Citation: Zhang Huifang, Qiu Zaozao, Xie Zuowei. Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives[J]. Chinese Journal of Organic Chemistry, ;2020, 40(10): 3203-3213. doi: 10.6023/cjoc202005079 shu

Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives

Zhang Huifang ^a,b ,
Qiu Zaozao ^b,c,, ,
Xie Zuowei ^b,d,,

a.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007
b.
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
c.
CAS Key Laboratory of Energy Regulation Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
d.
Department of Chemistry, The Chinese University of Hong Kong, Hong Kong

Corresponding author: Qiu Zaozao, qiuzz@sioc.ac.cn Xie Zuowei, zxie@cuhk.edu.hk
Received Date: 28 May 2020
Revised Date: 15 June 2020
Available Online: 19 June 2020
Fund Project: Chinese Academy of Sciences, and the Hong Kong Research Grants Council 14306519National Natural Science Foundation of China 21772223Project supported by the National Natural Science Foundation of China (No. 21772223), the Science and Technology Commission of Shanghai Municipality (No. 18590760800), the Chinese Academy of Sciences, and the Hong Kong Research Grants Council (No. 14306519)Science and Technology Commission of Shanghai Municipality 18590760800

Figures(22)

Carboranes are a class of carbon-boron molecular clusters with exceptional thermal and chemical stabilities. They are finding a variety of applications in medicine, materials, and coordination/organometallic chemistry as functional building blocks. To this end, the selective functionalization of carboranes has received growing research interests. Transition metal-promoted multicomponent cascade reactions are particularly attractive since they have the advantages of step- and atom- economy for the construction of complex products from readily available starting materials by simple operations. The recent advances in transition metal-promoted multicomponent cascade reactions for selective functionalization of carboranes are summarized in this focus review. The related reaction mechanisms and challenges in this research area are also discussed.
- borane cluster,
- carborane,
- transition metal,
- functionalization,
- cascade reaction
1. [1]
  (a) Grimes, R. N. Carboranes, 3rd ed., Academic Press, Amsterdam, 2016.
  (b) Hosmane, N. S. Boron Science: New Technologies and Application, CRC Press, Boca Raton, FL, 2012.
2. [2]
  (a) Scholz, M.; Hey-Hawkins, E. Chem. Rev. 2011, 111, 7035.
  (b) Leśnikowski, Z. J. J. Med. Chem. 2016, 59, 7738.
3. [3]
  (a) Hosmane, N. S.; Maguire, J. A. In Comprehensive Organometallic Chemistry Ⅲ, Vol. 3, Eds.: Crabtree, R. H.; Mingos, D. M. P., Elsevier, Oxford, 2007, Chapter 5.
  (b) Xie, Z. Acc. Chem. Res. 2003, 36, 1.
  (c) Yao, Z.-J.; Jin, G.-X. Coord. Chem. Rev. 2013, 257, 2522.
  (d) Qiu, Z.; Ren, S.; Xie, Z. Acc. Chem. Res. 2011, 44, 299.
  (e) Estrada, J.; Lavallo, V. Angew. Chem. Int. Ed. 2017, 56, 9906.
  (f) El-Hellani, A.; Lavallo, V. Angew. Chem. Int. Ed. 2014, 53, 4489.
  (g) Fisher, S. P.; Tomich, A. W.; Lovera, S. O.; Kleinsasser, J. F.; Guo, J.; Asay, M. J.; Nelson, H. M.; Lavallo, V. Chem. Rev. 2019, 119, 8262.
  (h) Yao, Z.-J.; Yu, W.-B.; Lin, Y.-J.; Huang, S.-L.; Li, Z.-H.; Jin, G.-X. J. Am. Chem. Soc. 2014, 136, 2825.
  (i) Gao, Y.; Guo, S.-T.; Cui, P.-F.; Aznarez, F.; Jin, G.-X. Chem. Commun. 2019, 55, 210.
  (j) Cui, P.-F.; Gao, Y.; Guo, S.-T.; Lin, Y.-J.; Li, Z.-H.; Jin, G.-X. Angew. Chem. Int. Ed. 2019, 58, 8129.
4. [4]
  (a) Jude, H.; Disteldorf, H.; Fischer, S.; Wedge, T.; Hawkridge, A. M.; Arif, A. M.; Hawthorne, M. F.; Muddiman, D. C.; Stang, P. J. J. Am. Chem. Soc. 2005, 127, 12131.
  (b) Koshino, M.; Tanaka, T.; Solin, N.; Suenaga, K.; Isobe, H.; Nakamura, E. Science 2007, 316, 853.
  (c) Dash, B. P.; Satapathy, R.; Gaillard, E. R.; Maguire, J. A.; Hosmane, N. S. J. Am. Chem. Soc. 2010, 132, 6578.
  (d) Kung, C.-W.; Otake, K.; Buru, C. T.; Goswami, S.; Cui, Y.; Hupp, J. T.; Spokoyny, A. M.; Farha, O. K. J. Am. Chem. Soc. 2018, 140, 3871.
  (e) Villagómez, C. J.; Sasaki, T.; Tour, J. M.; Grill, L. J. Am. Chem. Soc. 2010, 132, 16848.
  (f) Qian, E. Q.; Wixtrom, A. I.; Axtell, J. C.; Saebi, A.; Rehak, P.; Han, Y.; Moully, E. H.; Mosallaei, D.; Chow, S.; Messina, M.; Wang, J.-Y.; Royappa, A. T.; Rheingold, A. L.; Maynard, H. D.; Kral, P.; Spokoyny, A. M. Nat. Chem. 2017, 9, 333.
  (g) Saha, A.; Oleshkevich, E.; Viñas, C.; Teixidor, F. Adv. Mater. 2017, 29, 1704238.
  (h) Guo, J.; Liu, D.; Zhang, J.; Zhang, J.; Miao, Q.; Xie, Z. Chem. Commun. 2015, 51, 12004.
  (i) Jung, D.; Saleh, L. M. A.; Berkson, Z. J.; El-Kady, M. F.; Hwang, J. Y.; Mohamed, N.; Wixtrom, A. I.; Titarenko, E.; Shao, Y.; McCarthy, K.; Guo, J.; Martini, I. B.; Kraemer, S.; Wegener, E. C.; Saint-Cricq, P.; Ruehle, B.; Langeslay, R. R.; Delferro, M.; Brosmer, J. L.; Hendon, C. H.; Gallagher-Jones, M.; Rodriguez, J.; Chapman, K. W.; Miller, J. T.; Duan, X.; Kaner, R. B.; Zink, J. I.; Chmelka, B. F.; Spokoyny, A. M. Nat. Mater. 2018, 17, 341.
  (j) Cui, P.-F.; Lin, Y.-J.; Li, Z.-H.; Jin, G.-X. J. Am. Chem. Soc. 2020, 142, 8532.
5. [5]
  (a) Mukherjee, S.; Thilagar, P. Chem. Commun. 2016, 52, 1070.
  (b) Núñez, R.; Tarrés, M.; Ferrer-Ugalde, A.; de Biani, F. F.; Teixidor, F. Chem. Rev. 2016, 116, 14307.
  (c) Li, X.; Yan, H.; Zhao, Q. Chem. Eur. J. 2016, 22, 1888.
6. [6]
  (a) Heying, T. L.; Ager, J. W.; Clark, S. L.; Mangold, D. J.; Goldstein, H. L.; Hillman, M.; Polak, R. J.; Szymanski, J. W. Inorg. Chem. 1963, 2, 1089.
  (b) Fein, M. M.; Bobinski, J.; Mayes, N.; Schwartz, N.; Cohen, M. S. Inorg. Chem. 1963, 2, 1111.
  (c) El-Zaria, M. E., Keskar, K., Genady, A. R., Ioppolo, J. A., McNulty, J.; Valliant, J. F. Angew. Chem. Int. Ed. 2014, 53, 5156.
7. [7]
  (a) Wu, S.; Jones, M., Jr. Inorg. Chem. 1986, 25, 4802.
  (b) Bregadze, V. I. Chem. Rev. 1992, 92, 209.
  (c) Viñas, C.; Benakki, R.; Teixidor, F.; Casabó, J. Inorg. Chem. 1995, 34, 3844.
  (d) Gomez, F. A.; Johnson, S. E.; Hawthorne, M. F. J. Am. Chem. Soc. 1991, 111, 5915.
  (e) Gomez, F. A.; Hawthorne, M. F. J. Org. Chem. 1992, 57, 1384.
  (f) Anderson, K. P.; Mills, H. A.; Mao, C.; Kirlikovali, K. O.; Axtell, J. C.; Rheingold, A. L.; Spokoyny, A. M. Tetrahedron 2019, 75, 187.
8. [8]
  (a) Lu, J.-Y.; Wan, H.; Zhang, J.; Wang, Z.; Li, Y.; Du, Y.; Li, C.; Liu, Z.-T.; Liu, Z.-W.; Lu, J. Chem.-Eur. J. 2016, 22, 17542.
  (b) Tang, C.; Xie, Z. Angew. Chem. Int. Ed. 2015, 54, 7662.
  (c) Xie, Z. Sci. China Chem. 2014, 57, 1061.
  (d) Coult, R.; Fox, M. A.; Gill, W. R.; Herbertson, P. L.; MacBride, J. A. H.; Wade, K. J. Organomet. Chem. 1993, 462, 19.
9. [9]
  (a) Tang, C.; Zhang, J.; Xie, Z. Angew. Chem. Int. Ed. 2017, 56, 8642.
  (b) Tang, C.; Zhang, J.; Zhang, J.; Xie, Z. J. Am. Chem. Soc. 2018, 140, 16423.
10. [10]
  Lyu, H.; Zhang, J.; Yang, J.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2019, 141, 4219.
  (b) Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2015, 137, 3502.
  (c) Quan, Y.; Xie, Z. Angew. Chem. Int. Ed. 2016, 55, 1295.
  (d) Zhang, X.; Yan, H. Chem. Sci. 2018, 9, 3964.
  (e) Zhang, X.; Zheng, H.; Li, J.; Xu, F.; Zhao, J.; Yan, H. J. Am. Chem. Soc. 2017, 139, 14511.
  (f) Cao, K.; Huang, Y.; Yang, J.; Wu, J. Chem. Commun. 2015, 51, 7257.
  (g) Lin, F.; Yu, J.-L.; Shen, Y.; Zhang, S.-Q.; Spingler, B.; Liu, J.; Hong, X.; Duttwyler, S. J. Am. Chem. Soc. 2018, 140, 13798.
  (h) Xu, T. T.; Cao, K.; Zhang, C. Y.; Wu, J.; Ding, L. F.; Yang, J. Org. Lett. 2019, 21, 9276.
  (i) Xu, T. T.; Cao, K.; Zhang, C. Y.; Wu, J.; Jiang, L.; Yang, J. Chem. Commun. 2018, 54, 13603.
11. [11]
  (a) Liang, X.; Shen, Y.; Zhang, K.; Liu, J.; Duttwyler, S. Chem. Commun. 2018, 54, 12451.
  (b) Lin, F.; Shen, Y.; Zhang, Y.; Sun, Y.; Liu, J.; Duttwyler, S. Chem. Eur. J. 2018, 24, 551.
  (c) Lyu, H.; Quan, Y.; Xie, Z. Angew. Chem. Int. Ed. 2015, 54, 10623.
  (d) Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2014, 136, 15513.
  (e) Mirabelli, M. G. L.; Sneddon, L. G. J. Am. Chem. Soc. 1988, 110, 449.
  (f) Wu, J.; Cao, K.; Xu, T.-T.; Zhang, X.-J.; Jiang, L.; Yang, J.; Huang, Y., RSC Adv. 2015, 5, 91683.
  (g) Shen, Y.; Pan, Y.; Zhang, K.; Liang, X.; Liu, J.; Spingler, B.; Duttwyler, S. Dalton Trans. 2017, 46, 3135.
  (h) Shen, Y.; Zhang, K.; Liang, X.; Dontha, R.; Duttwyler, S. Chem. Sci. 2019, 10, 4177.
  (i) Cheng, R.; Qiu, Z.; Xie, Z. Chem. Eur. J. 2020, 26, 7121.
12. [12]
  (a) Chen, Y.; Au, Y. K.; Quan, Y.; Xie, Z. Sci. China Chem. 2019, 62, 74.
  (b) Quan, Y.; Tang, C.; Xie, Z. Chem. Sci. 2016, 7, 5838.
13. [13]
  Cheng, R.; Qiu, Z.; Xie, Z. Nat. Commun. 2017, 8, 14827. doi: 10.1038/ncomms14827
14. [14]
  Qiu, Z.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2013, 135, 12192. doi: 10.1021/ja405808t
15. [15]
  (a) Cui, C. X.; Zhang, J.; Qiu, Z.; Xie, Z. Dalton Trans. 2020, 49, 1380.
  (b) Au, Y. K.; Lyu, H.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2020, 142, 6940.
  (c) Lyu, H.; Quan, Y.; Xie, Z. Angew. Chem. Int. Ed. 2016, 55, 11840.
  (d) Cao, K.; Xu, T.-T.; Wu, J.; Jiang, L.; Yang, J. Chem. Commun. 2016, 52, 11446.
  (e) Li, C.-X.; Zhang, H.-Y.; Wong, T.-Y.; Cao, H.-J.; Yan, H.; Lu, C.-S. Org. Lett. 2017, 19, 5178.
16. [16]
  Lyu, H.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2016, 138, 12727. doi: 10.1021/jacs.6b07086
17. [17]
  Lyu, H.; Quan, Y.; Xie, Z. Chem. Eur. J. 2017, 23, 14866. doi: 10.1002/chem.201703006
18. [18]
  (a) Quan, Y.; Qiu, Z.; Xie, Z. Chem. Eur. J. 2018, 24, 2795.
  (b) Quan, Y.; Xie, Z. Chem. Soc. Rev. 2019, 48, 3660.
  (c) Yu, W.-B.; Cui, P.-F.; Gao, W.-X.; Jin, G.-X. Coord. Chem. Rev. 2017, 350, 300.
  (d) Zhang, X.; Yan, H. Coord. Chem. Rev. 2019, 378, 466.
19. [19]
  Qiu, Z.; Ren, S.; Xie, Z. Acc. Chem. Res. 2011, 44, 299. doi: 10.1021/ar100156f
20. [20]
  Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2009, 131, 2084. doi: 10.1021/ja809389k
21. [21]
  Deng, L.; Chan, H.-S.; Xie, Z. J. Am. Chem. Soc. 2006, 128, 7728. doi: 10.1021/ja061605j
22. [22]
  Ren, S.; Chan, H.-S.; Xie, Z. Organometallics 2009, 28, 4106. doi: 10.1021/om9002973
23. [23]
  Ren, S.; Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2012, 134, 3242. doi: 10.1021/ja211485t
24. [24]
  Ren, S.; Chan, H.-S.; Xie, Z. J. Am. Chem. Soc. 2009, 131, 3862. doi: 10.1021/ja900563u
25. [25]
  Ren, S.; Qiu, Z.; Xie, Z. Organometallics 2012, 31, 4435. doi: 10.1021/om300202p
26. [26]
  Ren, S.; Qiu, Z.; Xie, Z. Angew. Chem. Int. Ed. 2012, 51, 1010. doi: 10.1002/anie.201106212
27. [27]
  Quan, Y.; Zhang, J.; Xie, Z. J. Am. Chem. Soc. 2013, 135, 18742. doi: 10.1021/ja410233e
28. [28]
  Zhang, J.; Quan, Y.; Lin, Z.; Xie, Z. Organometallics 2014, 33, 3556. doi: 10.1021/om5004545
29. [29]
  Cui, C.-X.; Ren, S.; Qiu, Z.; Xie, Z. Dalton Trans. 2018, 47, 2453. doi: 10.1039/C7DT04751G
30. [30]
  Quan, Y.; Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2014, 136, 7599. doi: 10.1021/ja503489b
31. [31]
  Wang, Z.; Ye, H.; Li, Y.; Li, Y.; Yan, H. J. Am. Chem. Soc. 2013, 135, 11289. doi: 10.1021/ja4047075
32. [32]
  Zhang, R.; Zhu, L.; Liu, G.; Dai, H.; Lu, Z.; Zhao, J.; Yan, H. J. Am. Chem. Soc. 2012, 134, 10341. doi: 10.1021/ja303334t
33. [33]
  Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2010, 132, 16085. doi: 10.1021/ja1058789
34. [34]
  Lyu, H. Quan, Y.; Xie, Z. Chem. Sci. 2018, 9, 6390.
35. [35]
  Au, Y.-K.; Lyu, H.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2019, 141, 12855. doi: 10.1021/jacs.9b06204
36. [36]
  Au, Y.-K.; Lyu, H.; Quan, Y.; Xie, Z. Chin. J. Chem. 2020, 38, 383. doi: 10.1002/cjoc.201900475
37. [37]
  (a) Li, J.; Logan, C. F.; Jones, M. Jr. Inorg. Chem. 1991, 30, 4866.
  (b) Zheng, Z.; Jiang, W.; Zinn, A. A.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1995, 34, 2095.
  (c) Harakas, G.; Vu, T.; Knobler, C. B.; Hawthorne, M. F. J. Am. Chem. Soc. 1998, 120, 6405.
  (d) Viñas, C.; Barberà, G.; Oliva, J. M.; Teixidor, F.; Welch, A. J.; Rosair, G. M. Inorg. Chem. 2001, 40, 6555.
38. [38]
  Ge, Y.; Zhang, J.; Qiu, Z.; Xie, Z. Angew. Chem. Int. Ed. 2020, 59, 4851. doi: 10.1002/anie.201914500
39. [39]
  (a) Poater, J.; Solà, M.; Viñas, C.; Teixidor, F. Chem. Eur. J. 2016, 22, 7437.
  (b) Axtell, J. C.; Saleh, L. M. A.; Qian, E. A.; Wixtrom, A. I.; Spokoyny, A. M. Inorg. Chem. 2018, 57, 2333.
  (c) Bolli, C.; Derendorf, J.; Keßler, M.; Knapp, C.; Scherer, H.; Schulz, C.; Warneke, J. Angew. Chem. Int. Ed. 2010, 49, 3536.
  (d) Kirchmann, M.; Wesemann, L. Dalton Trans. 2008, 2144.
  (e) Messina, M. S.; Axtell, J. C.; Wang, Y.; Chong, P.; Wixtrom, A. I.; Kirlikovali, K. O.; Upton, B. M.; Hunter, B. M.; Shafaat, O. S.; Khan, S. I.; Winkler, J. R.; Gray, H. B.; Alexandrova, A. N.; Maynard, H. D.; Spokoyny, A. M. J. Am. Chem. Soc. 2016, 138, 6952.
  (f) Peryshkov, D. V.; Strauss, S. H. Inorg. Chem. 2017, 56, 4072.
  (g) Wang, W.; Wang, X.; Cao, J.; Liu, J.; Qi, B.; Zhou, X.; Zhang, S.; Gabel, D.; Nau, W. M.; Assaf, K. I.; Zhang, H. Chem. Commun. 2018, 54, 2098.
  (h) Assaf, K. I.; Ural, M. S.; Pan, F.; Georgiev, T.; Simova, S.; Rissanen, K.; Gabel, D.; Nau, W. M. Angew. Chem. Int. Ed. 2015, 54, 6852.
  (i) Assaf, K. I.; Hennig, A.; Peng, S.; Guo, D.-S.; Gabel, D.; Nau, W. M. Chem. Commun. 2017, 53, 4616.
  (j) Jung, D.; Saleh, L. M. A.; Berkson, Z. J.; El-Kady, M. F.; Hwang, J. Y.; Mohamed, N.; Wixtrom, A. I.; Titarenko, E.; Shao, Y.; McCarthy, K.; Guo, J.; Martini, I. B.; Kraemer, S.; Wegener, E. C.; Saint-Cricq, P.; Ruehle, B.; Langeslay, R. R.; Delferro, M.; Brosmer, J. L.; Hendon, C. H.; Gallagher-Jones, M.; Rodriguez, J.; Chapman, K. W.; Miller, J. T.; Duan, X.; Kaner, R. B.; Zink, J. I.; Chmelka, B. F.; Spokoyny, A. M. Nat. Mater. 2018, 17, 341.
40. [40]
  Zhang, Y.; Sun, Y.; Lin, F.; Liu, J.; Duttwyler, S. Angew. Chem. Int. Ed. 2016, 55, 15609. doi: 10.1002/anie.201607867
41. [41]
  Zhang, Y.; Wang, T.; Wang, L.; Sun, Y.; Lin, F.; Liu, J.; Duttwyler, S. Chem. Eur. J. 2018, 24, 15812. doi: 10.1002/chem.201803455
42. [42]
  Cheng, R.; Li, B.; Wu, J.; Zhang, J.; Qiu, Z.; Tang, W.; You, S. L.; Tang, Y.; Xie, Z. J. Am. Chem. Soc. 2018, 140, 4508. doi: 10.1021/jacs.8b01754
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142