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Citation: TANG Yue, DAI Quanquan, ZHANG Xuequan. Polymerization of Butadiene by Using a Novel Fe Catalyst System[J]. Chinese Journal of Applied Chemistry, ;2013, 30(1): 11-15. doi: DOI:10.3724/SP.J.1095.2013.20062 shu

Polymerization of Butadiene by Using a Novel Fe Catalyst System

TANG Yue ^a,b ,
DAI Quanquan ^b ,
ZHANG Xuequan ^a,b,,

1.
a Department of Chemical Engineering, Changchun University of Technology, Changchun 130012, China;
2.
b Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Corresponding author: ZHANG Xuequan,
Received Date: 28 February 2012
Available Online: 11 April 2012

Butadiene polymerization behaviors of Fe(CF₃SO₃)₂-Al(i-Bu)₃ catalyst system using diisooctyl phosphite as electron donor have been investigated.The catalyst system(n(Fe):n(P8):n(Al)=1:4:20) shows fair good activity,syndioselectivity,and especially,both catalytic activity and syndioselectivity increases as elevating polymerization temperature,yielding polybutadiene with over 85% of 1,2-structure content and 99% of syndiotacticity at 50℃.Differentiating from the Fe catalyst systems reported earlier,the current catalyst system possesses much better syndioselectivity and thermal tolerance allowing polymerizing butadiene at relatively high temperature.Particularly,the catalyst system does not involve using any noxious components,implying premising practical application in the area of butadiene polymerization.
- iron catalyst,
- butadiene polymerization,
- thermal tolerance,
- syndio-selectivity,
- syndiotactic 1,2-polybutadiene
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