Citation: Zhang Huifang, Qiu Zaozao, Xie Zuowei. Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives[J]. Chinese Journal of Organic Chemistry, ;2020, 40(10): 3203-3213. doi: 10.6023/cjoc202005079 shu

Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives

Zhang Huifang ^a,b ,
Qiu Zaozao ^b,c,, ,
Xie Zuowei ^b,d,,

a.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007
b.
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
c.
CAS Key Laboratory of Energy Regulation Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
d.
Department of Chemistry, The Chinese University of Hong Kong, Hong Kong

Corresponding author: Qiu Zaozao, qiuzz@sioc.ac.cn Xie Zuowei, zxie@cuhk.edu.hk
Received Date: 28 May 2020
Revised Date: 15 June 2020
Available Online: 19 June 2020
Fund Project: Chinese Academy of Sciences, and the Hong Kong Research Grants Council 14306519National Natural Science Foundation of China 21772223Project supported by the National Natural Science Foundation of China (No. 21772223), the Science and Technology Commission of Shanghai Municipality (No. 18590760800), the Chinese Academy of Sciences, and the Hong Kong Research Grants Council (No. 14306519)Science and Technology Commission of Shanghai Municipality 18590760800

Figures(22)

Carboranes are a class of carbon-boron molecular clusters with exceptional thermal and chemical stabilities. They are finding a variety of applications in medicine, materials, and coordination/organometallic chemistry as functional building blocks. To this end, the selective functionalization of carboranes has received growing research interests. Transition metal-promoted multicomponent cascade reactions are particularly attractive since they have the advantages of step- and atom- economy for the construction of complex products from readily available starting materials by simple operations. The recent advances in transition metal-promoted multicomponent cascade reactions for selective functionalization of carboranes are summarized in this focus review. The related reaction mechanisms and challenges in this research area are also discussed.
- borane cluster,
- carborane,
- transition metal,
- functionalization,
- cascade reaction
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沈阳化工大学材料科学与工程学院沈阳 110142