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Citation: Linquan Bao, Chengcheng Zhao, Shenggang Li, Yan Zhu. Benzalaniline from nitrobenzene and benzaldehyde catalyzed efficiently by an atomically precise palladium nanocluster[J]. Chinese Journal of Catalysis, ;2019, 40(10): 1499-1504. doi: S1872-2067(19)63423-6 shu

Benzalaniline from nitrobenzene and benzaldehyde catalyzed efficiently by an atomically precise palladium nanocluster

a Key Laboratory of Mesoscopic Chemistry, MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, Jiangsu, China;
b Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

Received Date: 18 June 2019
Revised Date: 16 July 2019

Fund Project: We acknowledge financial supports from National Natural Science Foundation of China (21773109, 91845104).

Nanoclusters with a precise number of atoms may exhibit unique and often unexpected catalytic properties. Here, we report an atomically precise Pd₃ nanocluster as an efficient catalyst, whose catalytic performance differs remarkably from typical Pd nanoparticle catalysts, with excellent reactivity and selectivity in the one-pot synthesis of benzalaniline from nitrobenzene and benzaldehyde. We anticipate that our work will serve as a starting point for the catalytic applications of these tiny atomically precise nanoclusters in green chemistry for the one-pot syntheses of fine chemicals.
- Nanoclusters,
- Palladium,
- Reductive amidation,
- Selectivity,
- Activity
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
1. [1]
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