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Citation: Ekaterina Kholkina, Paivi Maki-Arvela, Chloe Lozachmeuer, Roman Barakov, Nataliya Shcherban, Dmitry Yu. Murzin. Prins cyclisation of (-)-isopulegol with benzaldehyde over ZSM-5 based micro-mesoporous catalysts for production of pharmaceuticals[J]. Chinese Journal of Catalysis, ;2019, 40(11): 1713-1720. doi: S1872-2067(19)63305-X shu

Prins cyclisation of (-)-isopulegol with benzaldehyde over ZSM-5 based micro-mesoporous catalysts for production of pharmaceuticals

a Johan Gadolin Process Chemistry Centre, Faculty of Science and Engineering, Åbo Akademi University, Turku 20500, Finland;
b L.V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 pr. Nauky, Kiev 03028, Ukraine

Received Date: 7 December 2018
Revised Date: 17 January 2019

Several ZSM-5 derived micro-mesoporous catalysts were investigated in Prins cyclisation of (-)-isopulegol with benzaldehyde acting as a reactant and a solvent for production of heterocyclic oxygen containing 2H-chromene derivatives including the tetrahydropyran structure and exhibiting biological activity. The investigated catalysts were characterized by nitrogen adsorption, ammonia temperature programmed desorption, adsorption-desorption of pyridine and 2,6-di-tert-butylpyridine with Fourier transform infrared spectroscopic control. For the Prins reaction performed at 70℃, the highest yield of the desired product, equal to 67% at complete conversion of (-)-isopulegol, was obtained over a micro-mesoporous catalyst containing an optimum amount of strong acid sites and mesopores, being 12 fold larger than the size of the desired product.
- Micro-mesoporous material,
- Prins cyclisation,
- Tetrahydropyran
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