Citation: Lihua Yang, Xuewen Li, Ping Chen, Zhaoyin Hou. Selective oxidation of glycerol in a base-free aqueous solution: A short review[J]. Chinese Journal of Catalysis, ;2019, 40(7): 1020-1034. doi: S1872-2067(19)63301-2 shu

Selective oxidation of glycerol in a base-free aqueous solution: A short review

Lihua Yang ^a, ,
Xuewen Li ^a ,
Ping Chen ^a ,
Zhaoyin Hou ^a,b

a Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang, China;
b Center of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang, China

Received Date: 18 November 2018
Revised Date: 9 January 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (21773208, 21473155) and the Natural Science Foundation of Zhejiang Province (L12B03001).

Catalytic transformation of glycerol to value-added products has attracted the attention of scientists all over the world. Among various transformations, selective oxidation of glycerol with molecular oxygen to dihydroxyacetone, glyceric acid, glyceraldehydes, and tartronic acid is challenging both from the viewpoint of academic research and industrial application. Herein, we review the recent progresses in the selective oxidation of glycerol under base-free conditions. Those catalysts widely reported for the selective oxidation of the terminal hydroxyl and secondary hydroxyl groups in glycerol, such as monometallic Au, Pt, and Pd NPs, and bimetallic Au-Pt, Au-Pd, Pt-Bi, Pt-Sb, and Pt-Cu, were compared and discussed in detail. The reaction mechanism over Pt-based catalysts, possible catalyst deactivation, and the corresponding improvements are presented. Further, the recent progresses in the continuous oxidation of glycerol in fixed bed reactors and its excellent selectivity in the formation of dihydroxyacetone are highlighted.
- Glycerol,
- Oxidation,
- Base-free condition,
- Catalyst,
- Reaction mechanism
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
73. [73]
74. [74]
75. [75]
76. [76]
77. [77]
78. [78]
79. [79]
80. [80]
81. [81]
82. [82]
83. [83]
84. [84]
85. [85]
86. [86]
87. [87]
88. [88]
89. [89]
90. [90]
91. [91]
92. [92]
93. [93]
94. [94]
95. [95]
96. [96]
97. [97]
98. [98]
99. [99]
100. [100]
101. [101]
102. [102]
103. [103]
104. [104]
105. [105]
106. [106]
107. [107]
108. [108]
109. [109]
110. [110]
111. [111]
112. [112]
113. [113]
114. [114]
115. [115]
116. [116]
117. [117]
118. [118]
119. [119]
120. [120]
121. [121]
122. [122]
123. [123]
124. [124]
125. [125]
126. [126]
127. [127]
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