Citation: Sun Qiangsheng, Sun Wei. Recent Progress in C(sp³)-H Asymmetric Oxidation Catalyzed by Bioinspired Metal Complexes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(11): 3686-3696. doi: 10.6023/cjoc202006008 shu

Recent Progress in C(sp³)-H Asymmetric Oxidation Catalyzed by Bioinspired Metal Complexes

Sun Qiangsheng ,
Sun Wei ^,

State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Corresponding author: Sun Wei, wsun@licp.cas.cn
Received Date: 5 June 2020
Revised Date: 19 June 2020
Available Online: 8 July 2020
Fund Project: the National Natural Science Foundation of China 21473226the National Natural Science Foundation of China 21902166the Key Research Program of Frontier Sciences, CAS QYZDJ-SSW-SLH051the Natural Science Foundation of Jiangsu Province BK20170420the National Natural Science Foundation of China 21773273Project supported by the National Natural Science Foundation of China (Nos. 21773273, 21473226, 21902166), the Key Research Program of Frontier Sciences, CAS (No. QYZDJ-SSW-SLH051) and the Natural Science Foundation of Jiangsu Province (No. BK20170420)

Figures(19)

C—H oxidation represents one of the most important reactions in organic chemistry. In particular, asymmetric C—H oxidation, which can directly convert simple alkanes into chiral alcohols, ketones, aldehydes and so on, provides more economic and efficient access to the synthesis of complex molecules. Although increasing efforts have been devoted to this area, asymmetric C—H oxidation is still far away from the goal due to the inert nature of C—H and the subtle stereo-difference of C—H bonds. The factors that dictate the selectivity of asymmetric C—H oxidation, mechanism of the C—H oxidation catalyzed by enzyme and some successful examples achieved by biomimetic metal complexes bearing various ligands are reviewed.
- C-H oxidation,
- metal complex,
- asymmetric oxidation
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Recent Progress in C(sp3)-H Asymmetric Oxidation Catalyzed by Bioinspired Metal Complexes

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通讯作者: 陈斌, bchen63@163.com

Recent Progress in C(sp³)-H Asymmetric Oxidation Catalyzed by Bioinspired Metal Complexes