]
75. [75]
76. [76]
77. [77]
78. [78]
79. [79]
80. [80]
81. [81]
82. [82]
83. [83]
84. [84]
85. [85]
86. [86]
87. [87]
88. [88]
89. [89]
90. [90]
91. [91]
92. [92]
93. [93]
94. [94]
95. [95]
96. [96]
97. [97]
98. [98]
99. [99]
100. [100]
101. [101]
102. [102]
103. [103]
104. [104]
105. [105]
106. [106]
107. [107]
108. [108]
109. [109]
110. [110]
111. [111]
112. [112]
113. [113]
114. [114]
115. [115]
116. [116]
117. [117]
118. [118]
119. [119]
120. [120]
121. [121]
122. [122]
123. [123]
124. [124]
125. [125]
126. [126]
127. [127]
128. [128]
129. [129]
130. [130]
131. [131]
132. [132]
133. [133]
134. [134]
135. [135]
136. [136]
137. [137]
138. [138]
139. [139]
140. [140]
141. [141]
142. [142]
143. [143]
144. [144]
145. [145]
146. [146]
147. [147]
148. [148]
149. [149]
150. [150]
151. [151]
152. [152]
153. [153]
154. [154]
155. [155]
156. [156]
157. [157]
158. [158]
159. [159]
160. [160]
161. [161]
162. [162]
163. [163]
164. [164]
165. [165]
166. [166]
167. [167]
168. [168]
169. [169]
170. [170]
171. [171]
172. [172]
173. [173]
174. [174]
175. [175]
176. [176]
177. [177]
178. [178]
179. [179]
180. [180]
181. [181]
182. [182]
183. [183]
184. [184]
185. [185]
186. [186]
187. [187]
188. [188]
189. [189]
190. [190]
191. [191]
192. [192]
193. [193]
194. [194]
195. [195]
196. [196]
197. [197]
198. [198]
199. [199]
200. [200]
201. [201]
202. [202]
203. [203]
204. [204]
205. [205]
206. [206]
207. [207]
208. [208]
209. [209]
210. [210]
211. [211]
212. [212]
213. [213]
214. [214]
215. [215]
216. [216]
217. [217]
218. [218]
219. [219]
220. [220]
221. [221]
222. [222]
223. [223]
224. [224]
225. [225]
226. [226]
227. [227]
228. [228]
229. [229]
230. [230]
231. [231]
232. [232]
233. [233]
234. [234]
235. [235]
236. [236]
237. [237]
238. [238]
239. [239]
240. [240]
241. [241]
242. [242]
243. [243]
244. [244]
245. [245]
246. [246]
247. [247]
248. [248]
249. [249]
250. [250]
251. [251]
252. [252]
1. [1]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
2. [2]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
3. [3]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
4. [4]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
5. [5]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
6. [6]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
7. [7]
  Jiajie Cai , Chang Cheng , Bowen Liu , Jianjun Zhang , Chuanjia Jiang , Bei Cheng . CdS/DBTSO-BDTO S型异质结光催化制氢及其电荷转移动力学. Acta Physico-Chimica Sinica, 2025, 41(8): 100084-. doi: 10.1016/j.actphy.2025.100084
8. [8]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
9. [9]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
10. [10]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
11. [11]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
12. [12]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-. doi: 10.1016/j.actphy.2025.100068
13. [13]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
16. [16]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
18. [18]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . 二维共价有机框架作为光催化剂在有机合成中的研究进展. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-. doi: 10.1016/j.actphy.2025.100086
19. [19]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ^-壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
20. [20]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(680)
HTML views(102)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142