Citation: Rao Lu, Lei He, Yang Wang, Xin-Qian Gao, Wen-Cui Li. Promotion effects of nickel-doped Al₂O₃-nanosheet-supported Au catalysts for CO oxidation[J]. Chinese Journal of Catalysis, ;2020, 41(2): 350-356. doi: S1872-2067(19)63439-X shu

Promotion effects of nickel-doped Al₂O₃-nanosheet-supported Au catalysts for CO oxidation

State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Received Date: 10 May 2019
Revised Date: 23 June 2019

Supported gold catalysts show high activity toward CO oxidation, and the nature of the support significantly affects the catalytic activity. Herein, serial Ni doping of thin porous Al₂O₃ nanosheets was performed via a precipitation-hydrothermal method by varying the amount of Ni during the precipitation step. The prepared nanosheets were subsequently used as supports for the deposition of Au nanoparticles (NPs). The obtained Au/Ni_xAl catalysts were studied in the context of CO oxidation to determine the effect of Ni doping on the supports. Enhanced catalytic performances were obtained for the Au/Ni_xAl catalysts compared with those of the Au supported on bare Al₂O₃. The Ni content and pretreatment atmosphere were both shown to influence the catalytic activity. Pretreatment under a reducing atmosphere was beneficial for improving catalytic activity. The highest activity was observed for the catalysts with a Ni/Al molar ratio of 0.05, achieving complete CO conversion at 20℃ with a gold loading of 1 wt%. The in-situ FTIR results showed that the introduction of Ni strengthened CO adsorption on the Au NPs. The H₂-TPR and O₂-TPD results indicated that the introduction of Ni produced new oxygen vacancies and allowed the oxygen molecules to be adsorbed and activated more easily. The improved catalytic performance after doping Ni was attributed to the smaller size of the Au NPs and more active oxygen species.
- Alumina,
- Gold catalyst,
- Nickel doping,
- CO oxidation,
- Oxygen activation
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通讯作者: 陈斌, bchen63@163.com

Promotion effects of nickel-doped Al₂O₃-nanosheet-supported Au catalysts for CO oxidation